Effect of void fraction and friction factor models on the prediction of pressure drop of R134a during downward condensation in a vertical tube

The theoretical flow models of homogeneous and separated flow are applied to in-tube condensation to predict the pressure drop characteristics of R134a. The homogeneous flow model is modified by ten different dynamic viscosity correlations and various alternative correlations of total, frictional and momentum pressure drops to take account of the partial condensation inside the tube. Numerical analyses were performed to determine the average and local homogeneous wall shear stresses and friction factors by means of a CFD program. The equivalent Reynolds number model is modified by six different two-phase friction factors to determine the total condensation pressure drop in the separated flow model. The refrigerant side total pressure drops, frictional pressure drops, friction factors and wall shear stresses are determined within a ±30% error band. The importance of using the alternative total, momentum and frictional pressure drop correlations for the homogeneous flow model is also shown.     

Microscopic interacting boson model calculations for even-even <Superscript>128–138</Superscript>Ce nuclei

In this study, we determined the most appropriate Hamiltonian that is needed for the present calculations of energy levels and B(E2) values of ^128–138Ce nuclei which have a mass around A≅130 using the interacting boson model (IBM). Using the best-fitted values of parameters in the Hamiltonian of the IBM-2, we have calculated energy levels and B(E2) values for a number of transitions in ^{128,130,132,134,136,138}Ce. The results were compared with the previous experimental and theoretical (PTSM model) data and it was observed that they are in good agreement. Also some predictions of this model have better accuracy than those of PTSM model. It has turned out that the interacting boson approximation (IBA) is fairly reliable for calculating spectra in the entire set of ^{128,130,132,134,136,138}Ce isotopes and the quality of the fits presented in this paper is acceptable.      

Synthesis,spectroscopic properties,crystal structures,antioxidant activities and enzyme inhibition determination of Co(II) and Fe(II) complexes of Schiff base

Research on Chemical Intermediates - Considering the importance of metal complexes in the development of medical science, two different Schiff base Fe(II) and Co(II) metal complex compounds were...     

Back Cover: Manipulating Intermetallic Charge Transfer for Switchable External Stimulus-Enhanced Water Oxidation Electrocatalysis (Angew. Chem. Int. Ed. 44/2023)

Electrocatalytic processes involving the oxygen evolution reaction (OER) present a kinetic bottleneck due to the existence of linear-scaling relationships, which bind the energies of the different intermediates in the mechanism limiting optimization. Here, we offer a way to break these scaling relationships and enhance the electrocatalytic activity of a Co−Fe Prussian blue modified electrode in OER by applying external stimuli. Improvements of ≈11 % and ≈57 % were achieved under magnetic field (0.2 T) and light irradiation (100 mW cm⁻²), respectively, when working at fixed overpotential, η=0.6 V at pH 7. The observed enhancements strongly tie in with the intermetallic charge transfer (IMCT) intensity between Fe and Co sites. Density Functional Theory simulations suggest that tuning the IMCT can lead to a change of the OER mechanism to an external stimuli-sensitive spin crossover-based pathway, which opens the way for switchable electrocatalytic devices.