全文获取类型
收费全文 | 1139篇 |
免费 | 60篇 |
国内免费 | 19篇 |
专业分类
化学 | 703篇 |
晶体学 | 3篇 |
力学 | 14篇 |
数学 | 216篇 |
物理学 | 282篇 |
出版年
2023年 | 6篇 |
2022年 | 17篇 |
2021年 | 30篇 |
2020年 | 40篇 |
2019年 | 35篇 |
2018年 | 24篇 |
2017年 | 23篇 |
2016年 | 56篇 |
2015年 | 46篇 |
2014年 | 41篇 |
2013年 | 77篇 |
2012年 | 80篇 |
2011年 | 77篇 |
2010年 | 58篇 |
2009年 | 39篇 |
2008年 | 50篇 |
2007年 | 56篇 |
2006年 | 53篇 |
2005年 | 65篇 |
2004年 | 39篇 |
2003年 | 31篇 |
2002年 | 35篇 |
2001年 | 32篇 |
2000年 | 21篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 10篇 |
1992年 | 5篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1987年 | 4篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 11篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 8篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1970年 | 2篇 |
1967年 | 2篇 |
1915年 | 2篇 |
排序方式: 共有1218条查询结果,搜索用时 17 毫秒
111.
Let f be an L 2-normalized weight zero Hecke-Maaß cusp form of square-free level N, character χ and Laplacian eigenvalue λ≥1/4. It is shown that ‖f‖∞? λ N ?1/37, from which the hybrid bound ‖f‖∞?λ 1/4(N λ)?δ (for some δ>0) is derived. The first bound holds also for f=y k/2 F where F is a holomorphic cusp form of weight k with the implied constant now depending on k. 相似文献
112.
113.
Pavel Exner Takashi Ichinose Hagen Neidhardt Valentin A. Zagrebnov 《Integral Equations and Operator Theory》2007,57(1):67-81
We introduce a new product formula which combines an orthogonal projection with a complex function of a non-negative operator.
Under certain assumptions on the complex function the strong convergence of the product formula is shown. Under more restrictive
assumptions even operator-norm convergence is verified. The mentioned formula can be used to describe Zeno dynamics in the
situation when the usual non-decay measurement is replaced by a particular generalized observables in the sense of Davies. 相似文献
114.
Valentin Ferenczi 《Advances in Mathematics》2005,195(1):259-282
We show that any Banach space contains a continuum of non-isomorphic subspaces or a minimal subspace. We define an ergodic Banach space X as a space such that E0 Borel reduces to isomorphism on the set of subspaces of X, and show that every Banach space is either ergodic or contains a subspace with an unconditional basis which is complementably universal for the family of its block-subspaces. We also use our methods to get uniformity results. We show that an unconditional basis of a Banach space, of which every block-subspace is complemented, must be asymptotically c0 or ?p, and we deduce some new characterisations of the classical spaces c0 and ?p. 相似文献
115.
Efficient passively Q-switched laser operation of the disordered Yb:NaGd(WO(4))(2) crystal is demonstrated for the first time to our knowledge with a Cr(4+):YAG saturable absorber by diode end pumping. 2.05 W of average output power at a pulse repetition frequency of 13.3 kHz was obtained at an absorbed pump power of 7.7 W, with a slope efficiency of 40%. The energy and duration of the generated laser pulse were 154 microJ and 33 ns, respectively, corresponding to a peak power of 4.67 kW. In continuous-wave operation, the Yb:NaGd(WO(4))(2) laser yielded an output power of 5.5 W with an optical-optical efficiency of 51%. 相似文献
116.
We suggest a new method for studying finite dimensional dynamics for evolutionary differential equations. We illustrate this
method for the case of the KdV equation. As a side result we give constructive solutions of the boundary problem for the Schrodinger
equations whose potentials are solutions of stationary KdV equations and their higher generalizations. 相似文献
117.
Novel Mechanism of Bioluminescence: Oxidative Decarboxylation of a Moiety Adjacent to the Light Emitter of Fridericia Luciferin
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Maxim A. Dubinnyi Zinaida M. Kaskova Natalja S. Rodionova Mikhail S. Baranov Andrey Yu. Gorokhovatsky Alexey Kotlobay Kyril M. Solntsev Aleksandra S. Tsarkova Valentin N. Petushkov Ilia V. Yampolsky 《Angewandte Chemie (International ed. in English)》2015,54(24):7065-7067
A novel luciferin from a bioluminescent Siberian earthworm Fridericia heliota was recently described. In this study, the Fridericia oxyluciferin was isolated and its structure elucidated. The results provide insight into a novel bioluminescence mechanism in nature. Oxidative decarboxylation of a lysine fragment of the luciferin supplies energy for light generation, while a fluorescent CompX moiety remains intact and serves as the light emitter. 相似文献
118.
