全文获取类型
收费全文 | 187篇 |
免费 | 6篇 |
国内免费 | 2篇 |
专业分类
化学 | 92篇 |
力学 | 9篇 |
综合类 | 2篇 |
数学 | 67篇 |
物理学 | 25篇 |
出版年
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 6篇 |
2013年 | 14篇 |
2012年 | 9篇 |
2011年 | 12篇 |
2010年 | 5篇 |
2009年 | 7篇 |
2008年 | 9篇 |
2007年 | 3篇 |
2006年 | 7篇 |
2005年 | 9篇 |
2004年 | 7篇 |
2003年 | 11篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 7篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1961年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有195条查询结果,搜索用时 15 毫秒
101.
In this study, we demonstrate, for the first time to our knowledge, electronic wavelength sweeping of a continuous wave Ti:sapphire laser using an acousto-optic tunable filter (AOTF). The dependence of the laser output on the sweeping frequency and on the spectral tuning range was investigated. The lasing up to maximum scan rate 11 kHz for 10 nm tuning range and 5 W pump power was achieved. We detected and quantified asymmetry in the output for opposite scan directions. We theoretically characterized the maximum sweeping frequency for swept lasers with AOTFs and confirmed calculated results by measurements. 相似文献
102.
103.
Perrée J van Leeuwen TG Velema E Smeets M de Kleijn D Borst C 《Photochemistry and photobiology》2002,75(1):68-75
In this study we have explored the potential of PUVB (8-MOP + UVB) therapy for the reduction of luminal narrowing after arterial injury. In 15 rabbits, balloon dilation of iliac arteries was performed. In 20 arteries, dilation was combined with the delivery of pulsed ultraviolet light B (UVB) irradiation with 10 arteries being previously subjected to sensitizer infusion. Changes in vessel diameter, proliferation and extracellular matrix protein content at 6 weeks were evaluated by means of angiography and histomorphometry-immunohistochemistry. We found that PUVB, applied at the time of dilation, induced reduction in late loss (LL) at 6 weeks (percutaneous transluminal angioplasty vs UVB vs PUVB: 0.64 +/- 0.15 mm vs 0.61 +/- 0.05 mm vs 0.29 +/- 0.05 mm; p = 0.018). The same holds true for constrictive remodeling (0.53 +/- 0.15 mm vs 0.45 +/- 0.06 mm vs 0.15 +/- 0.05 mm; p = 0.016). In the irradiation groups, LL was independent of acute gain (AG), as opposed to the control. Collagen content increased significantly after PUVB in media and adventitia, without increased cellular proliferation in all vessel layers. Thus, PUVB at the time of dilation reduced luminal narrowing at follow-up without effecting proliferation. This effect was independent of AG and was associated with increased collagen content in media and adventitia. 相似文献
104.
105.
Faber DJ Aalders MC Mik EG Hooper BA van Gemert MJ van Leeuwen TG 《Physical review letters》2004,93(2):028102
We report on the scattering properties of oxygenated and deoxygenated whole blood from 250 to 1000 nm. We determine the complex refractive index of oxygenated and deoxygenated hemoglobin using a Kramers-Kronig analysis and optical coherence tomography measurements. Combining these data with Mie theory, the scattering properties are calculated. The strong oxygen saturation dependent scattering effects should be taken into account in the data analysis of optical oxymetry. 相似文献
106.
Let be a prime number and let be the group of all invertible matrices over the prime field . It is known that every irreducible -module can occur as a submodule of , the polynomial algebra with variables over . Given an irreducible -module , the purpose of this paper is to find out the first value of the degree of which occurs as a submodule of , the subset of consisting of homogeneous polynomials of degree . This generalizes Schwartz-Tri's result to the case of any prime .
107.
