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11.
Elif Kose UnverSimge Tarkuc Derya Baran Cihangir TanyeliLevent Toppare 《Tetrahedron letters》2011,52(21):2725-2729
Two low band gap conjugated polymers, poly[4,9-bis(4-hexylthien-2-yl)-6,7-di(thien-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline] (PHTTQ) and poly[5,10-bis(4-hexylthien-2-yl)-2,3,7,8-tetra(thien-2-yl)pyrazino[2,3-g]quinoxaline] (PHTPQ), consisting of alternating electron-rich 3-hexylthiophene and electron-deficient 6,7-di(thien-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline (TTQ) and 2,3,7,8-tetra(thien-2-yl)-2,3-dihydropyrazino[2,3-g]quinoxaline (TPQ) units were synthesized electrochemically. The structures of the π-conjugated monomers were tailored using thiophene as the pendant group on the acceptor units (TTQ and TPQ). The electrochemical and optical properties of the polymers were investigated by cyclic voltammetry and UV-vis-NIR spectroscopy. The absorption spectra of PHTPQ, revealing a 1.0 eV band gap, exhibited three maxima at 352 nm, 535 nm, and 750 nm. Consequently, its absorption spectra cover the region between 400 and 800 nm, which make the polymer almost black in appearance. PHTTQ shows a λmax value of 820 nm and a band gap of 0.8 eV which is very low among other [1,2,5]thiadiazolo[3,4-g]quinoxaline-containing donor-acceptor type polymers. 相似文献
12.
Rose-Munch F Marti A Cetiner D Tranchier JP Rose E 《Dalton transactions (Cambridge, England : 2003)》2011,40(7):1567-1575
First Suzuki-Miyaura coupling reactions applied to (η(5)-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η(5)-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η(6)-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by X-ray diffraction study. 相似文献
13.
A module M is said to be square free if whenever its submodule is isomorphic to N2 = N⊕N for some module N, then N = 0. Dually, a module M is said to be d-square free (dual square free) if whenever its factor module is isomorphic to N2 for some module N, then N = 0. In this paper, we give some fundamental properties of d-square free modules and study rings whose d-square free modules are closed under submodules or essential extensions. 相似文献
14.
A submodule N of a module M is idempotent if N = Hom(M, N)N. The module M is fully idempotent if every submodule of M is idempotent. We prove that over a commutative ring, cyclic idempotent submodules of any module are direct summands. Counterexamples are given to show that this result is not true in general. It is shown that over commutative Noetherian rings, the fully idempotent modules are precisely the semisimple modules. We also show that the commutative rings over which every module is fully idempotent are exactly the semisimple rings. Idempotent submodules of free modules are characterized. 相似文献
15.
Dacarbazine (DTIC) is a chemotherapy drug that is used for the treatment of Hodgkin's lymphoma, malignant melanoma, childhood solid tumors and soft tissue sarcoma. The surface confined interaction between DTIC and nucleic acids was investigated for the first time in this study by using both differential pulse voltammetry (DPV) and electrochemical impedance spectroscopy (EIS) in combination with disposable pencil graphite electrodes. The oxidation signals of DTIC and guanine were measured before and after interaction process using DPV technique. The interaction of DTIC with nucleic acids; poly[A], poly[G], or double stranded of poly[A]‐poly[T] and poly[G]‐poly[C] was also examined using DPV. Furthermore, EIS technique was utilized for detection of the interaction between DTIC and nucleic acids; ssDNA/dsDNA, poly[A], poly[G], or double stranded poly[A]‐poly[T] and poly[G]‐poly[C]. 相似文献
16.
In this Letter, we present analytical and numerical solutions for an axis-symmetric diffusion-wave equation. For problem formulation, the fractional time derivative is described in the sense of Riemann-Liouville. The analytical solution of the problem is determined by using the method of separation of variables. Eigenfunctions whose linear combination constitute the closed form of the solution are obtained. For numerical computation, the fractional derivative is approximated using the Grünwald-Letnikov scheme. Simulation results are given for different values of order of fractional derivative. We indicate the effectiveness of numerical scheme by comparing the numerical and the analytical results for α=1 which represents the order of derivative. 相似文献
17.
In the current work, two triazine‐based multidentate ligands (H2L1 and H2L2) and their homo‐dinuclear Mn (II), mononuclear Ln (III) and hetero‐dinuclear Mn (II)/Ln (III) (Where Ln: Eu or La) complexes were synthesized and characterized by spectroscopic and analytical methods. Single crystals of a homo‐dinuclear Mn (II) complex {[Mn (HL1)(CH3OH)](ClO4·CH3OH}2 ( 1 ) were obtained and the molecular structure was determined by X‐ray diffraction method. In the structure of the complex, each Mn (II) ion is seven‐coordinate and one of the phenolic oxygen bridges two Mn (II) centre forming a dimeric structure. The UV–Vis. and photoluminescence properties of synthesized ligands and their metal complexes were investigated in DMF solution and the compounds showed emission bands in the UV–Vis. region. The catecholase enzyme‐like activity of the complexes were studied for 3,5‐DTBC → 3,5‐DTBQ conversion in the presence of air oxygen. Homo‐dinuclear Mn (II) complexes ( 1 and 4 ) were found to efficiently catalyse 3,5‐DTBC → 3,5‐DTBQ conversion with the turnover numbers of 37.25 and 35.78 h?1 (kcat), respectively. Mononuclear Eu (III) and La (III) complexes did not show catecholase activity. 相似文献
18.
Kuno Schwrzer Saroj K. Rout Derya Bessinger Fabio Lima Cara E. Brocklehurst Konstantin Karaghiosoff Thomas Bein Paul Knochel 《Chemical science》2021,12(39):12993
We report the selective functionalization of the 1H-imidazo[1,2-b]pyrazole scaffold using a Br/Mg-exchange, as well as regioselective magnesiations and zincations with TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl), followed by trapping reactions with various electrophiles. In addition, we report a fragmentation of the pyrazole ring, giving access to push–pull dyes with a proaromatic (1,3-dihydro-2H-imidazol-2-ylidene)malononitrile core. These functionalization methods were used in the synthesis of an isostere of the indolyl drug pruvanserin. Comparative assays between the original drug and the isostere showed that a substitution of the indole ring with a 1H-imidazo[1,2-b]pyrazole results in a significantly improved solubility in aqueous media.A methodology for the selective functionalization of the 1H-imidazo[1,2-b]pyrazole scaffold has been developed and used in the synthesis of novel push–pull dyes and a non-classical isostere of the indolyl drug pruvanserin. 相似文献
19.
Derya Caliskan Christophe Croux Sarah Gelper 《Statistics & probability letters》2009,79(18):1900-1905
This paper presents a new method for robust online variability extraction in time series. The proposed estimator is simultaneously highly robust and efficient. We derive its breakdown point, influence function, and asymptotic variance and study the finite sample properties in a simulation study. 相似文献
20.