全文获取类型
收费全文 | 44366篇 |
免费 | 1594篇 |
国内免费 | 56篇 |
专业分类
化学 | 29319篇 |
晶体学 | 413篇 |
力学 | 812篇 |
数学 | 6553篇 |
物理学 | 8919篇 |
出版年
2023年 | 324篇 |
2022年 | 303篇 |
2021年 | 509篇 |
2020年 | 670篇 |
2019年 | 669篇 |
2018年 | 893篇 |
2017年 | 830篇 |
2016年 | 1574篇 |
2015年 | 1362篇 |
2014年 | 1378篇 |
2013年 | 2844篇 |
2012年 | 2869篇 |
2011年 | 3058篇 |
2010年 | 1875篇 |
2009年 | 1563篇 |
2008年 | 2559篇 |
2007年 | 2467篇 |
2006年 | 2259篇 |
2005年 | 1998篇 |
2004年 | 1672篇 |
2003年 | 1276篇 |
2002年 | 1191篇 |
2001年 | 885篇 |
2000年 | 830篇 |
1999年 | 606篇 |
1998年 | 482篇 |
1997年 | 394篇 |
1996年 | 529篇 |
1995年 | 390篇 |
1994年 | 392篇 |
1993年 | 404篇 |
1992年 | 371篇 |
1991年 | 291篇 |
1990年 | 292篇 |
1989年 | 247篇 |
1988年 | 246篇 |
1987年 | 227篇 |
1986年 | 221篇 |
1985年 | 326篇 |
1984年 | 298篇 |
1983年 | 226篇 |
1982年 | 220篇 |
1981年 | 218篇 |
1980年 | 189篇 |
1979年 | 215篇 |
1978年 | 208篇 |
1977年 | 203篇 |
1976年 | 222篇 |
1975年 | 195篇 |
1973年 | 192篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
941.
In the present paper we report the first experimental results on ac and dc conductivity and permittivity of adenine hemisulphate hydrate and adenine sulphate measured at atmospheric and high hydrostatic pressures. For both materials ac conductivity is of
s type, where:s 1·1· Room temperature dc conductivity of adenine hemisulphate hydrate equals approximately 5×10–15
–1 cm–1 with an activation energy of 0·86 eV; dc conductivity of adenine sulphate is less than 10–16 cm–1. On the basis of these measurements and those carried out at high pressure, it is concluded that conductivity of adenine hemisulphate hydrate is of electronic type.The authors wish to thank Dr. J. Zachová for the preparation of adenine salts single crystals. 相似文献
942.
The second order optical potential for thed system is derived in the framework of the Watson formalism and applied to the calculation of the 1s-state energy shift of the atom and thed scattering lengtha
d
. The results are in good agreement with those of the Faddeev type calculations.The authors wish to thank V. B. Belyaev, R. Mach, M. G. Sapozhnikov and R. A. Eramzhyan for stimulating discussions and helpful advice. 相似文献
943.
Expressing the influence of reservoirs (lattice modes, solvent etc.) on the exciton or electron propagation in homogeneous systems via two relaxation times in the Agranovich and Galanin model, the convolutionless Generalized Master Equations for the site occupation probabilities are derived. Two different projection operator techniques are used. Identity of the two approaches is verified for a dimer and physical contents of the result are discussed. 相似文献
944.
Elisângela Corradini Luís C. de Morais Nicole R. Demarquette José A. M. Agnelli Luiz H. C. Mattoso 《先进技术聚合物》2007,18(10):861-867
This work involved a study of the effect of processing variables (temperature, water content, rotor speed, and time) on the mechanical properties of starch:gluten:glycerol mixtures in the weight ratio of 40:40:20. The properties of the materials were affected by the processing variables. The torque decreased with water content, indicating that water facilitates the plasticization of mixtures, whereas the increase in temperature accelerated the evaporation of water, thus increasing the torque. Ultimate tensile strength was achieved at the lowest temperature (110°C) and the highest water content (20%), whereas maximum elongation was achieved for the material processed at the highest temperature, 150°C, and the fastest rotor speed, 70 rpm. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
945.
946.
