全文获取类型
收费全文 | 5880篇 |
免费 | 113篇 |
专业分类
化学 | 3207篇 |
晶体学 | 30篇 |
力学 | 130篇 |
数学 | 1375篇 |
物理学 | 1251篇 |
出版年
2021年 | 33篇 |
2020年 | 43篇 |
2019年 | 51篇 |
2018年 | 140篇 |
2017年 | 127篇 |
2016年 | 203篇 |
2015年 | 143篇 |
2014年 | 197篇 |
2013年 | 475篇 |
2012年 | 290篇 |
2011年 | 399篇 |
2010年 | 212篇 |
2009年 | 182篇 |
2008年 | 333篇 |
2007年 | 327篇 |
2006年 | 304篇 |
2005年 | 223篇 |
2004年 | 199篇 |
2003年 | 148篇 |
2002年 | 135篇 |
2001年 | 95篇 |
2000年 | 79篇 |
1999年 | 56篇 |
1998年 | 50篇 |
1997年 | 49篇 |
1996年 | 48篇 |
1995年 | 47篇 |
1994年 | 30篇 |
1993年 | 42篇 |
1992年 | 56篇 |
1991年 | 42篇 |
1990年 | 47篇 |
1989年 | 51篇 |
1988年 | 48篇 |
1987年 | 46篇 |
1986年 | 40篇 |
1985年 | 60篇 |
1984年 | 66篇 |
1983年 | 64篇 |
1982年 | 61篇 |
1981年 | 41篇 |
1980年 | 53篇 |
1979年 | 48篇 |
1978年 | 69篇 |
1977年 | 39篇 |
1976年 | 53篇 |
1975年 | 40篇 |
1974年 | 48篇 |
1973年 | 40篇 |
1972年 | 33篇 |
排序方式: 共有5993条查询结果,搜索用时 15 毫秒
991.
Göötz B Popović DB David DE Michl J Swiderek P 《The journal of physical chemistry. B》2006,110(11):5480-5485
Angular distributions of electrons scattered elastically and inelastically from cold solid molecular films of ethylene and nitrogen in various proportions, grown from the gas phase at different temperatures, have been studied by high-resolution electron energy loss spectroscopy. The probing depth of dipole and impact scattering has been investigated by covering the sample by overlayers of argon of increasing thickness. The angular distribution measured for elastically and inelastically dipole-scattered electrons was found to be peaked about the specular direction for all surface conditions studied, while a diffuse angular distribution was possible for electrons that underwent dipole-forbidden scattering. These results allow us to identify favorable conditions for monitoring the composition of a solid sample during the course of reactions occurring under exposure to low-energy electrons. 相似文献
992.
We study the conformational behavior of DNA molecules adsorbed on cationic-lipid membranes that are supported on grooved, one-dimensionally periodic microstructured surfaces. We reveal a striking ability of these periodically structured membranes to stretch DNA coils. We elucidate this DNA stretching phenomenon in terms of surface curvature dependent potential energy attained by the adsorbed DNA molecules. Because of it, DNA molecules undergo a localization transition causing them to stretch by binding to highly curved sections of the supported membranes. 相似文献
993.
Staresinić D Lunkenheimer P Hemberger J Biljaković K Loidl A 《Physical review letters》2006,96(4):046402
We report on broadband dielectric spectroscopy on the one-dimensional semiconductor (NbSe4)3I. Below the structural phase transition close to 270 K, which is accompanied by complex charge-order processes, we observe colossal dielectric constants with a frequency and temperature dependence very similar to what is observed in charge-density wave systems. 相似文献
994.
The generation and nonlinear dynamics of multidimensional optical dissipative solitonic pulses are examined. The variational method is extended to complex dissipative systems, in order to obtain steady state solutions of the (D + 1)-dimensional complex cubic-quintic Ginzburg-Landau equation (D = 1, 2, 3). A stability criterion is established fixing a domain of dissipative parameters for stable steady state solutions. Following numerical simulations, evolution of any input pulse from this domain leads to stable dissipative solitons. 相似文献
995.
