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81.
Ochiai M Nishi Y Mori T Tada N Suefuji T Frohn HJ 《Journal of the American Chemical Society》2005,127(30):10460-10461
Reported here for the first time are the synthesis, isolation, and characterization of hypervalent beta-haloalkenyl-lambda3-bromanes. Exposure of terminal alkynes to p-trifluoromethylphenyl(difluoro)-lambda3-bromane activated by BF3-i-Pr2O resulted in fluoro-lambda3-bromanation of the triple bonds in a Markovnikov fashion, yielding (E)-beta-fluoroalkenyl-lambda3-bromanes stereoselectively in good yields. 5-Chloro-1-pentynes undergo domino lambda3-bromanation-chlorine shift-fluorination or lambda3-bromanation-chlorine shift-alkyl shift-fluorination reaction, depending on the substituents and afford (E)-beta-chloroalkenyl-lambda3-bromanes stereoselectively in high yields. The beta-chloroalkenyl-lambda3-bromanes contain three kinds of halogen atoms, F, Cl, and Br, in the molecule. 相似文献
82.
Exposure of 1-alkynyl[p-(trifluoromethyl)phenyl](tetrafluoroborato)-lambda3-bromanes to 2-mercaptobenzimidazole or benzothiazole in dichloromethane at 0 degrees C under argon resulted in a domino Michael addition-carbene rearrangement-cyclization reaction to produce directly tricyclic heterocycles in high yields, whereas the reaction with 2-mercaptobenzoxazole afforded 1-alkynyl sulfides. 相似文献
83.
We have found a surfactant-promoted novel reductive synthesis of metallic Cu nanoclusters on metal oxides under hydrothermal synthesis conditions, which are active for the selective dehydrogenation of methanol. 相似文献
84.
85.
86.
Hisayuki Matsui Masayoshi Tamaki Shoichi Nasu Toshimasa Kurasawa 《Journal of Physics and Chemistry of Solids》1980,41(4):351-355
Electrical resistivities of arc-melted uranium carbides, UC, UC2, U2C3 and UC + UC2, were measured over the temperature range between 4 and 1900 K. The monocarbide, dicarbide and the mixture of carbides showed metallic character in their resistivity dependence on temperature above 30 K, while below this the resistivities were constant. U2C3 showed a knee in the resistivity curve at 54.0 K corresponding to a magnetic transition. Above 1100 K, the resistivity of U2C3 did not vary with temperature. The resistivity of the mixture (UC + UC2 with U2C3 precipitates) showed an arrest between 800 and 950 K. 相似文献
87.
Tsukamoto K Ohishi H Hiyama Y Maezaki N Tanaka T Ishida T 《Chemical communications (Cambridge, England)》2006,(34):3606-3608
Potassium salts of p-tert-butylcalix[6]arene p-bromophenylalanine derivative formed sizable octameric cages in the solid state that were revealed by X-ray crystallographic analysis. 相似文献
88.
89.
A marked acceleration property for the Diels-Alder reaction was observed in an aqueous micellar system composed of perfluorohexane and lithium perfluorooctanesulfonate. The reaction rate increased with the concentration of the equimolar mixture of PFH and LiFOS, and the rate in 500 mM PFH and 500 mM LiFOS was about 100-fold greater than that in water without the fluorous field. After completion of the reaction, the products were simply extracted from the aqueous reaction mixture using n-hexane. [reaction: see text]. 相似文献
90.
Toshimasa Ishii 《Journal of Graph Theory》2013,74(4):392-416
Given an undirected graph and an integer , we consider the problem of augmenting G by a minimum set of new edges so that the diameter becomes at most D. It is known that no constant factor approximation algorithms to this problem with an arbitrary graph G can be obtained unless , while the problem with only a few graph classes such as forests is approximable within a constant factor. In this article, we give the first constant factor approximation algorithm to the problem with an outerplanar graph G. We also show that if the target diameter D is even, then the case where G is a partial 2‐tree is also approximable within a constant. 相似文献