Solid Fabry-Perot etalons for X-rays

Solid Fabry-Perot etalons for X-rays have been constructed using sputter deposition techniques, each etalon consisting of two Layered Synthetic Microstructures (LSM) Bragg diffraction structures separated by a carbon spacer. The individual LS mirrors contain fifteen tungsten layers (t_w = 8.5 Å) separated by carbon layers (t_c = 19.1 Å. The thick carbon spacers act as resonant cavities; for the structures reported on here the spacer thicknesses, t_sp, are 496.6 Å and 981 Å. The structures were characterized at grazing incidence in reflection using Cu Kα (λ = 1.5418 Å) radiation. The measured response of the etalons agrees well with calculation. Observed reflection efficiencies for Cu K_α were approximately 50 percent of that calculated. This discrepancy is believed to be the result of the interfacial roughness (～3.25 Å) between component layers and the sensitivity of the etalon response to the divergence of the incident X-ray beam.     

Study of transverse momenta of charged hadrons produced in νp and\bar vp charged current interactions

Data from a neutrino and antineutrino hydrogen experiment with BEBC are used to investigate transverse properties of the produced charged hadrons. Measurements are presented on average transverse momenta of charged pions as functions of Feynman-x and the hadronic mass, on the transverse momentum flow within an event and on jet-related quantities. The main features of the data are well described by the LUND model. The data favour a version of the model in which soft gluon effects are included and the primordial transverse momentum of the quarks in the proton is small. Effects from 1^st order QCD (hard gluon emission) are negligible.     

Application of optimal control to CPMG refocusing pulse design

We apply optimal control theory (OCT) to the design of refocusing pulses suitable for the CPMG sequence that are robust over a wide range of B(0) and B(1) offsets. We also introduce a model, based on recent progress in the analysis of unitary dynamics in the field of quantum information processing (QIP), that describes the multiple refocusing dynamics of the CPMG sequence as a dephasing Pauli channel. This model provides a compact characterization of the consequences and severity of residual pulse errors. We illustrate the methods by considering a specific example of designing and analyzing broadband OCT refocusing pulses of length 10t(180) that are constrained by the maximum instantaneous pulse power. We show that with this refocusing pulse, the CPMG sequence can refocus over 98% of magnetization for resonance offsets up to 3.2 times the maximum RF amplitude, even in the presence of ±10% RF inhomogeneity.     

Advances in methods and algorithms in a modern quantum chemistry program package

Advances in theory and algorithms for electronic structure calculations must be incorporated into program packages to enable them to become routinely used by the broader chemical community. This work reviews advances made over the past five years or so that constitute the major improvements contained in a new release of the Q-Chem quantum chemistry package, together with illustrative timings and applications. Specific developments discussed include fast methods for density functional theory calculations, linear scaling evaluation of energies, NMR chemical shifts and electric properties, fast auxiliary basis function methods for correlated energies and gradients, equation-of-motion coupled cluster methods for ground and excited states, geminal wavefunctions, embedding methods and techniques for exploring potential energy surfaces.     

Electrophilic aromatic substituted luciferins as bioluminescent probes for glutathione S-transferase assays

New highly sensitive latent bioluminescent luciferin substrates were designed and synthesized for monitoring mammalian glutathione S-transferase (GST) and Schistosoma japonicum enzyme activities.     

Quasi-static deformation and final fracture behaviour of aluminium alloy 5083: influence of cryomilling

The commercial aluminium alloy 5083 was processed via cryomilling to produce nanocrystalline (NC) powders with an average grain size of ～25–50?nm. The powders were subsequently degassed at 723 K (450°C), pre-heated and immediately quasi-isostatic (QI)-forged to produce a thermally stable bulk ultrafine grain (UFG) material having average grain size values ranging from 190 to 350?nm, depending on the processing conditions used. In this paper, the tensile properties and fracture behaviour of the bulk UFG material are presented and compared with the tensile properties of its conventionally processed counterpart. The specific influence of preheat temperature on strength and ductility of the alloy is briefly discussed. Three different pre-heat temperatures of 523, 623 and 723?K (250, 350 and 450°C) were chosen and used with the primary objective of controlling grain growth during forging. The influence of preheat temperature on tensile deformation and final fracture behaviour is highlighted. The macroscopic fracture modes of the bulk nanostructured material (BNM) prepared following three pre-heat temperatures are investigated. The microscopic mechanisms controlling tensile deformation and final fracture behaviour are discussed with regards to the intrinsic microstructural effects in the UFG alloy, nature of loading, and the kinetics and mechanisms of deformation.     

The size Ramsey number of short subdivisions of bounded degree graphs

For graphs G and F, write if any coloring of the edges of G with colors yields a monochromatic copy of the graph F. Suppose is obtained from a graph S with s vertices and maximum degree d by subdividing its edges h times (that is, by replacing the edges of S by paths of length h + 1). We prove that there exists a graph G with no more than edges for which holds, provided that . We also extend this result to the case in which Q is a graph with maximum degree d on q vertices with the property that every pair of vertices of degree greater than 2 are distance at least h + 1 apart. This complements work of Pak regarding the size Ramsey number of “long subdivisions” of bounded degree graphs.