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41.
Ngo Ngoc Ha Nguyen Truong Giang Tran Ngoc Khiem Nguyen Duc Dung Tom Gregorkiewicz 《固体物理学:研究快报》2016,10(11):824-827
Photogenerated carriers in Si–Ge alloy nanocrystals (NCs) prepared by co‐sputtering method were investigated by mean of transient induced absorption. The carrier relaxation features multiple components, with three decay life times of τ ≈ 600 fs, 12 ps, and 15 ns, established for Si0.2Ge0.8 alloy NCs of a mean crystal size of 9 nm and standard deviation of 3 nm. Deep carrier traps, identified at the boundary between the NCs and the SiO2 host with the ionization energy of about 1 eV, are characterized by a long‐range Coulombic potential. These are responsible for rapid depletion of free carrier population within a few picoseconds after the excitation, which explains the low emissivity of the investigated materials, and also sheds light on the generally low luminescence of Si/Ge and Ge NCs. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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Clear evidence for symplectic symmetry in low-lying states of 12C and 16O is reported. Eigenstates of 12C and 16O, determined within the framework of the no-core shell model using the J-matrix inverse scattering potential with A相似文献
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Víctor Manuel Castor-Villegas José Manuel Guevara-Vela Wilmer E. Vallejo Narváez Ángel Martín Pendás Tomás Rocha-Rinza Alberto Fernández-Alarcón 《Journal of computational chemistry》2020,41(26):2266-2277
Hydrogen bonds (HB) are arguably the most important noncovalent interactions in chemistry. We study herein how differences in connectivity alter the strength of HBs within water clusters of different sizes. We used for this purpose the interacting quantum atoms energy partition, which allows for the quantification of HB formation energies within a molecular cluster. We could expand our previously reported hierarchy of HB strength in these systems (Phys. Chem. Chem. Phys., 2016, 18 , 19557) to include tetracoordinated monomers. Surprisingly, the HBs between tetracoordinated water molecules are not the strongest HBs despite the widespread occurrence of these motifs (e.g., in ice Ih). The strongest HBs within H2O clusters involve tricoordinated monomers. Nonetheless, HB tetracoordination is preferred in large water clusters because (a) it reduces HB anticooperativity associated with double HB donors and acceptors and (b) it results in a larger number of favorable interactions in the system. Finally, we also discuss (a) the importance of exchange-correlation to discriminate among the different examined types of HBs within H2O clusters, (b) the use of the above-mentioned scale to quickly assess the relative stability of different isomers of a given water cluster, and (c) how the findings of this research can be exploited to indagate about the formation of polymorphs in crystallography. Overall, we expect that this investigation will provide valuable insights into the subtle interplay of tri- and tetracoordination in HB donors and acceptors as well as the ensuing interaction energies within H2O clusters. 相似文献
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Tom Scherzer 《Journal of Polymer Science.Polymer Physics》1996,34(3):459-470
Rheo-optical FTIR spectroscopy was used for the first time to monitor molecular orientation phenomena in highly crosslinked epoxies. After studying the orientation behavior of epoxy/amine networks during uniaxial deformation above their glass transition temperature in a preceding article, this article deals with the rheo-optical characterization of the deformation process of those epoxy systems below Tg. The orientation behavior is influenced by the different molecular structure of the constituents and the free volume entrapped in the resins. Yield strain and tensile modulus are correlated with the slope of the orientation function. The orientation function was found to show an abrupt change of its slope in the yield point region. This phenomenon is discussed with respect to the mechanism of plastic deformation. © 1996 John Wiley & Sons, Inc. 相似文献
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Tom Lowrie 《International Journal of Computers for Mathematical Learning》2002,7(3):301-318
This paper explores the way in which young children (6 year olds) made sense of screen-based images on the computer. The participants
were required to interpret 3D-like representations and relate these images to objects in their environment. Both static and
relatively dynamic software programs were used in the investigation. Some of the children could not make links between the
screen representation and the intended three-dimensional (3D) objects. It is argued that young children should be exposed
to activities that establish explicit links between 2D and 3D objects ``away' from the computer before attempting the more
difficult links required to interpret and represent 3D objects in ICT contexts.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献