全文获取类型
收费全文 | 652篇 |
免费 | 18篇 |
国内免费 | 3篇 |
专业分类
化学 | 509篇 |
晶体学 | 8篇 |
力学 | 5篇 |
数学 | 31篇 |
物理学 | 120篇 |
出版年
2023年 | 2篇 |
2022年 | 4篇 |
2020年 | 7篇 |
2019年 | 11篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 16篇 |
2013年 | 41篇 |
2012年 | 45篇 |
2011年 | 40篇 |
2010年 | 26篇 |
2009年 | 14篇 |
2008年 | 43篇 |
2007年 | 37篇 |
2006年 | 47篇 |
2005年 | 41篇 |
2004年 | 34篇 |
2003年 | 31篇 |
2002年 | 20篇 |
2001年 | 8篇 |
2000年 | 17篇 |
1999年 | 16篇 |
1998年 | 11篇 |
1997年 | 13篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 9篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 4篇 |
1986年 | 12篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 11篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1971年 | 1篇 |
排序方式: 共有673条查询结果,搜索用时 453 毫秒
91.
Toshifumi Inouchi Dr. Takuya Nakashima Dr. Masaya Toba Prof. Tsuyoshi Kawai 《化学:亚洲杂志》2011,6(11):3020-3027
T‐shaped π‐conjugated molecules with an N‐methyl‐benzimidazole junction have been synthesized and their acid‐responsive photophysical properties owing to the change in the π‐conjugation system are discussed. T‐shaped π‐conjugated molecules consist of two orthogonal π‐conjugated systems including a phenyl thiophene extended from the 2‐position and alkyl phenylenes connected through various π‐spacers from the 4,7‐positions of the N‐methyl‐benzimidazole junction. The π‐spacers, such as thiophene, ethyne, and ethane, have an effect on the acid response of photophysical properties in terms of changes in conformation, excited‐state energy and charge‐transfer (CT) characteristics. In particular, the π‐conjugated molecule with ethynyl spacers exhibited a marked redshift in the fluorescence spectrum with a large Stokes shift upon the addition of acid, whereas the other molecules showed substantial quenching. The redshift in emission was studied in detail by temperature‐dependent fluorescence measurements, which indicated the transition to a CT state over the finite activation energy at the excited state. The change in the frontier molecular orbitals upon acid addition was further discussed by means of DFT calculations. 相似文献
92.
Katsumi Saitoh Koichiro Sera Tadashi Shirai Tatsuji Sato Matsuo Odaka 《Analytical sciences》2003,19(4):525-528
The purpose of this study is to clarify the chemical characterization of PM2.5 and PM10 in diesel exhaust particles (DEP). Sampling of PM2.5 and PM10 in DEP was carried out in November 1999 using an automobile exhaust testing system at the National Traffic Safety and Environment Laboratory, with a diesel truck (engine type: direct injection, displacement: 7,961 cc, carrying weight: 2,020 kg, equivalent inertia weight: 5,600 kg) placed on a chassis dynamometer. Sampling conditions included idling, constant speed of 40 km/h, M-15 test pattern and 60%-revolution/40%-load of maximum power. Samples were collected on a polycarbonate membrane filter (Nuclepore, pore size: 0.8 microm) using a MiniVol Portable Air Sampler (Airmetrics Co., Inc.). The concentrations of several elemental and ionic species in the PM2.5 and PM10 samples were determined by particle induced X-ray emission (PIXE) and ion chromatography analysis. PIXE analysis of the PM2.5 and PM10 samples revealed 15 elements, of which Na, Mg, Si, S, Cl, Ca, Fe and Zn were found to be the major components. Ionic species were Cl-, NO2-, NO3-, SO4(2-), Na+, NH4+, K+ and Ca2+. Concentrations of elements and ionic species under the sampling condition of 60%-revolution/40%-load were highest in comparison with those of the other sampling conditions. The elemental and ionic species data were compared for PM2.5 and PM10; PM2.5 concentrations were 70% or more of PM10 concentrations for the majority of elements, and concentrations of ionic species in PM2.5 and PM10 were almost identical. 相似文献
93.
Issei Otsuka Ryosuke Sakai Toshifumi Satoh Ryohei Kakuchi Harumi Kaga Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):5855-5863
A poly(phenylacetylene) bearing a polycarbohydrate ionophore as a graft chain (copolymer 4 ) was synthesized by the copolymerization of end‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐O‐ethyl‐D ‐glucitol with a 4‐ethynylbenzoyl group (macromonomer 2 ) with phenylacetylene. Copolymer 4 showed a split‐type circular dichroism (CD) in the long absorption region of the conjugated polymer backbone (280–500 nm), and the CD pattern varied in response to external stimuli, such as the solvents and temperature. This suggested that 4 had a predominantly one‐handed helical conformation in the polyacetylene backbone. The CD pattern of 4 was completely inverted by the formation of a complex between the macromolecular ionophore units and the selected metal cations, that is, Ba2+, Pb2+, Sr2+, Na+, and Li+. This suggested that copolymer 4 underwent a helix–helix transition through the host–guest complexation with achiral inorganic metal cations. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5855–5863, 2005 相似文献
94.
