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101.
For any ? > 0 we show the existence of continuous periodic weak solutions v of the Euler equations that do not conserve the kinetic energy and belong to the space ; namely, x ? v (x,t) is ??ε‐Hölder continuous in space at a.e. time t and the integral is finite. A well‐known open conjecture of L. Onsager claims that such solutions exist even in the class .© 2016 Wiley Periodicals, Inc. 相似文献
102.
The optical and electrochemical properties of the ruthenium phthalocyanine complexes [[(t-Bu)4Pc]Ru(4-Rpy)2], where R = NO2, Me, NH2, and NMe2, are reported. The electron density at the macrocycle may be adjusted using the axial ligand substituents, which have varying electron-donating/withdrawing strengths. Electrochemical data show that the axial pyridine ligand substituents exert significant influence over the phthalocyanine ring-based redox processes. The axial ligands also influence the electronic absorption properties of the complexes with influence also being observed in the electrogenerated oxidized and reduced species. 相似文献
103.
Drechsler SL Volkova O Vasiliev AN Tristan N Richter J Schmitt M Rosner H Málek J Klingeler R Zvyagin AA Büchner B 《Physical review letters》2007,98(7):077202
From thermodynamics, local spin density approximation+Hubbard U studies and exact diagonalizations of a five-band Hubbard model on CuO2 stripes we find that Li2ZrCuO4 (Li2CuZrO4 in traditional notation) is close to a ferromagnetic critical point. Analyzing its susceptibility chi(T) and specific heat cp(T,H) within a Heisenberg model, we show that the ratio of the 2nd to the 1st neighbor exchange integrals alpha=-J2/J1 approximately 0.3 is close to the critical value alphac=1/4. Comparing with related chain cuprates we explain the rather strong field dependence of cp, the monotonic downshift of the peak of chi(T), and its increase for alpha-->alphac+0. 相似文献
104.
Pike RD deKrafft KE Ley AN Tronic TA 《Chemical communications (Cambridge, England)》2007,(36):3732-3734
The structurally unique and highly luminescent 20 : 7 complex of CuCN with piperazine (Pip) was formed under aqueous conditions; its structure reveals two interpenetrated 2D sub-networks in 6 : 1 ratio: (CuCN)2(Pip) and (CuCN)8(Pip), the latter consisting of Cu18(CN)16(Pip)2 macrocycles. 相似文献
105.
Inke Jess Tristan Neumann Huayna Terraschke Gianpiero Gallo Robert Dinnebier Christian Näther 《无机化学与普通化学杂志》2020,646(14):1046-1054
Reaction of MX2 (M = Cd, Zn; X = Cl, Br, I) with 2-cyanopyrazine leads to the formation of compounds with the composition CdX2(2-cyanopyrazine)2 (X = Cl; CdCl , X = Br; CdBr and X = I; CdI ) and ZnX2(2-cyanopyrazine)2 (X = Cl; ZnCl , X = Br; ZnBr and X = I; ZnI/I ). In the crystal structures of the Cd compounds and in ZnCl , the metal cations are octahedrally coordinated and are linked into chains by the halide anions via common edges. In contrast, in the crystal structures of ZnBr and ZnI/I the metal cations are tetrahedrally coordinated into discrete complexes. Further investigations show that a second modification of ZnCl2(2-cyanopyrazine)2 exists ( ZnI/II ), which is formed by kinetic control. The thermal properties of the 2-cyanopyrazine rich compounds were investigated by TG-DTA and temperature dependent XRPD measurements. Upon heating the Cd compounds, all 2-cyanopyrazine ligands are removed in a single step with no indication of the formation of a 2-cyanopyrazine deficient phase. A similar behavior is observed for ZnI , whereas for ZnCl and ZnBr , TG-DTA measurements suggest the formation of a 2-cyanopyrazine deficient phase that, in case of ZnBr , cannot be isolated and, for ZnCl , cannot be obtained pure. The emission of these compounds is shifted from the blue to orange depending on the crystal structure and the nature of the halide anion. 相似文献
106.
Dr. Hao Sun Dr. Wei Cao Dr. Nanzhi Zang Dr. Tristan D. Clemons Georg M. Scheutz Ziying Hu Dr. Matthew P. Thompson Yifei Liang Maria Vratsanos Xuhao Zhou Wonmin Choi Prof. Dr. Brent S. Sumerlin Prof. Dr. Samuel I. Stupp Prof. Dr. Nathan C. Gianneschi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(43):19298-19304
Herein, we report the photoinitiated polymerization-induced self-assembly (photo-PISA) of spherical micelles consisting of proapoptotic peptide–polymer amphiphiles. The one-pot synthetic approach yielded micellar nanoparticles at high concentrations and at scale (150 mg mL−1) with tunable peptide loadings up to 48 wt. %. The size of the micellar nanoparticles was tuned by varying the lengths of hydrophobic and hydrophilic building blocks. Critically, the peptide-functionalized nanoparticles imbued the proapoptotic “KLA” peptides (amino acid sequence: KLAKLAKKLAKLAK) with two key properties otherwise not inherent to the sequence: 1) proteolytic resistance compared to the oligopeptide alone; 2) significantly enhanced cell uptake by multivalent display of KLA peptide brushes. The result was demonstrated improved apoptosis efficiency in HeLa cells. These results highlight the potential of photo-PISA in the large-scale synthesis of functional, proteolytically resistant peptide–polymer conjugates for intracellular delivery. 相似文献
107.
108.
109.
Moro AJ Schmidt J Doussineau T Lapresta-Fernandéz A Wegener J Mohr GJ 《Chemical communications (Cambridge, England)》2011,47(21):6066-6068
The design of two-dyed fluorescent silica nanoparticles for ATP detection is presented. The indicator dye possesses a dipicolyl-amine (DPA) unit complexed with Zn(II) as a receptor function for ATP while a rhodamine derivative is used as the reference dye. The nanoparticles were fully characterized regarding analytical performance, morphology and cytocompatibility. 相似文献
110.
Fraix A Montier T Le Gall T Sevrain CM Carmoy N Lindberg MF Lehn P Jaffrès PA 《Organic & biomolecular chemistry》2012,10(10):2051-2058
When considering a family of cationic lipids designed for gene delivery, the nature of the cationic polar head probably has a great influence on both the transfection efficacy and toxicity. Starting from a cationic lipothiophosphoramidate bearing a trimethylammonium headgroup, we report herein the impact on gene transfection activity of the replacement of the trimethylammonium moiety by a trimethylphosphonium or a trimethylarsonium group. A series of three different human epithelial cell lines were used for the experimental transfection studies (HeLa, A549 and 16HBE14o(-)). The results basically showed that such structural modifications of the cationic headgroup can lead to a high transfection efficacy at low lipid/DNA charge ratios together with a low cytotoxicity. It thus appears that the use of a trimethylarsonium cationic headgroup for the design of efficient gene carriers, which was initially proposed in the lipophosphoramidate series, can be extended to other series of cationic lipids and might therefore have great potential for the development of novel non-viral vectors in general. 相似文献