全文获取类型
收费全文 | 90491篇 |
免费 | 16366篇 |
国内免费 | 9188篇 |
专业分类
化学 | 61526篇 |
晶体学 | 915篇 |
力学 | 5746篇 |
综合类 | 512篇 |
数学 | 10089篇 |
物理学 | 37257篇 |
出版年
2024年 | 344篇 |
2023年 | 2043篇 |
2022年 | 3293篇 |
2021年 | 3503篇 |
2020年 | 3927篇 |
2019年 | 3509篇 |
2018年 | 3216篇 |
2017年 | 2866篇 |
2016年 | 4582篇 |
2015年 | 4362篇 |
2014年 | 5320篇 |
2013年 | 6766篇 |
2012年 | 8209篇 |
2011年 | 8397篇 |
2010年 | 5547篇 |
2009年 | 5379篇 |
2008年 | 5779篇 |
2007年 | 5064篇 |
2006年 | 4760篇 |
2005年 | 3818篇 |
2004年 | 2940篇 |
2003年 | 2294篇 |
2002年 | 2107篇 |
2001年 | 1815篇 |
2000年 | 1604篇 |
1999年 | 1839篇 |
1998年 | 1591篇 |
1997年 | 1576篇 |
1996年 | 1563篇 |
1995年 | 1322篇 |
1994年 | 1150篇 |
1993年 | 996篇 |
1992年 | 858篇 |
1991年 | 783篇 |
1990年 | 643篇 |
1989年 | 501篇 |
1988年 | 370篇 |
1987年 | 308篇 |
1986年 | 323篇 |
1985年 | 261篇 |
1984年 | 151篇 |
1983年 | 117篇 |
1982年 | 100篇 |
1981年 | 57篇 |
1980年 | 42篇 |
1979年 | 15篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1957年 | 31篇 |
1922年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
271.
Peng Chen Jun Chen Baoqing Zhang Jun Zhang Jiasong He 《Journal of Polymer Science.Polymer Physics》2006,44(6):1020-1030
Polycarbonate (PC) was melt blended with small amount of liquid‐crystalline polymer (LCP) and various contents of glass beads (GB) having different diameters. The rheological measurements indicated that the GB addition increased the viscosity ratio and seemed unfavorable to the LCP fibrillation. However, the morphological observation showed that the LCP fibrillation was promoted by the GB addition and varied with the GB packing. With the increased GB packing by increasing the GB content and/or decreasing the GB diameter, LCP deformed from spheres and ellipsoids into stretched ellipsoids at lower shear rates and into long fibrils at higher shear rates. Although higher content of smaller GB jammed into the larger LCP droplets and inhibited the LCP fibrillation, very long LCP fibrils formed at higher shear rates at a high enough packing of GB. The relationship between GB packing and LCP fibrillation revealed two kinds of hydrodynamic effects of GB promoting the LCP fibrillation: at lower GB packing, the shear flow was enhanced by the high local shear between GB, in quantity; and for a high enough GB packing, the shear flow was changed, in quality, into elongational flow, which was more effective for the LCP fibrillation. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1020–1030, 2006 相似文献
272.
Xiaoqing Liu Chuncheng Li Dong Zhang Yaonan Xiao 《Journal of Polymer Science.Polymer Physics》2006,44(6):900-913
This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (PBS) and its copolyester (PBSR) modified with rosin maleopimaric acid anhydride, using wide‐angle X‐ray diffraction, differential scanning calorimeter (DSC), and polarized optical microscope. Subsequent DSC scans of isothermally crystallized PBS and PBSR exhibited two melting endotherms, respectively, which was due to the melt‐recrystallization process occurring during the DSC scans. The equilibrium melting point of PBSR (125.9 °C) was lower than that of PBS (139 °C). The commonly used Avrami equation was used to describe the isothermal crystallization kinetics. For nonisothermal crystallization studies, the model combining Avrami equation and Ozawa equation was employed. The result showed a consistent trend in the crystallization process. The crystallization rate was decreased, the perfection of crystals was decreased, the recrystallization was reduced, and the spherulitic morphologies were changed when the huge hydrogenated phenanthrene ring was added into the chain of PBS. The activation energy (ΔE) for the isothermal crystallization process determined by Arrhenius method was 255.9 kJ/mol for PBS and 345.7 kJ/mol for PBSR. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 900–913, 2006 相似文献
273.
