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101.
Cunefare KA Biesel VB Tran J Rye R Graf A Holdhusen M Albanese AM 《The Journal of the Acoustical Society of America》2003,113(2):881-892
Qualification of anechoic chambers is intended to demonstrate that the chamber supports the intended free-field environment within some permissible tolerance bounds. Key qualification issues include the method used to obtain traverse data, the analysis method for the data, and the use of pure tone or broadband noise as the chamber excitation signal. This paper evaluates the relative merits of continuous versus discrete traverses, of fixed versus optimal reference analysis of the traverse data, and of the use of pure tone versus broadband signals. The current practice of using widely space discrete sampling along a traverse is shown to inadequately sample the complexity of the sound field extant with pure tone traverses, but is suitable for broadband traverses. Continuous traverses, with spatial resolution on the order of 15% of the wavelength at the frequency of interest, are shown to be necessary to fully resolve the spatial complexity of pure tone qualifications. The use of an optimal reference method for computing the deviations from inverse square law is shown to significantly improve the apparent performance of the chamber for pure tone qualifications. Finally, the use of broadband noise as the test signal, as compared to pure tone traverses over the same span, is demonstrated to be a marginal indicator of chamber performance. 相似文献
102.
103.
Evidence is provided that nucleophilic attack on five-membered ring oxocarbenium ions occurs from the inside face of the envelope. An eight-five fused-bicyclic system in which two substituents are constrained to pseudoequatorial positions underwent nucleophilic addition with selectivity that was comparable to an unconstrained monocyclic system. On the other hand, a bicyclic six-five analogue underwent reaction with low selectivity. This observation indicates that minimization of eclipsing interactions by attacking inside the envelope is not enough to control selectivity, but that the changes in the overall three-dimensional structure of the ring must be favorable as well. In the bicyclic six-five series, the six-membered ring is accommodated in the cation, but it destabilizes the transition state structure leading to the first-formed product of inside attack. 相似文献
104.
Nguyen H. V. Hu'ng Tran Ngoc Nam 《Transactions of the American Mathematical Society》2001,353(12):5029-5040
Let the mod 2 Steenrod algebra, , and the general linear group, , act on with in the usual manner. We prove the conjecture of the first-named author in Spherical classes and the algebraic transfer, (Trans. Amer. Math Soc. 349 (1997), 3893-3910) stating that every element of positive degree in the Dickson algebra is -decomposable in for arbitrary 2$">. This conjecture was shown to be equivalent to a weak algebraic version of the classical conjecture on spherical classes, which states that the only spherical classes in are the elements of Hopf invariant one and those of Kervaire invariant one.
105.
This article is based on a talk given in Dijon for the 2000 summer school Topological and Geometrical Methods: Applications to Dynamical Systems. The standard definitions of the monodromy invariant for completely integrable classical systems are reviewed, and the link to the quantum monodromy observed in the joint spectrum of commuting operators is explained. The mathematical treatment relies on a modern and attractive version of the Bohr–Sommerfeld quantisation rules. 相似文献
106.
Tran Duc Thiep Truong Thi An Nguyen The Vinh Phan Viet Cuong A. G. Belov O. D. Maslov Trinh Thi Thu My 《Physics of Particles and Nuclei Letters》2007,4(5):397-402
We have carried out the study on the isomeric ratios in (γ,p) photonuclear reactions with isotopes
40
92
Zr and
74
183
W in the giant dipole resonance (GDR) region. The targets were irradiated with bremsstrahlungs produced by electron accelerator
Microtron MT-25 of the Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, Dubna, Russia. Spectra
of the irradiated samples were measured with a spectroscopic system consisting of 8192-channel analyzer CANBERRA and high-energy
resolution semiconductor detector CANBERRA. The results were discussed and compared with those of other authors.
The text was submitted by the authors in English. 相似文献
107.
We report a direct observation of the temperature field on a steel specimen during ablation by multiple femtosecond laser pulses using an infrared thermography technique. From the experimental results and simulation study of the temperature field, we quantified the deposited thermal power into the specimen during the ablation process. We found that more than two thirds of the incident laser power was deposited in the steel specimen when ablated by multiple femtosecond laser pulses. This result provides further understanding of the heating effect in materials processing by ultrashort laser pulses. 相似文献
108.
H. Tran V. Dana X. Thomas 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,108(3):342-362
Line intensities are measured for 546 transitions belonging to 13 bands of the main isotopologue 12C2H2 of the acetylene molecule, in the 1.5-μm spectral domain. A multispectrum fitting procedure is used to retrieve line parameters from Fourier transform spectra. Prior to this work, line intensities were known for only 4 bands in this spectral region, from the work of El Hachtouki and Vander Auwera [Absolute line intensities in acetylene: the 1.5 μm region. J Mol Spectrosc 2002;216:355-62]. An excellent agreement is found with the results of these authors, showing that the accuracy of both results is likely better than 1% for the strong bands. However, the spectrum becomes very crowded when one wants to study weaker bands, so that the average accuracy of the intensities reported in the present work is 5%. From these data, vibrational transition dipole moments squared and Herman-Wallis coefficients have been determined for all the bands. 相似文献
109.
110.
Jan L. Allen Bria A. Crear Rishav Choudhury Michael J. Wang Dat T. Tran Lin Ma Philip M. Piccoli Jeff Sakamoto Jeff Wolfenstine 《Molecules (Basel, Switzerland)》2021,26(9)
Spinel-structured solids were studied to understand if fast Li+ ion conduction can be achieved with Li occupying multiple crystallographic sites of the structure to form a “Li-stuffed” spinel, and if the concept is applicable to prepare a high mixed electronic-ionic conductive, electrochemically active solid solution of the Li+ stuffed spinel with spinel-structured Li-ion battery electrodes. This could enable a single-phase fully solid electrode eliminating multi-phase interface incompatibility and impedance commonly observed in multi-phase solid electrolyte–cathode composites. Materials of composition Li1.25M(III)0.25TiO4, M(III) = Cr or Al were prepared through solid-state methods. The room-temperature bulk Li+-ion conductivity is 1.63 × 10−4 S cm−1 for the composition Li1.25Cr0.25Ti1.5O4. Addition of Li3BO3 (LBO) increases ionic and electronic conductivity reaching a bulk Li+ ion conductivity averaging 6.8 × 10−4 S cm−1, a total Li-ion conductivity averaging 4.2 × 10−4 S cm−1, and electronic conductivity averaging 3.8 × 10−4 S cm−1 for the composition Li1.25Cr0.25Ti1.5O4 with 1 wt. % LBO. An electrochemically active solid solution of Li1.25Cr0.25Mn1.5O4 and LiNi0.5Mn1.5O4 was prepared. This work proves that Li-stuffed spinels can achieve fast Li-ion conduction and that the concept is potentially useful to enable a single-phase fully solid electrode without interphase impedance. 相似文献