Characteristics of Gain-Guided Laser Diodes with Cylindrical-Mirror Cavity

We have developed highly reliable etched-mirror laser diodes using a dry etching method. The lasers without facet-coating have been operating stably over 2500 h under automatic-power control (APC) at a power of 3 mW/facet at 50°C. The gain-guided laser diodes with a cylindrical-mirror cavity (CMC) have coaxial mirrors and a fan-shaped stripe structure. By decreasing the curvature radius of the inner facet or increasing the stripe width of the inner facet, the beam waist parallel to the junction plane can be moved outside of the laser diode, while the beam waist perpendicular to the junction plane stops at the mirror facet. A particular CMC laser has a low astigmatism of 4.1 μm and a low relative intensity of noise (RIN) less than –134 dB/Hz at 4 mW under 0–1% optical feedback without high frequency current superposition.     

Electrochemically regenerative visible light-induced reactivity of α-Fe2O3 films with Ag(core)–AgCl(shell) microcrystal composites

Ag(core)–AgCl(shell) microcrystal composites (Ag@AgCl) have been formed on an α-Fe₂O₃ film-coated SnO₂ electrode by a 2 step method consisting of the electrochemical reduction of Ag⁺ ions and the subsequent electrochemical oxidation. The synergy of α-Fe₂O₃ and Ag@AgCl gave rise to a high visible light-induced reactivity (λ_ex > 420 nm) for the oxidation of 2-naphthol (2-NAP) used as a model water pollutant in the presence and absence of oxygen. These findings were attributable to the function of Ag@AgCl composites as an excellent charge-separation promoter and built-in acceptor.     

Mechanismus der Charge-transfer-Polymerisation. 12. Mitt. Der Einfluß der Wellenlänge des einfallenden Lichtes auf die kationische Photopolymerisation von N-Vinylcarbazol mit Bromund Chloranil in Benzol

Ohne Zusammenfassung     

ATR mode of surface magnon polaritons on YIG

The first discussion on ATR mode of surface magnon polaritons on semi- infinite YIG is presented for the Otto configuration (polyethylene-air-YIG geometry). Damping and the effect of retardation are included in the analysis. The thickness of the air layer appropriate for ATR measurements is determined.     

Synthesis and characterization of beta-haloalkenyl-lambda3-bromanes: stereoselective Markovnikov addition of difluoro(aryl)-lambda3-bromane to terminal acetylenes

Reported here for the first time are the synthesis, isolation, and characterization of hypervalent beta-haloalkenyl-lambda3-bromanes. Exposure of terminal alkynes to p-trifluoromethylphenyl(difluoro)-lambda3-bromane activated by BF3-i-Pr2O resulted in fluoro-lambda3-bromanation of the triple bonds in a Markovnikov fashion, yielding (E)-beta-fluoroalkenyl-lambda3-bromanes stereoselectively in good yields. 5-Chloro-1-pentynes undergo domino lambda3-bromanation-chlorine shift-fluorination or lambda3-bromanation-chlorine shift-alkyl shift-fluorination reaction, depending on the substituents and afford (E)-beta-chloroalkenyl-lambda3-bromanes stereoselectively in high yields. The beta-chloroalkenyl-lambda3-bromanes contain three kinds of halogen atoms, F, Cl, and Br, in the molecule.