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排序方式: 共有230条查询结果,搜索用时 250 毫秒
11.
Dr. Marina Büchert Torben Steenbock Christian Lukaschek Marie C. Wolff Prof. Dr. Carmen Herrmann Prof. Dr. Jürgen Heck 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(44):14351-14361
Parallel alignment of dipolar electron‐donor–π‐bridge‐electron‐acceptor entities can strongly enhance their nonlinear optical properties. This favorable arrangement can be in principle achieved by linking these units covalently or through metal coordination. Four dipolar single‐strand chromophores decorated with a 5‐electron‐donor–5′‐electron‐acceptor‐modified 2,2′‐bipyridine functionality were synthesized. For two of these chromophores triple‐stranded dendritic structures were successfully formed. All of the compounds were characterized with respect to their linear and nonlinear optical properties. For the aldehyde derivatives an enhancement of the first hyperpolarizability of 4.5 rather than 3 was obtained when going from single to triple strands. Theoretical calculations with density functional theory suggest that interstrand transitions contribute to the optical properties of the dendritic structures. 相似文献
12.
A simple Maxwell-Wagner-Butler-Volmer approach to the impedance of the hydrogen electrode in a nafion fuel cell 总被引:1,自引:0,他引:1
A simple one-dimensional model of the impedance of a hydrogen/Nafion electrode is set up combining the usual Maxwell-Wagner approach for linear, homogeneous, and isotropic media with the linearized Butler-Volmer equation for the interfacial, electrochemical reaction. Only one relaxation semicircle is normally seen in the Nyquist diagram, but a low-frequency arc may appear at high overvoltages. The model is described by only two dimensionless parameters (in addition to the dimensionless frequency). These parameters are related to the double-layer capacitance and to the interfacial electrochemical reaction rate, respectively. With some adjustments, the model can be used to explain the observed equilibrium impedance from 40 to 70 degrees C of a symmetric cell of the type C/Pt/H(2)|Nafion 117/H(2)/Pt/C. The hydrogen electrodes in this cell were built up as a disperse multiphase region (carbon, platinum grains, Nafion 117, and hydrogen gas) as commonly done in solid polymer fuel cells. 相似文献
13.
Niels Olaf Østerberg Torben Smith Sørensen Jørgen Birger Jensen 《Journal of Electroanalytical Chemistry》1981,119(1):93-108
The emf of electrochemical cells containing various sorts of salt bridges between various concentrations has been measured. The net diffusion potential over a salt bridge has been treated theoretically. An expression to calculate the net diffusion potential has been derived and tested on values estimated from the emf measurements. A merit factor has been calculated for a saturated KCl bridge separating two HCl solutions and compared with the merit factor estimated from emf measurements on the cell:Pt|Ag|AgCl, HCl(c1)|KCl(sat)|HCl(c2), AgCl|Ag|Pt The practical performance of two commonly used reference electrodes with salt bridges has been tested on emf measurements on KBr solutions. 相似文献
14.
Nour-Mohhamadi F Nguyen SD Boschloo G Hagfeldt A Lund T 《The journal of physical chemistry. B》2005,109(47):22413-22419
The oxidative degradation rate, kdeg, of the solar cell dye (Bu4N+)2[Ru(dcbpyH)2(NCS)2]2-, referred to as N719 or [RuL2(NCS)2], was obtained by applying a simple model system. Colloidal solutions of N719-dyed TiO2 particles in acetonitrile were irradiated with 532-nm monochromatic light, and the sum of the quantum yields for the oxidative degradation products [RuL2(CN)2], [RuL2(NCS)(CN)], and [RuL2(NCS)(ACN)], Phideg, was obtained at eight different light intensities in the range of 0.1-16.30 mW/cm2 by LC-UV-MS. The Phideg values decreased from 3.3 x 10-3 to 2.0 x 10-4 in the applied intensity range. By using the relation kdeg = Phidegkback and back electron-transfer reaction rates, kback, obtained with photoinduced absorption spectroscopy, it was possible to calculate an average value for the oxidative degradation rate of N719 dye attached to TiO2 particles, kdeg = 4.0 x 10-2 s-1. The stability of N719 dye during solar cell operation was discussed based on this number, and on values of the electron-transfer rate between [Ru(III)L2(NCS)2] and iodide ion that are available in the literature. 相似文献
15.
Torben Maack Bisgaard 《Analysis Mathematica》2001,27(1):37-54
For >2, let Q
+() be the infimum of those q>0 for which the function n epn is positive definite on N
0 for every pq. We shall prove that Q
+()0 as 2. 相似文献
16.
