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891.
The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions. 相似文献
892.
Johansson Seechurn CC Kitching MO Colacot TJ Snieckus V 《Angewandte Chemie (International ed. in English)》2012,51(21):5062-5085
In 2010, Richard Heck, Ei-ichi Negishi, and Akira Suzuki joined the prestigious circle of Nobel Laureate chemists for their roles in discovering and developing highly practical methodologies for C-C bond construction. From their original contributions in the early 1970s the landscape of the strategies and methods of organic synthesis irreversibly changed for the modern chemist, both in academia and in industry. In this Review, we attempt to trace the historical origin of these powerful reactions, and outline the developments from the seminal discoveries leading to their eminent position as appreciated and applied today. 相似文献
893.
Antonio Galdámez Fernanda López-Vergara Patricia Barahona Victor Manríquez Ricardo E. ávila 《Journal of Solid State Electrochemistry》2012,16(2):697-702
The new solid solutions AgPbSb1 − x
Bi
x
S3 were prepared by solid state reactions. The phases were characterized by powder X-ray diffractions (XRD), scanning electron
microscopy, and thermal analysis. The XRD patterns of different members (x = 0.5, 0.7, 0.8, and 1.0) are consistent with pure phases crystallizing in the cubic PbS-type structure. The electrical characterization
was carried out using ac impedance spectroscopy and dc methods. The temperature dependence of the dc conductivity shows typical
semiconductor Arrhenius behavior. The impedance measurements were performed in the frequency range of 0.1 Hz to 10 MHz and
at the temperature range of 15 °C to 350 °C. The ac conductivity conforms to Jonscher’s universal power law. The frequency
dependence of the dielectric permittivity follows the normal dielectric material behavior, and the relaxation is thermally
activated. The frequency and temperature dependences of the electrical data are found to follow Summerfield scaling formalism. 相似文献
894.
Maté B Rodríguez-Lazcano Y Herrero VJ 《Physical chemistry chemical physics : PCCP》2012,14(30):10595-10602
An investigation of porosity and isothermal crystallization kinetics of amorphous ice produced either by background water vapour deposition (ASW) or by hyperquenching of liquid droplets (HGW) is presented. These two types of ice are relevant for astronomical ice research (Gálvez et al., Astrophys. J., 2010, 724, 539) and are studied here for the first time under comparable experimental conditions. From CH(4) isothermal adsorption experiments at 40 K, surface areas of 280 ± 30 m(2) g(-1) for the ASW deposits and of 40 ± 12 m(2) g(-1) for comparable HGW samples were obtained. The crystallization kinetics was studied at 150 K by following the evolution of the band shape of the OD stretching vibration in HDO doped ASW and HGW samples generated at 14 K, 40 K and 90 K. Comparable rate constants of ~7 × 10(-4) s(-1) were obtained in all cases. However a significant difference was found between the n Avrami parameter of the samples generated at 14 K (n~ 1) and that of the rest (n > 2). This result hints at the possible existence of a structurally different form of amorphous ice for very low generation temperatures, already suggested in previous literature works. 相似文献
895.
Development of a selective chemical etch to improve the conversion efficiency of Zn-rich Cu2ZnSnS4 solar cells 总被引:2,自引:0,他引:2
Fairbrother A García-Hemme E Izquierdo-Roca V Fontané X Pulgarín-Agudelo FA Vigil-Galán O Pérez-Rodríguez A Saucedo E 《Journal of the American Chemical Society》2012,134(19):8018-8021
Improvement of the efficiency of Cu(2)ZnSnS(4) (CZTS)-based solar cells requires the development of specific procedures to remove or avoid the formation of detrimental secondary phases. The presence of these phases is favored by the Zn-rich and Cu-poor conditions that are required to obtain device-grade layers. We have developed a selective chemical etching process based on the use of hydrochloric acid solutions to remove Zn-rich secondary phases from the CZTS film surface, which are partly responsible for the deterioration of the series resistance of the cells and, as a consequence, the conversion efficiency. Using this approach, we have obtained CZTS-based devices with 5.2% efficiency, which is nearly twice that of the devices we have prepared without this etching process. 相似文献
896.
