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41.
The determination of lanthanides by Inductively Coupled Plasma Mass Spectrometry (ICP‐MS) is complicated by several spectral overlaps from M+, MO+ or MOH+ ions formed in the ICP. Especially, it is essential to avoid the spectral interferences from lighter lanthanide and Ba polyatomic ions on middle or heavier lanthanides. To tackle this problem, we have developed a mathematical correction method, which reduces all the spectral overlaps from oxide species of Pr, Nd, Ce and Sm over Gd, Tb, Dy and Ho, and Gd, Tb over Yb and Lu. It can also successfully correct the oxide and hydroxide interference of Ba over Eu. The effectiveness of the proposed the mathematical correction scheme is demonstrated for the USGS Standard Rock samples AGV‐1 and G‐2. The results show that the experimental data obtained by applying the mathematical correction scheme for lanthanides is in good agreement with the reported values, using pneumatic and ultrasonic nebulisation methods, for their ICP‐MS analysis. 相似文献
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The kick-out model for impurity diffusion in semiconductors is studied. The kick-out mechanism is thought to play an important rôle in a number of applications, including the diffusion of zinc and chromium in gallium arsenide. Asymptotic solutions are derived for both one- and two-dimensional surface source problems. In the one-dimensional case, a mechanism for the destruction of self-interstitials is also incorporated. The calculated diffusion profiles have shapes which are typical of diffusion systems in which the kick-out mechanism is believed to be active. For the two-dimensional problem, contours of constant impurity concentration are calculated and some are found to have the bird's beak shape which is frequently observed in experiments. 相似文献
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Demonstration of a fundamental quantum logic gate 总被引:1,自引:0,他引:1
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McFarland KS Naples D Arroyo CG Auchincloss P de Barbaro P Bazarko AO Bernstein RH Bodek A Bolton T Budd H Conrad J Drucker RB Harris DA Johnson RA Kim JH King BJ Kinnel T Koizumi G Koutsoliotas S Lamm MJ Lefmann WC Marsh W McNulty C Mishra SR Nienaber P Nussbaum M Oreglia MJ Perera L Quintas PZ Romosan A Sakumoto WK Schumm BA Sciulli FJ Seligman WG Shaevitz MH Smith WH Spentzouris P Steiner R Stern EG Vakili M Yang UK 《Physical review letters》1995,75(22):3993-3996
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Arroyo CG King BJ Bachmann KT Bazarko AO Bolton T Foudas C Lefmann WC Leung WC Mishra SR Oltman E Quintas PZ Rabinowitz SA Sciulli FJ Seligman WG Shaevitz MH Merritt FS Oreglia MJ Schumm BA Bernstein RH Borcherding F Fisk HE Lamm MJ Marsh W Merritt KW Schellman HM Yovanovitch DD Bodek A Budd HS de Barbaro P Sakumoto WK Kinnel T Sandler PH Smith WH 《Physical review letters》1994,72(22):3452-3455
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Density functional theory (DFT) at the hybrid B3LYP level has been applied to the germanium clusters Ge(9)(z) clusters (z = -6, -4, -3, -2, 0, +2, and +4) starting from three different initial configurations. Double-zeta quality LANL2DZ basis functions extended by adding one set of polarization (d) and one set of diffuse (p) functions were used. The global minimum for Ge(9)(2)(-) is the tricapped trigonal prism expected by Wade's rules for a 2n + 2 skeletal electron structure. An elongated tricapped trigonal prism is the global minimum for Ge(9)(4)(-) similar to the experimentally found structure for the isoelectronic Bi(9)(5+). However, the capped square antiprism predicted by Wade's rules for a 2n + 4 skeletal electron structure is only 0.21 kcal/mol above this global minimum indicating that these two nine-vertex polyhedra have very similar energies in this system. Tricapped trigonal prismatic structures are found for both singlet and triplet Ge(9)(6)(-), with the latter being lower in energy by 3.66 kcal/mol and far less distorted. The global minimum for the hypoelectronic Ge(9) is a bicapped pentagonal bipyramid. However, a second structure for Ge(9) only 4.54 kcal/mol above this global minimum is the C(2)(v)() flattened tricapped trigonal prism structure found experimentally for the isoelectronic Tl(9)(9)(-). For the even more hypoelectronic Ge(9)(2+), the lowest energy structure consists of an octahedron fused to two trigonal bipyramids. For Ge(9)(4+), the global minimum is an oblate (squashed) pentagonal bipyramid with two pendant Ge vertices. 相似文献