Reversible core-interconversion of an iron(III) dihydroxo bridged complex

Complexes [Fe(Hhbi)(2)(NO(3))].2EtOH (1.2EtOH) and [Fe(2)(mu-OH)(2)(Hhbi)(4)].2H(2)O.8EtOH (2.2H(2)O.8EtOH) crystallize in the orthorhombic Fdd2 and P4(2)2(1)2 space groups, respectively (Hhbi(-) = the monoanion of 2-(2'-hydroxyphenyl benzimidazole). Complex 1 exhibits paramagnetic relaxation as evidenced by Mossbauer spectroscopy, and significant axial zero-field splitting (1.5 cm(1) 相似文献   

Slow magnetic relaxation of a ferromagnetic Ni(II)5 cluster with an S = 5 ground state

Complex [Ni 5{pyCOpyC(O)(OMe)py} 2(O 2CMe) 4(N 3) 4(MeOH) 2].2MeOH.2.6H 2O ( 1.2MeOH.2.6H 2O) was synthesized by the reaction of Ni(O 2CMe) 2.4H 2O with pyCOpyCOpy and NaN 3 in refluxing MeOH. It crystallizes in the monoclinic C2/ c space group and consists of five Ni (II) atoms in a helical arrangement. Direct current magnetic susceptibility studies reveal ferromagnetic interactions between the Ni (II) ( S = 1) ions, stabilizing an S = 5 ground state. Alternating current susceptibility experiments revealed the existence of out-of-phase signals indicative of slow magnetic relaxation. Analysis of the signals showed that they are composite, suggesting more than one relaxation process, while analysis of their magnitudes suggests not all molecules undergo slow magnetic relaxation. Magnetization field-sweep experiments revealed hysteresis at 1.8 K, and magnetization decay experiments clearly verified the appearance of slow magnetic relaxation at that temperature.     

Calculation of Electromagnetic Scattering from a Pruppacher-Pitter Raindrop Using M.A.S. and Slant Path Rain AttenuationPrediction

The combined effects of hydrometeor scattering and absorption result in significant power loss, for Earth-space microwave links operating at frequencies above 10GHz. With the increasing deployment of higher frequencies in commercial wireless networks, the accurate estimation of the specific rain attenuation is very significant for the reliable design of a radio communication system. In the present paper, the scattering of a plane electromagnetic wave from a Pruppacher-Pitter raindrop is treated using the Method of Auxiliary Sources (MAS). The obtained data are compared with those taken from the open literature -in the form of real and imaginary part of the forward scattering amplitude - with excellent results. Then, they are used for the numerical calculation of both the specific rain attenuation and the exceedance probability function, in the case of a hypothetical satellite link located in various climatic regions. The comparison with other models against experimental data has given very encouragingresults.     

Activation de la Ponction Hydroxyle Anomere via les Sels d'Iminium. O-Glycosylation des Tri-O-benzyl-2,3,5-D-arabino et -ribotorannoses

Abstract

The glycosylation reaction based upon anomeric free hydroxyl group activation by its transformation into an alkcxyiminium salt by the action of the N,N-dimethylformamide/phosgene complex has been extended to the pentofuranose series. The mechanism of this glycosylation is discussed. Nine glycosides have been prepared.     

Comparative analysis of ancient ceramics by neutron activation analysis,inductively coupled plasma-optical-emission spectrometry,inductively coupled plasma-mass spectrometry,and X-ray fluorescence

The accurate measurement of the maximum possible number of elements in ancient ceramic samples is the main requirement in provenance studies. For this reason neutron activation analysis (NAA) and X-ray fluorescence (XRF) have been successfully used for most of the studies. In this work the analytical performance of inductively coupled plasma-optical-emission spectrometry (ICP-OES) and inductively coupled plasma-mass spectrometry (ICP-MS) has been compared with that of XRF and NAA for the chemical characterization of archaeological pottery. Correlation coefficients between ICP techniques and XRF or NAA data were generally better than 0.90. The reproducibility of data calculated on a sample prepared and analysed independently ten times was approximately 5% for most of the elements. Results from the ICP techniques were finally evaluated for their capacity to identify the same compositional pottery groups as results from XRF and NAA analysis, by use of multivariate statistics.     