X Kong LA O'Dell V Terskikh E Ye R Wang G Wu 《Journal of the American Chemical Society》2012,134(35):14609-14617
We report a comprehensive variable-temperature solid-state (17)O NMR study of three (17)O-labeled crystalline sulfonic acids: 2-aminoethane-1-sulfonic acid (taurine, T), 3-aminopropane-1-sulfonic acid (homotaurine, HT), and 4-aminobutane-1-sulfonic acid (ABSA). In the solid state, all three compounds exist as zwitterionic structures, NH(3)(+)-R-SO(3)(-), in which the SO(3)(-) group is involved in various degrees of O···H-N hydrogen bonding. High-quality (17)O NMR spectra have been obtained for all three compounds under both static and magic angle spinning (MAS) conditions at 21.1 T, allowing the complete set of (17)O NMR tensor parameters to be measured. Assignment of the observed (17)O NMR parameters to the correct oxygen sites in the crystal lattice was achieved with the aid of DFT calculations. By modeling the temperature dependence of (17)O NMR powder line shapes, we have not only confirmed that the SO(3)(-) groups in these compounds undergo a 3-fold rotational jump mechanism but also extracted the corresponding jump rates (10(2)-10(5) s(-1)) and the associated activation energies (E(a)) for this process (E(a) = 48 ± 7, 42 ± 3, and 45 ± 1 kJ mol(-1) for T, HT, and ABSA, respectively). This is the first time that SO(3)(-) rotational dynamics have been directly probed by solid-state (17)O NMR. Using the experimental activation energies for SO(3)(-) rotation, we were able to evaluate quantitatively the total hydrogen bond energy that each SO(3)(-) group is involved in within the crystal lattice. The activation energies also correlate with calculated rotational energy barriers. This work provides a clear illustration of the utility of solid-state (17)O NMR in quantifying dynamic processes occurring in organic solids. Similar studies applied to selectively (17)O-labeled biomolecules would appear to be very feasible. 相似文献
897.
898.
Anthony K. Amert Victor V. Gozhenko Keith W. Whites 《Applied Physics A: Materials Science & Processing》2012,109(4):1007-1013
The Pendry et?al. field averaging method for calculation of effective material parameters is reviewed and its limits explored. The method is then extended so that it can accurately calculate the effective material parameters of lattices where the unit cell size is appreciable but still quasistatic (d??0.1?? 0). The new algorithm is verified by calculating the effective material properties of periodically placed particles suspended in free space, as the unit cell size becomes appreciable. Results of our proposed formulation are then compared with the Pendry et?al. and conventional volumetric averaging algorithms. 相似文献
899.
We develop a hybrid Monte Carlo approach for modelling nematic liquid crystals of homopolymer melts. The polymer architecture is described with a discrete worm-like chain model. A quadratic density functional accounts for the limited compressibility of the liquid, while an additional quadratic functional of the local orientation tensor of the segments captures the nematic ordering. The approach can efficiently address large systems parametrized according to volumetric and conformational properties, representative of real polymeric materials. The results of the simulations regarding the influence of the molecular weight on the isotropic-nematic transition are compared to predictions from a Landau-de Gennes free energy expansion. The formation of the nematic phase is addressed within Rouse-like dynamics, realized using the current model. 相似文献
900.
E Haussühl J Schreuer B Winkler S Haussühl L Bayarjargal V Milman 《J Phys Condens Matter》2012,24(34):345402
Structure-property relations of monoclinic petalite, LiAlSi(4)O(10), were determined by experiment and atomistic modeling based on density functional theory. The elastic stiffness coefficients were measured between room temperature and 570?K using a combination of the plate-resonance technique and resonant ultrasound spectroscopy. The thermal expansion was studied between 100 and 740?K by means of dilatometry. The heat capacity between 2 and 398?K has been obtained by microcalorimetry using a quasi-adiabatic calorimeter. The experimentally determined elastic stiffness coefficients were employed to benchmark the results of density functional theory based model calculations. The values in the two data sets agreed to within a few GPa and the anisotropy was very well reproduced. The atomistic model was then employed to predict electric field gradients, the lattice dynamics and thermodynamic properties. The theoretical charge density was analyzed to investigate the bonding between atoms. 相似文献