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951.
为研究老年人彩色视觉频率响应特性,获取彩度对比敏感度与空间频率之间的函数关系,本文在LCH均匀颜色空间基础上,固定明度和色调角值,以彩度作为变量,设计人眼彩度对比敏感度实验,进行人眼视觉观察实验。获得彩度对比敏感度与空间频率的关系,并构建指数型对比敏感度函数模型。经分析表明老年人眼彩度对比敏感度随着空间频率的增加,产生先升高再缓慢降低的变化,各色调角下彩度对比度存在差异。经分析人眼对比敏感度差异与人眼视觉辨色特性有很大的相关性。并且,将构建的对比敏感度函数模型用于实现基于人眼视觉系统的滤波处理。 相似文献
952.
The effect of polystyrene sulfonic acid (PSSA) macromolecules on the polymerization of acrylamide (AM) has been studied. It was found that the rates of polymerization of AM were greatly increased in the presence of PSSA in the polymerization system.The maximum value of the rate of polymerization of AM was obtained when the ratio of [—SO_3H]: [AM] reached 3:1. When the insoluble crosslinked PSSA was used instead of the soluble one, this effect decreased considerably. The interaction between molecules of PSSA and AM was determined by infrared spectroscopy, elementary analysis and X-ray photoelectron spectroscopy. The combination form, —SO_3-NH_3~ CO—, formed between sulfonic group and amide group was found to be existed since the infrared absorption band of —NH_2 shifted from 3400cm~(-1) to 3150 cm~(-1), the binding energy of electron N_(18) changed from 399.7 eV to 401.3 eV, and the atomic ratio of N to S of the products was similar to the ratio of reagents. Based on these experimental results, the mechanism of AM polymerization in the presence of PSSA is proposed. The initial step is the combination of AM with sulfonic group to form —CONH_3~ , then followed by polymerization on the PSSA macromolecule. The role of PSSA on the polymerization of AM is discussed. 相似文献
953.
954.
应用ahinitio计算程序,我们对飞行时间质谱产生的谱图进行了理论分析。稳定的MnnPm+和CrnPm+的结构基本上是多面体,仅有少数结构为环状和平面的。在计算中,我们尚未发现有链状的簇合物,这与风簇绝大多数是多面体是相一致的。因此,单枚金属簇合物的形成机制很大可能是金属进入磷形成的笼簇中。一般地说,除了磷的个别笼状团簇外,金属和磷相互成键是普遍存在的;在二核、多核金属磷簇合物中,金属间相互作用不常见,绝大多数是通过桥磷相连的。 相似文献
955.
To assay antiviral effects of the polysaccharide and its separated products from Sargassumfusiforme on HSV-1 and CVB3 and their antiviral mechanism, the antiviral effects of all samples on HSV-1 and CVB3 and their cytotoxicity on vero cells were studied by CPE and MTT method. Antiviral mechanism of two samples was briefly studied by four different ways. The cytotoxicity of samples on vero cells was not detected (CC>5000 μg/mL). All samples except PSJ had obviously HSV-1 inhibitory effect. Antiviral activities of them were increasingly strengthened with raising their purities.Antiviral activities of F1, F2 and F4 were better than that of ACV, and antiviral activities of all samples on CVB3 were better than ribavirin injection. Fi, F2 and F4 had remarkable anti-CVB3 activity. The experiment showed that polysaccharide was able to not only kill the above viruses directly but also restrain them by getting into cell or absorbing on cells. 相似文献
956.
957.
In this paper, the nanosecond transient absorption spectra and the fluorescence spectraof Hypocrellin A(HA) are examined in solvents of varying polarity. There are three absorp-tion bands in dilute HA solutions: Ⅰa, Ⅱa are defined as the triplet-triplet absorption ofHA, the band Ⅲa is supposed to be the absorption of the solvent--sepatated ion pair (SSIP).In more concentrated solutions, only the absorption of SSIP was observed. The effects ofsolvent polarity on transient absorption spectra and fluorescence spectra of HA and the effectof oxygen on the intensities of the fluorescence of HA are discussed. Then a reasonablemechanism for the photolysis of HA is proposed. 相似文献
958.
用INDO/CI方法研究了含有Fe-Fe键的原子簇体系[Fe2S2X4]^2-(X=Cl,Br,I)的电子光谱及电子结构,对于这些多谱带体系,谱带波数计算值与实验值符合,在谱带的指认分析中,发现了πd^1→πd等新的跃迁方式,对跃迁方式作了解释和分类,并讨论了谱带的电荷转移性质,此外,还对体系的化学键等性质进行了分析。 相似文献
959.
960.
用X-射线晶体结构衍射法测定了双[1-苄基-1-乙基丙基环戊二烯基]二氯化锆[η5-C5H4C(C2H5)2CH2C6H5]2ZrCl2(I)及(1,2-二异丁基-1,2-甲基-乙基桥联)双环戊二烯基二氯化锆[η5-C5H4C(CH3)(C4H9-i)C(CH3)(C4H9-i)C5H4-η5]ZrCl2(Ⅱ)的结构。二者皆为单斜晶系,(I)的空间群为P2/n,a=12.582(3),b=7.992(2),c=14.979(3)A,β=101.68(1)°,V=1474.9(9)A3,Mr=612.84,Z=2,Dx=1.38g/cm3,μ=5.69cm(-1),F(000)=640,R=0.033,Rω=0.036。(Ⅱ)的空间群为Cc,a=13.309(3),b=9.591(1),c=16.449(8)A。β=4.83(3)°,V=209.2(2)A3,Mr=458.63,Z=4,Dx=1.456g/cm3,μ=7.77cm(-1),F(000)=952,R=0.051,Rω=0.061。化合物(I)以重叠式存在,两个苄基处于反式。晶体(Ⅱ)以交叉式存在,甲基、异丁基以反式构象存在。 相似文献