V. V. Brazhkin Y. Katayama A. G. Lyapin S. V. Popova Y. Inamura H. Saitoh W. Utsumi 《JETP Letters》2005,82(11):713-718
The results of investigating the phase diagrams of ZnCl2 and AlCl3 halides, as well as the structure of the shortrange order of the corresponding melts under pressures up to 6.5 GPa, by the method of energy-dispersive x-ray diffraction are reported. When a ZnCl2 crystal is compressed, a phase transition occurs from the γ phase (HgI2 structure type) to the δ phase (distorted CdI2 structure, WTe2 type). The structural studies of the liquid state of ZnCl2 and AlCl3 indicate that the intermediate-range order decreases rapidly in the tetrahedral network of both melts as the pressure increases to 1.8 and 2.3 GPa for ZnCl2 and AlCl3, respectively. With further compression, the transitions in both melts occur with a change in the structure of the short-range order and with an increase in the coordination number. In this case, the transition in AlCl3 occurs at ≈4 GPa and is a sharp first order transition, whereas the transition in ZnCl2 occurs more smoothly in a pressure range of 2–4 GPa with a maximum intensity near 3 GPa. Thus, the AlCl3 and ZnCl2 compounds exemplify the existence of two phenomena—gradual decay of intermediate-range structural correlations and a sharper liquid-liquid coordination transition. 相似文献
95.
N. Hashimoto T.R. Saitoh G. Sletten R.A. Bark M. Bergström K. Furuno T. Komatsubara T. Shizuma S. Törmänen P.G. Varmette 《The European Physical Journal A - Hadrons and Nuclei》1998,2(4):327-330
Abstact: High-spin states in 183Re have been studied using the 176Yb(11B,4n) reaction at 52 and 57 MeV. Two high-K bands have been observed directly by a time-correlated γ-γ coincidence measurement. One of the bands is built on an isomeric
K
π=(25/2)+ state at E
x= 1908 keV with a half-life of 0.82(2) ms. The other band, assigned as K
π=(29/2)− at E
x= 2739 keV, decays to the (25/2)+ band. These bands are interpreted as three-quasiparticle structures, π(5/2)+[402] &⊗ν(9/2)+[624] ⊗ν(11/2)+[615] for the (25/2)+ band and π(9/2)−[514] ⊗ν(9/2)+[624] ⊗ν(11/2)+[615] for the (29/2)− band. The K
π= (29/2)− band becomes strongly Coriolis mixed with increasing spin and is gradually changing into a low-K s-band structure.
Received: 20 April 1998 相似文献
96.
Masashi Nakagawa Tatsuo Iwasa Satoshi Kikkawa Toshifumi Takao Yasutsugu Shimonishi Motoyuki Tsuda 《Photochemistry and photobiology》1997,65(1):187-191
Abstract— We determined the structure and site of fatty acid incorporated in octopus rhodopsin using a combination of fluorescence label and enzymatic cleavage methods in conjunction with fast-atom bombardment (FAB) mass spectrometry. A single peptide containing two adjacent cysteines, Cys337 and Cys338, was successfully isolated using the fluorescence from a dye conjugated to Cys345. The FAB mass spectrometric analysis of the peptide (323phe-340 phe) revealed that two palmitoyl groups are linked to Cys337 and Cys338 via thioester bonds in octopus rhodopsin as in bovine rhodopsin. 相似文献
97.
Toshifumi Miyazawa Toshihiko Otomatsu Takashi Yamada Shigeru Kuwata 《Tetrahedron letters》1984,25(7):771-772
Copper(II) chloride was found to be an extremely efficient additive suppressing racemization in the carbodiimide mediated couplings. 相似文献
98.
Okimichi Yano Susumu Saito Yoshio Sato Toshifumi Takeda Atsushi Tanaka Yasaku Wada 《Journal of Polymer Science.Polymer Physics》1981,19(2):221-227
The dielectric loss of high-density polyethylene was measured from 1 kHz to 100 MHz with the improved calorimetric method at liquid-helium temperature for samples with different oxidation times t. Two loss peaks, centered at ca. 4 kHz and at 1 MHz, both increase in height with increasing t. On the bases of these results along with previously reported ones, the low-frequency and high-frequency losses are ascribed to the tunneling of protons of OH groups in crystalline and amorphous regions, respectively. 相似文献
99.
100.