Tasić U Alexeev Y Vayner G Crawford TD Windus TL Hase WL 《Physical chemistry chemical physics : PCCP》2006,8(40):4678-4684
Ab initio calculations at the CCSD(T)/aug-cc-pVTZ level of theory were used to characterize the Ar-CH(3)OH intermolecular potential energy surface (PES). Potential energy curves were calculated for four different Ar + CH(3)OH orientations and used to derive an analytic function for the intermolecular PES. A sum of Ar-C, Ar-O, Ar-H(C), and Ar-H(O) two-body potentials gives an excellent fit to these potential energy curves up to 100 kcal mol(-1), and adding an additional r(-n) term to the Buckingham two-body potential results in only a minor improvement in the fit. Three Ar-CH(3)OH van der Waals minima were found from the CCSD(T)/aug-cc-pVTZ//MP2/aug-cc-pVTZ calculations. The structure of the global minimum is in overall good agreement with experiment (X.-C. Tan, L. Sun and R. L. Kuczkowski, J. Mol. Spectrosc., 1995, 171, 248). It is T-shaped with the hydroxyl H-atom syn with respect to Ar. Extrapolated to the complete basis set (CBS) limit, the global minimum has a well depth of 0.72 kcal mol(-1) with basis set superposition error (BSSE) correction. The aug-cc-pVTZ basis set gives a well depth only 0.10 kcal mol(-1) smaller than this value. The well depths of the other two minima are within 0.16 kcal mol(-1) of the global minimum. The analytic Ar-CH(3)OH intermolecular potential also identifies these three minima as the only van der Waals minima and the structures predicted by the analytic potential are similar to the ab initio structures. The analytic potential identifies the same global minimum and the predicted well depths for the minima are within 0.05 kcal mol(-1) of the ab initio values. Combining this Ar-CH(3)OH intermolecular potential with a potential for a OH-terminated alkylthiolate self-assembled monolayer surface (i.e., HO-SAM) provides a potential to model Ar + HO-SAM collisions. 相似文献
996.
The mechanisms of the carboxylations of lithium, potassium, rubidium, and cesium phenoxides are investigated by means of the DFT method with the LANL2DZ basis set. It is shown that the reactions of all alkali metal phenoxides with carbon dioxide occur via very similar reaction mechanisms. The reactions can proceed in the ortho and para positions. The exception is lithium phenoxide which yields only salicylic acid in the Kolbe-Schmitt reaction. It is found that the yield of the para substituted product increases with increasing the ionic radius of the alkali metal used. An explanation for this experimental and theoretical observation is proposed. 相似文献
997.
Hydride affinities (HAs) of the ethynes substituted by a wide range of different substituents are considered by using the B3LYP methodology. The computed values are in fair agreement with available experimental data, which are unfortunately scarce. The trend of changes of the HAs is rationalized by trichotomy formula. One of the important results of this analysis is a finding that similar HA values might result from completely different effects. Alternative sites of the H- attack are examined and the difference in energies relative to the most susceptible positions is interpreted. Structural features of substituted ethyne hydrides are briefly discussed. 相似文献
998.
A review of results of bioactivity and reactivity examinations of marine sesquiterpene (hydro)quinones is presented. The article is focused mostly on friedo- rearranged drimane structural types, isolated from sponges of the order Dictyoceratida. Examples of structural correlations are outlined. Available results on the mechanism of redox processes and examinations of chemo- and regioselectivity in addition reactions are presented and, where possible, analyzed in relation to established bioactivities. Most of the bioactivity examinations are concerned with antitumor activities and the mechanism thereof, such as DNA damage, arylation of nucleophiles, tubulin assembly inhibition, protein kinase inhibition, inhibition of the arachidonic cascade, etc. Perspectives on marine drug development are discussed with respect to biotechnological methods and synthesis. Examples of the recognition of validated core structures and synthesis of structurally simplified compounds retaining modes of activity are analyzed. 相似文献
999.
Josipa-Pina Milišić 《Journal of Differential Equations》2018,264(9):5629-5658
In this paper we consider a degenerate pseudoparabolic equation for the wetting saturation of an unsaturated two-phase flow in porous media with dynamic capillary pressure-saturation relationship where the relaxation parameter depends on the saturation. Following the approach given in [13] the existence of a weak solution is proved using Galerkin approximation and regularization techniques. A priori estimates needed for passing to the limit when the regularization parameter goes to zero are obtained by using appropriate test-functions, motivated by the fact that considered PDE allows a natural generalization of the classical Kullback entropy. Finally, a special care was given in obtaining an estimate of the mixed-derivative term by combining the information from the capillary pressure with the obtained a priori estimates on the saturation. 相似文献
1000.
Bojan Vučković 《Discrete Mathematics》2018,341(3):820-824
Let be a graph without isolated edges, and let be a coloring of the edges, where adjacent edges may be colored the same. The color code of a vertex is the ordered -tuple , where is the number of edges incident with that are colored . If every two adjacent vertices of have different color codes, such a coloring is called multi-set neighbor distinguishing. In this paper, we prove that three colors are sufficient to produce a multi-set neighbor distinguishing edge coloring for every graph without isolated edges. 相似文献