Kinetics and mechanism of osmium(VIII) catalyzed oxidation of tellurium(IV) by cerium(IV)

The reaction is first order in substrate and catalyst and zero order in cerium(IV). The rate decreases with increasing [H⁺] as well as with increasing ionic strength. H and S have been found to be 44.8 kJ mol^–1 and 161.8 JK^–1 mol^–1 respectively. A mechanism is proposed.

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(IV). [H⁺], . , H S 44,8 ·^–1 161,8 ·^–1–1, . .

     

Design,Synthesis, Antimicrobial,and Antioxidant Activity of Dimers of Chromene Containing 1,2,3-Triazole Derivatives Bearing an Alkyl Spacer

A new series of chromene based 1,2,3-triazole derivatives has been synthesized by incorporating biologically active heterocyclic rings containing chromene and triazole moieties in one molecular structure. All newly synthesized compounds are characterized by ¹H and ¹³C NMR, mass, and IR spectra. The title compounds are tested for their activity against different bacterial and fungal strains, and antioxidant activity. Several compounds are determined to be potent antimicrobial and antioxidant agents.

     

Scattering of light by a periodic structure in the presence of randomness VII: Application of statistical detection test

Detection of periodic structures, hidden in random surfaces has been addressed by us for some time and the ‘extended matched filter’ method, developed by us, has been shown to be effective in detecting the hidden periodic part from the light scattering data in circumstances where conventional data analysis methods cannot reveal the successive peaks due to scattering by the periodic part of the surface. It has been shown that if r ₀ is the coherence length of light on scattering from the rough part and Λ is the wavelength of the periodic part of the surface, the extended matched filter method can detect hidden periodic structures for (r ₀/Λ) ≥ 0.11, while conventional methods are limited to much higher values ((r ₀/Λ) ≥ 0.33). In the method developed till now, the detection of periodic structures involves the detection of the central peak, first peak and second peak in the scattered intensity of light, located at scattering wave vectors v _x = 0, Q, 2Q, respectively, where Q = 2Gp/Λ, their distinct identities being obfuscated by the fact that the peaks have width Δv _x = 2Gp/r ₀ ≫ Q. The relative magnitudes of these peaks and the consequent problems associated in identifying them is discussed. The Kolmogorov-Smirnov statistical goodness test is used to justify the identification of the peaks. This test is used to ‘reject’ or ‘not reject’ the null hypothesis which states that the successive peaks do exist. This test is repeated for various values of r ₀/Λ, which leads to the conclusion that there is really a periodic structure hidden behind the random surface.      

Synthesis and Antimicrobial Activity of Linked Heterocyclics Containing Pyrazole and Oxadiazoles

A new series of 3‐(arylaminomethyl)‐5‐(5‐methyl‐1‐phenyl‐1H‐4‐pyrazolyl)‐2,3‐dihydro‐1,3,4‐oxadiazole‐2‐thiones 6a , 6b , 6c , 6d , 6e , 6f , 6g , 6h , 6i , 6j has been synthesized by the reaction of 5‐(5‐methyl‐1‐phenyl‐1H‐4‐pyrazolyl)‐1,3,4‐oxadiazol‐2‐ylhydrosulfide 5 with formaldehyde and corresponding anilines. The chemical structures of newly synthesized compounds were elucidated by IR, ¹H, ¹³C‐NMR, MS, and elemental analyses. The compounds 6a , 6b , 6c , 6d , 6e , 6f , 6g , 6h , 6i , 6j were evaluated for their antibacterial activity against three representative Gram positive bacteria viz. Bacillus subtilis (MTCC 441), Bacillus sphaericus (MTCC 11) and Staphylococcus aureus (MTCC 96), and three Gram negative bacteria viz. Pseudomonas aeruginosa (MTCC 741), Klobsinella aerogenes (MTCC 39) and Chromobacterium violaceum. Among the screened 6b , 6d , 6i , and 6j in which oxadiazole moiety bearing 4‐fluoroanilinomethyl, 4‐chloroanilinomethyl, 2‐trifluoromethylanilinomethyl, and 2,5‐difluoroanilinomethyl groups, respectively, showed high activity against all the microorganisms used. In addition these compounds were also screened for their antifungal activity against four fungal organisms viz. Candida albicans (ATCC 10231), Aspergillus fumigatus (HIC 6094), Trichophyton rubrum (IFO 9185), and Trichophyton mentagrophytes (IFO 40996). Most of these new compounds showed appreciable activity against test fungi, and emerged as potential molecules for further development.     

Search for the effect of pressure on liquid-liquid critical phenomena

The coexistence curve of methanol + cyclohexane has been reanalyzed using an intrinsically simpler equation to study the influence of pressure on its asymmetry. The results confirm that no pressure dependence is discernible in the coexistence curve. Suggestions for future work in this direction are made.