全文获取类型
收费全文 | 1449篇 |
免费 | 27篇 |
国内免费 | 6篇 |
专业分类
化学 | 879篇 |
晶体学 | 34篇 |
力学 | 86篇 |
数学 | 144篇 |
物理学 | 339篇 |
出版年
2024年 | 2篇 |
2023年 | 9篇 |
2022年 | 29篇 |
2021年 | 33篇 |
2020年 | 24篇 |
2019年 | 43篇 |
2018年 | 47篇 |
2017年 | 41篇 |
2016年 | 57篇 |
2015年 | 34篇 |
2014年 | 45篇 |
2013年 | 100篇 |
2012年 | 75篇 |
2011年 | 104篇 |
2010年 | 80篇 |
2009年 | 60篇 |
2008年 | 84篇 |
2007年 | 78篇 |
2006年 | 93篇 |
2005年 | 80篇 |
2004年 | 71篇 |
2003年 | 43篇 |
2002年 | 44篇 |
2001年 | 18篇 |
2000年 | 28篇 |
1999年 | 13篇 |
1998年 | 23篇 |
1997年 | 27篇 |
1996年 | 14篇 |
1995年 | 4篇 |
1994年 | 10篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1983年 | 3篇 |
1982年 | 12篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 6篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1970年 | 3篇 |
1963年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有1482条查询结果,搜索用时 62 毫秒
11.
N. N. Koval’ Yu. F. Ivanov I. M. Goncharenko O. V. Krysina Yu. A. Kolubaeva K. A. Koshkin 《Russian Physics Journal》2007,50(2):146-152
Phase composition, defect substructure, and mechanical properties of the Ti-Si-N coating deposited on metal and ceramic-metal substrates by electroarc sputtering of the Ti-Si composite cathode in an ionized
nitrogen atmosphere are investigated by the methods of modern materials science. It is established that coatings so formed
with a thickness of ∼1–3 μm are superhard (Hv ∼ 50 GPa), and have the nanocrystalline structure (with crystalline sizes D = 7 nm) based on titanium nitride δ-TiN.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 46–51, February, 2007. 相似文献
12.
13.
Characterization of spherical particles using high-order neural networks and scanning flow cytometry
Vladimir V. Berdnik Alexander Shvalov Valeri Maltsev Valery A. Loiko 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,102(1):62-72
We retrieve the radius R, real n and imaginary k parts of the refractive index of homogeneous spherical particles using angular distribution of the light-scattering intensity. To solve the inverse light-scattering problem we use a high-order neural-network technique. The effect of network parameters on optimization is examined. The technique is evaluated for noise-corrupted input data at 0.6 μm<R<10.6 μm, 1.02<n<1.38, and 0<k<0.03. The errors of retrieval for nonabsorbing particles do not exceed 0.05 μm for radius and 0.015 for refractive index. The experimental verification is fulfilled by experimental data retrieved by means of a scanning flow cytometer. The light-scattering profiles of polystyrene beads and spherized red blood cells are processed with the high-order neural networks and a non-linear regression at Mie theory. The parameters retrieved by the high-order neural networks correlate well with the parameters retrieved by the least-square method. 相似文献
14.
Yi Liu David D. Díaz Adrian A. Accurso K. Barry Sharpless Valery V. Fokin M. G. Finn 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5182-5189
1,2,3‐Triazole‐based polymers generated from the Cu(I)‐catalyzed cycloaddition between multivalent azides and acetylenes are effective adhesive materials for metal surfaces. The adhesive capacities of candidate mixtures of azide and alkyne components were measured by a modified peel test, using a customized adhesive tester. A particularly effective tetravalent alkyne and trivalent azide combination was identified, giving exceptional strength that matches or exceeds the best commercial formulations. The addition of Cu catalyst was found to be important for the synthesis of stronger adhesive polymers when cured at room temperature. Heating also accelerated curing rates, but the maximum adhesive strengths achieved at both room temperature and high temperature were the same, suggesting that crosslinking reaches the same advanced point in all cases. Polytriazoles also form adhesives to aluminum, but copper is bound more effectively, presumably because active Cu(I) ions may be leached from the surface to promote crosslinking and adhesion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5182–5189, 2007 相似文献
15.
On the basis of critical comparison of experimental and theoretical values of the E parameter and investigation of the retardation effect of oxygen on the evaporation rate of ZnO, CdO and HgO, it was concluded that the dissociative evaporation of ZnO and HgO proceeds with releasing of atomic oxygen (O) as a primary product of decomposition. By contrast, the mechanism of dissociative evaporation of CdO corresponds to the equilibrium reaction with releasing of molecular oxygen (O2) as a primary product of decomposition. As was shown, this difference in mechanisms is not related with interatomic OO distances in these oxides. From the analysis of crystal structure for 12 different oxides, which evaporate with releasing of atomic oxygen, and for 13 compounds, which evaporate with releasing of molecular oxygen, it was revealed that the first mechanism is observed for all oxides with the cubic crystal structure. It was proposed that a decisive role in this difference belongs to a local symmetry in the position of O atoms. 相似文献
16.
Valery A. Khoze Torbjörn Sjöstrand 《Zeitschrift fur Physik C Particles and Fields》1996,70(4):625-635
The process ${? e}^{+}{? e}^{-}?ghtarrow {? W}^{+}{? W}^{-}?ghtarrow {? f}_{1}{?erline {? f}}_{2}{? f}_{3}{?erline {? f}}_{4}$ contains charges in the initial, intermediate and final stages. This gives a rich selection of possible QED interconnection effects. Coulomb interaction is the simplest of these, and can thus be used to explore consequences. We study a number of experimental observables, with emphasis on those related to the W momentum distribution. Second-order Coulomb effects are shown to be practically negligible. The limited LEP 2 statistics will not allow detailed tests, so any theory uncertainty will be reflected in the systematic error on the W mass. Currently the uncertainty from this source may be as high as 20 MeV. 相似文献
17.
V. T. Kalinnikov Zh. A. Ezhova N. A. Zakharov E. M. Koval’ 《Russian Journal of Inorganic Chemistry》2007,52(1):112-115
The CaCl2-(NH4)2HPO4-NH2(CH2)4NH2CHCOOH-NH3-H2O system at 25°C is studied using Tananaev’s solubility (residual concentrations) method and pH measurements. Lysine-containing calcium hydroxylapatite Ca10(PO4)6(OH)1.9[NH2(CH2)4NH2CHCOO]0.1 · 6H2O is identified using chemical analysis, thermogravimetry, powder X-ray diffraction, and IR spectroscopy. 相似文献
18.
19.
20.
Alexei Yu. Lukin Sergei V. Shevyakov Alexei V. Laptev Olga I. Davydova Vitali I. Shvets Olga V. Demina Yury P. Strokach Valery A. Barachevsky Michail V. Alfimov Sergei P. Gromov Artem I. Vedernikov Johan Lugtenburg Andrey A. Khodonov 《Journal of inclusion phenomena and macrocyclic chemistry》2004,49(1-2):153-161
An effective synthetic approach to the preparation of a new crown-ether vinylogs involving the Horner–Emmons olefination of carbonyl precursors with the use of C2- and C5-phosphonates was proposed. The effects of the conjugation chain length and the nature of the terminal polar functions in the phosphonate reagent on the yield and process stereoselectivity were discussed. 相似文献