Rheological and fracture properties of optimally mixed flour doughs from three wheat cultivars which perform differently in cereal products were studied in uniaxial and biaxial extension. Doughs were also tested in small angle sinusoidal oscillation. In accordance with previously published results the linear region was found to be very small. The rheological properties at small deformations hardly depended on the cultivar. A higher water content of the dough resulted in a lower value for the storage modulus and a slightly higher value for tan . For both uniaxial and biaxial extension a more than proportional increase in stress was found with increasing strain, a phenomenon called strain hardening. In uniaxial extension (i) stresses at a certain strain were higher and (ii) the stress was less dependent on the strain rate than in biaxial extension. This indicates that in elongational flow orientational effects are of large importance for the mechanical properties of flour dough. This conclusion is consistent with published data on birefringence of stretched gluten. Fracture stress and strain increased with increasing deformation rate. The observed time-dependency of fracture properties can best be explained by inefficient transport of energy to the crack tip. Presumably, this is caused by energy dissipation due to inhomogeneous deformation because of friction between structural elements, e.g. between dispersed particles and the network. Differences in the rheological properties at large deformations between the cultivars were observed with respect to (i) stress, (ii) strain hardening, (iii) strain rate dependency of the stress, (iv) fracture properties and (v) the stress difference between uniaxial and biaxial extension. 相似文献
108.
Cellulose nanopaper is a strong and tough fibrous network composed of hydrogen bonded cellulose nanofibres. Upon loading, cellulose nanopaper exhibits a long inelastic portion of the stress–strain curve which imparts high toughness into the material. Toughening mechanisms in cellulose nanopaper have been studied in the past but mechanisms proposed were often rather speculative. In this paper, we aim to study potential toughening mechanisms in a systematic manner at multiple hierarchical levels in cellulose nanopaper. It was proposed that the toughness of cellulose nanopaper is not, as is often assumed, entirely caused by large scale inter-fibre slippage and reorientation of cellulose nanofibres. Here it is suggested that dominant toughening mechanism in cellulose nanopaper is associated with segmental motion of molecules facilitated by the breakage of hydrogen bonds within amorphous regions . 相似文献
109.
That QT Jossang J Jossang A Kim PP Jaureguiberry G 《The Journal of organic chemistry》2007,72(19):7102-7105
Two new sesquiterpene lactones, wedelolides A (1) and B (2), were isolated by bioassay-guided fractionation from the leaves of Wedelia trilobata, together with known trilobolides 6-O-isobutyrate (3) and 6-O-methacrylate (4). The compounds 1 and 2 were the first examples of an unprecedented framework: a novel sesquiterpene delta-lactone, (9R)-eudesman-9,12-olide. The structures of the antimalarial wedelolides A (1) and B (2) were determined on the basis of MS and 2D NMR spectral analysis. The absolute configuration of eight carbon stereocenters of compounds 1 and 2 was determined to be 1S,4S,5S,6R,7S,8S,9R,10S by mean of auxiliary chiral MTPA derivatives. 相似文献
110.
Ganzevles RA Kosters H Vliet Tv Stuart MA de Jongh HH 《The journal of physical chemistry. B》2007,111(45):12969-12976
Because the formation of protein/polysaccharide complexes is dominated by electrostatic interaction, polysaccharide charge density is expected to play a major role in the adsorption behavior of the complexes. In this study, pullulan (a non-charged polysaccharide) carboxylated to four different charge densities (fraction of carboxylated subunits: 0.1, 0.26, 0.51, and 0.56) was used to investigate the effect of charge density on the properties of mixed protein/polysaccharide adsorbed layers at air/water interfaces. With all pullulan samples, soluble complexes with beta-lactoglobulin could be formed at low ionic strength, pH 4.5. It was shown that the higher was the pullulan charge density, the more the increase of surface pressure in time was retarded as compared to that for pure beta-lactoglobulin. The retardation was even more pronounced for the development of the dilatational modulus. The lower dilatational modulus can be explained by the ability of the polysaccharides to prevent the formation of a compact protein layer at the air/water interface due to electrostatic repulsion. This ability of the polysaccharides to prevent "layer compactness" increases with the net negative charge of the complexes. If charge density is sufficient (> or = 0.26), polysaccharides may enhance the cohesion between complexes within the adsorbed layer. The charge density of polysaccharides is shown to be a dominant regulator of both the adsorption kinetics as well as the resulting surface rheological behavior of the mixed layers formed. These findings have significant value for the application of complex protein-polysaccharide systems. 相似文献