Boron‐Containing Polycyclic Aromatic Hydrocarbons: Facile Synthesis of Stable,Redox‐Active Luminophores
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
M. Sc. Valentin M. Hertz Dr. Michael Bolte Dr. Hans‐Wolfram Lerner Prof. Dr. Matthias Wagner 《Angewandte Chemie (International ed. in English)》2015,54(30):8800-8804
Herein we show that replacing the two meso carbon atoms of the polycyclic aromatic hydrocarbon (PAH) bisanthene by boron atoms transforms a near‐infrared dye into an efficient blue luminophore. This observation impressively illustrates the impact of boron doping on the frontier orbitals of PAHs. To take full advantage of this tool for the targeted design of organic electronic materials, the underlying structure–property relationships need to be further elucidated. We therefore developed a modular synthesis sequence based on a Peterson olefination, a stilbene‐type photocyclization, and an Si–B exchange reaction to substantially broaden the palette of accessible polycyclic aromatic organoboranes and to permit a direct comparison with their PAH congeners. 相似文献
119.
Yury D. Fomin Elena N. Tsiok Valentin N. Ryzhov 《Journal of computational chemistry》2015,36(12):901-906
We present the molecular dynamics study of benzene molecules confined into the single wall carbon nanotube. The local structure and orientational ordering of benzene molecules are investigated. It is found that the molecules mostly group in the middle distance from the axis of the tube to the wall. The molecules located in the vicinity of the wall demonstrate some deviation from planar shape. There is a tilted orientational ordering of the molecules which depends on the location of the molecule. It is shown that the diffusion coefficient of the benzene molecules is very small at the conditions we report here. © 2015 Wiley Periodicals, Inc. 相似文献
120.
Parameterization of electrostatic interactions for molecular dynamics simulations of heterocyclic polymers
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Victor M. Nazarychev Sergey V. Larin Alexander V. Yakimansky Natalia V. Lukasheva Andrey A. Gurtovenko Iosif V. Gofman Vladimir E. Yudin Valentin M. Svetlichnyi Jose M. Kenny Sergey V. Lyulin 《Journal of Polymer Science.Polymer Physics》2015,53(13):912-923
The paper focuses on the problem of electrostatic interactions in molecular dynamics simulations of thermal properties of heterocyclic polymers. The study focuses on three thermoplastic polyimides synthesized on the basis of 1,3‐bis‐(3′,4‐dicarboxyphenoxy)benzene (dianhydride R) and three diamines: 4,4′‐bis‐(4″‐aminophenoxy) diphenylsulfone (diamine BAPS), 4,4′‐bis‐(4″‐aminophenoxy) biphenyl (diamine BAPB), and 4,4′‐bis‐(4''‐aminophenoxy) diphenyloxide (diamine BAPO). In the molecular dynamics simulations these polyimides were described by the Gromos53a5 force field. To parameterize the electrostatic interactions four methods of calculating the partial atomic charges were chosen: B3LYP/6–31G*(Mulliken), AM1(Mulliken), HF/6–31G*(Mulliken), and HF/6–31G*(ChelpG). As our parameterization is targeted to reproduce thermal properties of the thermoplastic polyimides, the choice of proper partial charges was finalized on a basis of the closest match between computational and experimental data for the thermal expansion coefficients of the polyimides below glass transition temperatures. Our finding clearly show that the best agreement with experimental data is achieved with the Mulliken partial atomic charges calculated by the Hartree‐Fock method with 6–31G* basis set. Furthermore, in addition to the thermal expansion coefficients this set of partial atomic charges predicts an experimentally observed relationship between glass transition temperatures of the three polyimides under study: . A mechanism behind the change in thermal properties upon the change in the chemical structure in considered polyimides may be related to an additional spatial ordering of sulfone groups due to dipole‐dipole interactions. Overall, the modified force‐field is proved to be suitable for accurate prediction of thermal properties of thermoplastic polyimides and can serve as a basis for building up atomistic theoretical models for describing other heterocyclic polymers in bulk. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 912–923 相似文献