Martin Sahlberg Premysl Beran Thomas Kollin Nielsen Yngve Cerenius Krisztina Kads Marko P.J. Punkkinen Levente Vitos Olle Eriksson Torben R. Jensen Yvonne Andersson 《Journal of solid state chemistry》2009,182(11):3113-3117
A novel aluminium rich alloy for hydrogen storage has been discovered, ScAl0.8Mg0.2, which has very promising properties regarding hydrogen storage capacity, kinetics and stability towards air oxidation in comparison to hydrogen absorption in state-of-the-art intermetallic compounds. The absorption of hydrogen was found to be very fast, even without adding any catalyst, and reversible. The discovered alloy crystallizes in a CsCl-type structure, but decomposes to ScH2 and Al(Mg) during hydrogen absorption. Detailed analysis of the hydrogen absorption in ScAl0.8Mg0.2 has been performed using in situ synchrotron radiation powder X-ray diffraction, neutron powder diffraction and quantum mechanical calculations. The results from theory and experiments are in good agreement with each other. 相似文献
17.
Management review of the quality-management system is an item in many quality standards and a requirement of the ISO 9001:2000
standard and of laboratory standards ISO 15189 and ISO 17125, and others. These reviews are conducted to ensure that the top
management is informed and involved in the quality-management system with respect to continuing adequacy and effectiveness,
and opportunities for improvement of the system. The management review is a process that should be conducted and audited utilizing
the process approach. A process approach is defined as “An activity using resources and managed in order to enable the transformation
of inputs into outputs” (ISO 9001:2000). All identified main processes in the quality system should be monitored through data
collection by appropriate methods, assuring that data are valid, representative, and adequate. For management review data
must be collected and presented in an accessible form so that processes can be evaluated according to objectives, goals, resources,
etc. On the basis of this information the laboratory management makes the necessary decisions and ensure that actions are
taken that improve the effectiveness of the quality-management system. As output from the management review process, there
should be evidence of decisions regarding: change of quality policy and objectives; plans and possible actions for improvements;
corrective actions as appropriate; increased customer satisfaction; and planning of resources needs. Identification of the
processes involved and using the process approach in the management review ensures the continual improvement of the quality
system.
Presented at the conference Quality in the Spotlight, March 2006, Antwerp, Belgium. 相似文献
18.
It is shown how to compute the lexicographically maximum suffix of a string of n?2 characters over a totally ordered alphabet using at most (4/3)n−5/3 three-way character comparisons. The best previous bound, which has stood unchallenged for more than 25 years, is (3/2)n−O(1) comparisons. We also prove an interesting property of an algorithm for computing the maximum suffix both with respect to a total order < and with respect to its inverse order >. 相似文献
19.
Luca Pasquini Elsa Callini Matteo Brighi Federico Boscherini Amelia Montone Torben R. Jensen Chiara Maurizio Marco Vittori Antisari Ennio Bonetti 《Journal of nanoparticle research》2011,13(11):5727-5737
We report on the hydrogen storage behaviour of Mg nanoparticles (NPs) (size range 100 nm–1 μm) with metal-oxide core–shell
morphology synthesized by inert gas condensation and decorated by transition metal (TM) (Pd or Ti) clusters via in situ vacuum
deposition. The structure and morphology of the as-prepared and hydrogenated NPs is studied by electron microscopy, X-ray
diffraction including in situ experiments and X-ray absorption spectroscopy, in order to investigate the relationships with
the hydrogen storage kinetics measured by the volumetric Sieverts method. With both Pd and Ti, the decoration deeply improves
the hydrogen sorption properties: previously inert NPs exhibit complete hydrogenation with fast transformation kinetics, good
stability and reversible gravimetric capacity that can attain 6 wt%. In the case of Pd-decoration, the occurrence of Mg–Pd
alloying is observed at high temperatures and in dependence of the hydrogen pressure conditions. These structural transformations
modify both the kinetics and thermodynamics of hydride formation, while Ti-decoration has an effect only on the kinetics.
The experimental results are discussed in relation with key issues such as the amount of decoration, the heat of mixing between
TM and Mg and the binding energy between TM and hydrogen. 相似文献
20.
Torben Maack Bisgaard 《Czechoslovak Mathematical Journal》2002,52(1):155-196
We characterize finitely generated abelian semigroups such that every completely positive definite function (a function all of whose shifts are positive definite) is an integral of nonnegative miltiplicative real-valued functions (called nonnegative characters). 相似文献