L. Koester K. Knopf W. Waschkowski A. Klüver 《Zeitschrift für Physik A Hadrons and Nuclei》1985,320(4):661-668
Coherent neutron scattering lengths and total cross sections have been measured for elemental Zn,Zn-compounds and on isotopicly enriched samples for neutron energies from 0.5 meV up to 143 keV using different techniques. From the experimental data the following quantities were obtained: the coherent scattering lengths (b in fm) of Zn (5.689±0.014);64Zn (5.23±0.04);66Zn (5.98±0.05);67Zn (7.58±0.08;b +=9.4±0.5/5.8±0.5;b ?=5.0±0.7/10.1±0.7);68Zn (6.04 ±0.03); the potential scattering radii (R′ in fm) of Zn (6.2±0.2),64Zn (6.0±0.3) and66Zn (6.2 ±0.3); the absorption cross sections (σ γ at 0.025 eV in barn) of Zn (1.11±0.02);64Zn (1.1 ±0.1) and66Zn (0.62±0.06). Derived quantities are the “zero energy” scattering cross sections (σ 0 in barn) for Zn (4.128±0.010) and67Zn (7.8±0.3) and the incoherent bound cross sections of Zn (0.061 ±0.023) and67Zn (0.6±0.4). In the epithermal region the Zn-cross section can be described by introduction of two strong bound levels of67Zn+n for which estimated parameters are given. 相似文献
947.
We calculate the density of states for the nondegenerate Anderson model for various values ofu=U/ andn
f
using the perturbation theory withu as the expansion parameter. Summing all the -independent self-energy diagrams, we use the Friedel sum rule and Ward identities to express the physical quantities in terms of the remaining -dependent part of the self-energy, which we evaluate to the 2nd order. The results for the spin and charge susceptibilities obtained in such a way compare rather well with the Bethe-ansatz results. The density of states exhibits different features in different parts of the parameter space. In Kondo region (u>1,n
f
1, i.e., –
f
~U/2), we obtain a many-body resonance (half-width T
K
) around the Fermi level and two broad peaks () at about
f
+n
f
U and
f
+U. In the VF region (u>1, and |
f
|) we obtain only two peaks (), one at about
f
and one between
f
+n
f
U and
f
+U. The consequences regarding the shape of the photoemission and inverse photoemission spectra of Ce intermetallics are discussed. 相似文献
948.
Barral L. Cano J. López J. López-Bueno I. Nogueira P. Ramírez C. Abad M. J. 《Journal of Thermal Analysis and Calorimetry》1999,55(1):37-45
A study of an epoxy-cycloaliphatic amine system has been realized using a thermogravimetric technique (TG). Isothermal and
non-isothermal (dynamic) methods were employed to determine the kinetic data of this system.
Five methods were used for determining the activation energies of this system in the dynamic heating experiments. In two of
them (Flynn-Wall-Ozawa, and Kissinger) it is not necessary to have a prior knowledge of the reaction mechanism of the degradation
behaviour for this system. In the other ones (Coats and Redfern, Horowitz and Metzger, and Van Krevelen et al.) it is necessary
to know this reaction mechanism, besides Criado et al. method was used for determining it.
The results have shown that good agreement between the activation energies obtained from all methods can be achieved if it
is assumed that the degradation behaviour of this system is of sigmoidal-rate type.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
949.
Diffusion reflectance fourier transform infrared spectroscopy in the mid-IR region was used to assess the authenticity of tea varieties. The differences between the spectra of 12 different tea varieties (seven black, two green, three semifermented grades) were sufficient to allow their discrimination by the soft independent modelling of class analogy classification method or linear discriminant analysis, despite a significant heterogeneity of the samples as revealed by variance analysis. 相似文献
950.
Zusammenfassung Eine Reihe von Metallkomplexen des 2,5-Dibenzoyl-3,4-dihydroxy-selenophens wurden spektroskopisch untersucht. Das Verhalten des Wismutkomplexes und die Möglichkeiten einer spektrophotometrischen Wismutbestimmung auf diesem Wege wurden eingehend studiert.
Herrn Univ.-Prof. Dr.Hans Lieb zum 80. Geburtstag gewidmet. 相似文献
Summary A spectroscopic examination was made of a series of metal complexes of 2,5-dibenzoyl-3,4-dihydroxyselenophen. The behavior of the bismuth complex and the possibilities of a spectrophotometric method of determining bismuth in this manner were studied thoroughly.
Herrn Univ.-Prof. Dr.Hans Lieb zum 80. Geburtstag gewidmet. 相似文献