Yabin Zhou Shifeng Wang Yinxi Zhang Yong Zhang 《Journal of Polymer Science.Polymer Physics》2006,44(8):1226-1236
Methacrylic acid (MAA) was used as in situ surface modifier to improve the interface interaction between nano‐CaCO3 particle and ethylene–propylene–diene monomer (EPDM) matrix, and hence the mechanical properties of nano‐CaCO3‐filled EPDM vulcanizates. The results showed that the incorporation of MAA improved the filler–matrix interaction, which was proved by Fourier transformation infrared spectrometer (FTIR), Kraus equation, crosslink density determination, and scanning electron microscope (SEM). The formation of carboxylate and the participation of MAA in the crosslinking of EPDM indicated the strong filler–matrix interaction from the aspect of chemical reaction. The results of Kraus equation showed that the presence of MAA enhanced the reinforcement extent of nano‐CaCO3 on EPDM vulcanizates. Crosslink density determination proved the formation of the ionic crosslinks in EPDM vulcanizates with the existence of MAA. The filler particles on tensile fracture were embedded in the matrix and could not be observed obviously, indicating that a strong interfacial interaction between the filler and the matrix had been achieved with the incorporation of MAA. Meanwhile, the presence of MAA remarkably increased the modulus and tensile strength of the vulcanizates, without negative effect on the high elongation at break. Furthermore, the ionic bond was thought to be formed only on filler surface because of the absolute deficiency of MAA, which resulted in the possible structure where filler particles were considered as crosslink points. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1226–1236, 2006 相似文献
274.
Jia-Zhong Zhang 《Analytical sciences》2006,22(1):57-60
Incorporation of a liquid waveguide capillary flow cell into a flow injection instrument enhances the sensitivity of flow injection analysis with spectrophotometric detection by two orders of magnitude. Nitrite determination at nM levels has been used to demonstrate the feasibility of this novel technique for trace analysis. Combining the long pathlength spectrophotometry with flow injection analysis, this technique has advantages of low detection limit, good precision and high sample throughput. 相似文献
275.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献
276.
This paper is concerned with the existence of positive solutions of two-point Dirichlet singular and nonsingular boundary problems for second-order quasi-linear differential equations with changing sign nonlinearities. 相似文献
277.
The newton filtration and d-determination of bifurcation problems related to C
0 contact equivalence
In this paper, from the Newton filtration’s point of view, we construct the singular Riemannian metric and use the method in singular theory to study the bifurcation problems, and give the sufficient condition of d-determination of bifurcation problems with respect to C 0 contact equivalence. The special cases of the main result in this paper are the results of Sun Weizhi and Zou Jiancheng. 相似文献
278.
Model and empirical study on some collaboration networks 总被引:8,自引:0,他引:8
Pei-Pei Zhang Kan Chen Yue He Tao Zhou Bei-Bei Su Yingdi Jin Hui Chang Yue-Ping Zhou Li-Cheng Sun Bing-Hong Wang Da-Ren He 《Physica A》2006,360(2):599-616
In this paper we present an empirical study of a few practical systems described by cooperation networks, and propose a model to understand the results obtained. We study four non-social systems, which are the Bus Route Networks of Beijing and Yangzhou, the Travel Route Network of China, Huai-Yang recipes of Chinese cooked food, and a social system, which is the Collaboration Network of Hollywood Actors. In order to explain the results related to the degree distribution, act-degree distribution and act-size distribution (especially about the degree distribution, which may be better fitted using a stretched exponential distribution (SED)), we suggest a simple model to show a possible evolutionary mechanism for the emergence of such networks. The analytic and numerical results obtained from the model are in good agreement with the empirical results. 相似文献
279.
环形线电荷的电场分布 总被引:30,自引:10,他引:20
给出了圆环形线电荷电场分布的理论公式,并利用计算机计算出其具体分布规律。 相似文献
280.
本文讨论非线性退缩方程组uit=△ηi(ui)+fi(x,t,u1,…,uN),(x,t)∈QT=Ω×(0,T)具有Dirichlet边界条件的解之整体存在和非整体存在. 相似文献