On the Hardness of the Quadratic Assignment Problem with Metaheuristics

Meta-heuristics are a powerful way to approximately solve hard combinatorial optimization problems. However, for a problem, the quality of results can vary considerably from one instance to another. Understanding such a behaviour is important from a theoretical point of view, but also has practical applications such as for the generation of instances during the evaluation stage of a heuristic.In this paper we propose a new complexity measure for the Quadratic Assignment Problem in the context of metaheuristics based on local search, e.g. simulated annealing. We show how the ruggedness coefficient previously introduced by the authors, in conjunction with the well known concept of dominance, provides important features of the search space explored during a local search algorithm, and gives a rather precise idea of the complexity of an instance for these heuristics. We comment previous experimental studies concerning tabu search methods and genetic algorithms with local search in the light of our complexity measure. New computational results with simulated annealing and taboo search are presented.     

Expanding the 3d-4f heterometallic chemistry of the (py)2CO and pyCOpyCOpy ligands: structural, magnetic and Mössbauer spectroscopic studies of two Fe(II)-Gd(III) complexes

Complex [Fe(II)Gd(III){pyCO(OEt)pyCOH(OEt)py}(3)](ClO(4))(2) (1) crystallizes in the Cc space group and contains one hexacoordinate ferrous ion and one enneacoordinate Gd(III) ion. Complex [Fe(2)(II)Gd(III){pyCO(OEt)py}(4)(NO(3))(H(2)O)][Gd(NO(3))(5)](0.5)(ClO(4)) (2) crystallizes in the C2/c space group and contains two hexacoordinate ferrous ions and one octacoordinate Gd(III) ion. Both complexes have been prepared by the metal-assisted ethanolysis of ligands di-2,6-(2-pyridylcarbonyl)pyridine (pyCOpyCOpy, dpcp) and di-2-pyridyl ketone ((py)(2)CO, dpk), which exhibit similar structures. M?ssbauer spectroscopic studies of 2 revealed the presence of two quadrupole-split doublets of equal intensities, each assigned to a ferrous site. These doublets exhibit similar isomer shifts (δ(1) = 1.14 mm s(-1), δ(2) = 1.11 mm s(-1)) but quite different quadrupole splittings (ΔE(Q1) = 3.55 mm s(-1), ΔE(Q2) = 2.74 mm s(-1)). Magnetic studies revealed weak ferromagnetic Fe(II)-Gd(III) interactions for both complexes (J(FeGd) = +0.68 cm(-1), D(Fe) = 12.0 cm(-1) for 1 and J(FeGd) = +0.03 cm(-1), J(FeFe) = -1.73 cm(-1) for 2, according to the -JS(i)S(j) spin-Hamiltonian formalism).     

Special issue on global flow instability and control

This special issue is intended to provide a snapshot of current research in the area of ??Global Flow Instability and Control??. The original papers, and to a certain extent the topic itself, are intimately linked with the series of symposia by the same name that were held in Crete, Greece, between 2001 and 2009. As members of the organizing committees of the Crete symposia, we invited all past participants to contribute, and all papers were reviewed following the strict standards of the journal. This preface gives a brief historical account of events that have shaped ideas in the field over the past decade, followed by a synopsis of the papers published herein.     

An example where separation of variables fails

We present in detail a linear, constant-coefficient initial/boundary value problem for which the classical method of eigenfunction expansions fails. We note that the new method recently introduced by A. Fokas and B. Pelloni (2005) in [3] can be successfully applied to the same problem.     

Finite order spreading models

Extending the classical notion of spreading model, the k$k$-spreading models of a Banach space are introduced, for every k∈N$k\in \mathbb{N}$. The definition, which is based on the k$k$-sequences and plegma families, reveals a new class of spreading sequences associated to a Banach space. Most of the results of the classical theory are stated and proved in the higher order setting. Moreover, new phenomena like the universality of the class of the 2-spreading models of _c0$c_0$ and the composition property are established. As consequence, a problem concerning the structure of the k$k$-iterated spreading models is solved.