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141.
Berestetsky N Vaganova E Wachtel E Leitus G Goldberg A Yitzchaik S 《The journal of physical chemistry. B》2008,112(12):3662-3667
We describe a hydrogen-bonded poly(4-vinyl pyridine)-based dielectric material, in which conductivity can be induced due to the presence of side-chain protonated species that form spontaneously when the polymer is dissolved in pyridine. The conductivity of the proton conductive gel can be controlled by direct irradiation at the proton-transfer center: a reversible change of conductivity was observed in response to the on/off switching of 385 nm wavelength radiation. Over most of the range of intensities used, the proton conductivity exhibited a bimolecular character. We present a model of the protonated pyridine side-chain unit in the ground and excited states (DFT level). In the ground state, the protonated pyridine moiety has a cyclic, conjugated structure. 相似文献
142.
A relaxation dispersion pulse scheme is presented for quantifying chemical exchange processes in proteins that exploits 1H chemical shifts as probes of changes in conformation. The experiment selects 1H single-quantum magnetization from the I = 1/2 manifolds of the methyl group, which behave like AX spin systems, while suppressing coherences that derive from the 3/2 manifold that are extremely sensitive to pulse imperfections and that would otherwise severely compromise the accuracy of the experiment. The utility of the sequence is first demonstrated with an application to a protein system that is known not to undergo chemical exchange and flat dispersion profiles are obtained. Subsequently, the methodology is applied to study the folding of a G48M mutant of the Fyn SH3 domain that has been shown previously to undergo exchange between folded and unfolded states on the millisecond time scale. 相似文献
143.
In a strongly nonlinear viscous granular chain impacted by a single grain we observe a wave disturbance that consists of two parts exhibiting two time scales of dissipation. Above a critical viscosity there is no separation of the two pulses, and the dissipation and nonlinearity dominate the shocklike attenuating pulse. 相似文献
144.
Consider an operator T:C2(R)→C(R) and isotropic maps A1,A2:C1(R)→C(R) such that the functional equation
145.
Consider an operator T:C1(R)→C(R) satisfying the Leibniz rule functional equation
146.
Przemyslaw Dera Barbara Lavina Yue Meng Vitali B. Prakapenka 《Journal of solid state chemistry》2011,184(11):3040-3049
Synchrotron single-crystal x-ray diffraction experiments have been performed on corundum-type Cr2O3 up to a pressure of 55 GPa in Ne and He pressure transmitting media. Diffraction experiments were complemented by measurements of optical absorption spectra with single crystal samples up to 60 GPa. Results of the diffraction data analysis rule out the earlier reported monoclinic distortion at 15–30 GPa, but indicate evidence of two discontinuous transitions of electronic or magnetic nature, most likely associated with a change in magnetic ordering and charge transfer. The compression mechanism established from single crystal refinements indicates much smaller distortion of the Cr3+ coordination environment than was previously assumed. 相似文献
147.
V. I. Wachtel D. E. Denisov D. A. Korshunov 《Proceedings of the Steklov Institute of Mathematics》2013,282(1):273-297
As is well known, for a supercritical Galton-Watson process Z n whose offspring distribution has mean m > 1, the ratio W n := Z n /m n has almost surely a limit, say W. We study the tail behaviour of the distributions of W n and W in the case where Z 1 has a heavy-tailed distribution, that is, $\mathbb{E}e^{\lambda {\rm Z}_1 } = \infty $ for every λ > 0. We show how different types of distributions of Z 1 lead to different asymptotic behaviour of the tail of W n and W. We describe the most likely way in which large values of the process occur. 相似文献
148.
Xiao Hu Guillaume Guery Joshua Boerstler J. David Musgraves Don Vanderveer Peter Wachtel Kathleen Richardson 《Journal of Non》2012,358(5):952-958
Glass ceramic materials with composition 75TeO2–xBi2O3–(25-x)ZnO (x = 13, 12, 11) possessing transparency in the near- and mid-infrared (MIR) regions were studied in this paper. It was found that as the Bi2O3 content increased in the glass composition, the observed crystallization tendency is enhanced, and high crystal concentrations were obtained for the glasses with high Bi2O3 content while maintaining transparency in the MIR region. Crystal size in the glass ceramic was reduced by adjusting the heat treatment conditions; the smallest average size obtained in this study is 700 nm. Bi0.864Te0.136O1.568 was identified using X-ray Diffraction (XRD) and found to be the only crystal phase developed in the glass ceramics when the treatment temperature was fixed at 335 °C. The morphology of the crystals was studied using Scanning Electron Microscopy (SEM), and crystals were found to be polyhedral structures with uniform sizes and a narrow size distribution for a fixed heat treatment regime. Infrared absorption spectra of the resulting glass ceramics were studied. The glass ceramic retained transparency in the infrared region when the crystals inside were smaller than 1 μm, with an absorption coefficient less than 0.5/cm in the infrared region from 1.25 to 2.5 μm. The mechanical properties were also improved after crystallization; the Vickers Hardness value of the glass ceramic increased by 10% relative to the base glass. 相似文献
149.
Cavity optomechanics represents a flexible platform for the implementation of quantum technologies, useful in particular for the realization of quantum interfaces, quantum sensors and quantum information processing. However, the dispersive, radiation–pressure interaction between the mechanical and the electromagnetic modes is typically very weak, harnessing up to now the demonstration of interesting nonlinear dynamics and quantum control at the single photon level. It has already been shown both theoretically and experimentally that if the interaction is mediated by a Josephson circuit, one can have an effective dynamics corresponding to a huge enhancement of the single-photon optomechanical coupling. Here we analyze in detail this phenomenon in the general case when the cavity mode and the mechanical mode interact via an off-resonant qubit. Using a Schrieffer–Wolff approximation treatment, we determine the regime where this tripartite hybrid system behaves as an effective cavity optomechanical system in the strong coupling regime. 相似文献
150.
Hydrolysis of organotrifluoroborates to the corresponding organoboronic acids is readily achieved under either thermal or microwave conditions in the presence of alumina. The organoboronic acid products are obtained in good to excellent yields with essentially no loss of boronated reagent due to protoboronation. 相似文献