全文获取类型
收费全文 | 821篇 |
免费 | 37篇 |
国内免费 | 2篇 |
专业分类
化学 | 605篇 |
晶体学 | 8篇 |
力学 | 14篇 |
数学 | 125篇 |
物理学 | 108篇 |
出版年
2023年 | 8篇 |
2022年 | 13篇 |
2021年 | 23篇 |
2020年 | 17篇 |
2019年 | 15篇 |
2018年 | 15篇 |
2017年 | 19篇 |
2016年 | 35篇 |
2015年 | 30篇 |
2014年 | 29篇 |
2013年 | 48篇 |
2012年 | 60篇 |
2011年 | 54篇 |
2010年 | 42篇 |
2009年 | 24篇 |
2008年 | 50篇 |
2007年 | 49篇 |
2006年 | 58篇 |
2005年 | 44篇 |
2004年 | 22篇 |
2003年 | 28篇 |
2002年 | 16篇 |
2001年 | 9篇 |
2000年 | 5篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 9篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1971年 | 2篇 |
排序方式: 共有860条查询结果,搜索用时 10 毫秒
81.
Predictions of the “redox” and “complex” schemes for the Fe3+ catalyzed decomposition of H2O2 have been compared with published and new experimental data by numerical integratior of the appropriate complete sets of differential equations. Apparent discrepancies for the redox scheme at high Fe3+/H2O2 ratios are shown to disappear in the complete treatment, and inconsistencies of the complex scheme with both kinetic data and spectroscopic measurements are pointed out. 相似文献
82.
83.
Ajay N. Jain Thomas G. Dietterich Richard H. Lathrop David Chapman Roger E. Critchlow Jr. Barr E. Bauer Teresa A. Webster Tomas Lozano-Perez 《Journal of computer-aided molecular design》1994,8(6):635-652
Summary Building predictive models for iterative drug design in the absence of a known target protein structure is an important challenge. We present a novel technique, Compass, that removes a major obstacle to accurate prediction by automatically selecting conformations and alignments of molecules without the benefit of a characterized active site. The technique combines explicit representation of molecular shape with neural network learning methods to produce highly predictive models, even across chemically distinct classes of molecules. We apply the method to predicting human perception of musk odor and show how the resulting models can provide graphical guidance for chemical modifications. 相似文献
84.
Attempts to characterize nucleic acid-silver interactions raise questions about how the free nucleic acid bases interact with silver ions in dilute aqueous solution. Studies of ultraviolet and infrared dichroism lead to the conclusion that with silver(I) ions in dilute solution adenine forms linear polymers, whereas 1-methyladenine forms dimers. The composition and structure of the complexes are further discussed against the background of the spectroscopic results. 相似文献
85.
We present a novel Monte Carlo algorithm for N diffusing finite particles that react on collisions. Using the theory of first-passage processes and time dependent Green's functions, we break the difficult N-body problem into independent single- and two-body propagations circumventing numerous diffusion hops used in standard Monte Carlo simulations. The new algorithm is exact, extremely efficient, and applicable to many important physical situations in arbitrary integer dimensions. 相似文献
86.
Highly photoconductive properties are reported for organic-inorganic hybrid sol-gel thin film materials composed of a classical poly(vinylcarbazole)/2,4,7-trinitro-9-fluorenone (PVK/TNF) polymeric mixture, entrapped in a SiO(2) matrix, whose pores have been chemically modified by organic functional groups. The highest photosensitivity obtained, 3.4 x 10(-10) cm Omega(-1) W(-1) at E 22 V microm(-)1, at the optimum molar ratio between the active components, TNF, PVK, and SiO(2), is in the range of the highest values ever reported for any PVK/TNF-based classical photoconductive material. It is demonstrated that the PVK/TNF-based sol-gel films follow Onsager's classical charge-generation model. The analysis of the photocurrent efficiency (Phi) of PVK/TNF-based sol-gel films by such a model provides the primary quantum yield of thermalized pair formation and the initial thermalized pair distance, phi(0) = 0.12 and r(0) = 66.1 Angstrom, respectively, for the optimized sample. As a result of Onsager's analysis, a notorious improvement of the photocurrent generation process was achieved for low TNF concentrations. 相似文献
87.
This paper considers Hardy–Lieb–Thirring inequalities for higher order differential operators. A result for general fourth-order
operators on the half-line is developed, and the trace inequality
tr( (-D)2 - CHRd,2\frac1|x|4 - V(x) )-g £ Cgò\mathbbRd V(x)+g+ \fracd4 dx, g 3 1 - \frac d 4,\mathrm{tr}\left( (-\Delta)^2 - C^{\mathrm{HR}}_{d,2}\frac{1}{|x|^4} - V(x) \right)_-^{\gamma}\leq C_\gamma\int\limits_{\mathbb{R}^d} V(x)_+^{\gamma + \frac{d}{4}}\,\mathrm{d}x, \quad \gamma \geq 1 - \frac d 4, 相似文献
88.
89.
90.
Svensson T Andersson M Rippe L Johansson J Folestad S Andersson-Engels S 《Optics letters》2008,33(1):80-82
We present minimalistic and cost-efficient instrumentation employing tunable diode laser gas spectroscopy for the characterization of porous and highly scattering solids. The sensitivity reaches 3 x 10(-6) (absorption fraction), and the improvement with respect to previous work in this field is a factor of 10. We also provide the first characterization of the interference phenomenon encountered in high-resolution spectroscopy of turbid samples. Revealing that severe optical interference originates from the samples, we discuss important implications for system design. In addition, we introduce tracking coils and sample rotation as new and efficient tools for interference suppression. The great value of the approach is illustrated in an application addressing structural properties of pharmaceutical materials. 相似文献
|