全文获取类型
收费全文 | 124831篇 |
免费 | 1527篇 |
国内免费 | 456篇 |
专业分类
化学 | 68467篇 |
晶体学 | 2035篇 |
力学 | 4955篇 |
综合类 | 5篇 |
数学 | 12112篇 |
物理学 | 39240篇 |
出版年
2016年 | 1272篇 |
2015年 | 982篇 |
2014年 | 1319篇 |
2013年 | 4775篇 |
2012年 | 3376篇 |
2011年 | 4383篇 |
2010年 | 2733篇 |
2009年 | 2514篇 |
2008年 | 3922篇 |
2007年 | 3977篇 |
2006年 | 4037篇 |
2005年 | 3962篇 |
2004年 | 3453篇 |
2003年 | 3150篇 |
2002年 | 3053篇 |
2001年 | 3571篇 |
2000年 | 2674篇 |
1999年 | 2196篇 |
1998年 | 1884篇 |
1997年 | 1873篇 |
1996年 | 1802篇 |
1995年 | 1772篇 |
1994年 | 1545篇 |
1993年 | 1533篇 |
1992年 | 1754篇 |
1991年 | 1746篇 |
1990年 | 1677篇 |
1989年 | 1684篇 |
1988年 | 1684篇 |
1987年 | 1674篇 |
1986年 | 1587篇 |
1985年 | 2135篇 |
1984年 | 2262篇 |
1983年 | 1887篇 |
1982年 | 2213篇 |
1981年 | 2027篇 |
1980年 | 2074篇 |
1979年 | 2058篇 |
1978年 | 2186篇 |
1977年 | 2091篇 |
1976年 | 2115篇 |
1975年 | 2053篇 |
1974年 | 1895篇 |
1973年 | 2102篇 |
1972年 | 1282篇 |
1971年 | 977篇 |
1970年 | 912篇 |
1969年 | 923篇 |
1968年 | 1050篇 |
1967年 | 1101篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
911.
912.
913.
914.
915.
Summary This paper describes the determination of all carbamate pesticides mentioned in the Austrian regulations for pesticides and of some other carbamates commonly used in the EEC. Clean-up procedure is carried out by ethyl acetate extraction. Purification is by a liquid-liquid extraction step followed by use of a florisil column. Final detection of the carbamates is carried out by HPLC on silica gel and GLC respectively The method works well for all carbamates under consideration. Only benzimidazolamine-2, the decomposition product of benomyl and carbendazime cannot be determined by the method described. Therefore determination of benomyl, carbendazime and benzimidazolamine-2 was by hydrolysis of benomyl and carbendazime to benzimidazolamine-2, which is then determined by reversed-phase chromatography. 相似文献
916.
J. Goworek W. Stefaniak Agnieszka Kierys Mariola Iwan 《Journal of Thermal Analysis and Calorimetry》2007,87(1):217-222
Mesoporous silica material of MCM-41 type was synthesized by co-condensation
of highly concentrated octyltriethoxysilane (OTEOS), octadecyltriethoxysilane
(ODTEOS) and tetraethoxysilane (TEOS). The obtained hybrid materials were
characterized using XRD, TG-DSC and low temperature adsorption/desorption
of nitrogen. It was shown that the applied method of synthesis allows to obtain
silica of MCM-41 type with a high degree of hydrocarbon saturation. 相似文献
917.
A. W. Flounders D. L. Brandon A. H. Bates 《Applied biochemistry and biotechnology》1995,50(3):265-284
Monoclonal antibodies specific for thiabendazole were immobilized to silicon, silicon dioxide, stoichiometric silicon nitride,
and silicon-rich silicon nitride surfaces. This work provides the foundation for the development of a homogeneous sensor system
for rapid detection and quantification of thiabendazole residues in produce and animal tissue. Immobilization was performed
via aqueous silanization of the substrate followed sequentially by treatment with glutaraldehyde and contact with antibody
solution in the presence of detergent. Surfaces were challenged with thiabendazole-horseradish peroxidase conjugate in an
ELISA format to estimate immobilized antibody load. A stable and reproducible surface loading of 2 x 1011 antibodies/cm2 was obtained only after surfaces received postimmobilization treatments to remove nonspecifically adsorbed antibody. No difference
in surface loading was noted when using 30% hydrogen peroxide rather than nitric acid for silanol activation. Little difference
was noted among the antibody loadings achieved on the various silicon substrates. Bound antigen-enzyme conjugate was eluted
with 0.1N acetic acid and reproducible surface activity was measured for up to four consecutive antigen challenges. Immobilized
antibody surfaces were stabilized with 2% sucrose, dehydrated at 37‡C and stored in vacuum or stored at 4‡C in phosphate buffered
saline containing 0.01% sodium azide without significant loss of activity. 相似文献
918.
Since the early reports of MOFs and their interesting properties, research involving these materials has grown wide in scope and applications. Various synthetic approaches have ensued in view of obtaining materials with optimised properties, the extensive scope of application spanning from energy, gas sorption, catalysis biological applications has meant exponentially evolved over the years. The far‐reaching synthetic and PSM approaches and porosity control possibilities have continued to serve as a motivation for research on these materials. With respect to the biological applications, MOFs have shown promise as good candidates in applications involving drug delivery, BioMOFs, sensing, imaging amongst others. Despite being a while away from successful entry into the market, observed results in sensing, drug delivery, and imaging put these materials on the spot light as candidates poised to usher in a revolution in biology. In this regard, this review article focuses current approaches in synthesis, post functionalization and biological applications of these materials with particular attention on drug delivery, imaging, sensing and BioMOFs. 相似文献
919.
Summary A method for the gas chromatographic trace analysis of underivatized nitrophenols in ground-water is presented. Using a highly
de-activated separation system a satisfactory precision for their quantitative GC analysis could be achieved by avoiding condensation
of the solvent and by fast injection of the sample. The reproducibility of the peak areas of eleven nitrophenols in ethylacetate
was <5 % RSD. Using a nitrogen-phosphorus detector detection limits were in a range from 10 to 30 pg. Within the concentration
range from 0.1 to 10 ng μl−1 the calibrations were linear with correlation coefficients >0.992.
The approach described was applied to the analysis of nitrophenols in ground-water near a former ammunition plant, after preconcentration
by continuous liquid/liquid extraction with ethylacetate. Using a GC-MS technique and retention times various nitrophenols
were identified and then quantified in the μg/L-range by applying NPD. 相似文献
920.
Ghandi K Addison-Jones B Brodovitch JC McCollum BM McKenzie I Percival PW 《Journal of the American Chemical Society》2003,125(32):9594-9595
Muoniated free radicals have been detected in muon-irradiated aqueous solutions of acetone at high temperatures and pressures. At temperatures below 250 degrees C, the radical product is consistent with muonium addition to the keto form of acetone. However, at higher temperatures, a different radical was detected, which is attributed to muonium addition to the enol form. Muon hyperfine coupling constants have been determined for both radicals over a wide range of temperatures, significantly extending the range of conditions under which these radicals and the keto-enol equilibrium have been studied. 相似文献