食品分析中微量元素铁,锰,锌,铜快速分光光度测定法的研究

铁、锰、锌、铜的快速分析常用原子吸收光度法、发射光谱法、等离子体法、电位溶出法等。本文则研究了快速分光光度法，提出了新的分析方法及若干试验研究结果。     

Fabrication of small-sized silver NPs/graphene sheets for high-quality surface-enhanced Raman scattering

In this paper, small-sized and highly dispersed Ag nanoparticles (NPs) supported on graphene nanosheets are fabricated via a strategy for etching a copper template with Ag(+). Firstly, big-sized Cu NPs are supported on graphene, and then the small-sized and highly dispersed Ag NPs are supported on graphene by replacement reaction, mainly making use of graphene passing electrons between Cu and Ag(+). The graphene used in the experiment is prepared by in situ self-generating template and has good dispersion, excellent crystallinity and little defects. Thus, in the process of Ag/graphene synthesis, there is no any intervention of surfactant, which ensures that SERS activity sites have not been passivated. And, the little defects of graphene benefit the excellent conductivity of graphene and ensured the replacement reaction between Cu and Ag(+). The obtained material exhibits significant high-quality and distinctive SERS activity. Especially, a serial new peak of p-aminothiophenol (PATP) is observed, this is suggested two reasons: one is "surface geometry" of the PATP on small-sized Ag NPs and another is the charge-transfer between Ag and graphene.     

ICP—AES法测定银系列合金中的次成份

本法用硝酸溶样，无需分离基体，用ＩＣＰ－ＡＥＳ内标法测定ＡｇＣｕＺｎＣｄＮｉ，ＡｇＣｕＺｎＮｉ及ＡｇＣｕ系列合金中的次成份，该法干扰小，准确度高，快速简单。     

Ši’lnikov Chaos in the Generalized Lorenz Canonical Form of Dynamical Systems

This paper studies the generalized Lorenz canonical form of dynamical systems introduced by elikovský and Chen [International Journal of Bifurcation and Chaos 12(8), 2002, 1789]. It proves the existence of a heteroclinic orbit of the canonical form and the convergence of the corresponding series expansion. The ilnikov criterion along with some technical conditions guarantee that the canonical form has Smale horseshoes and horseshoe chaos. As a consequence, it also proves that both the classical Lorenz system and the Chen system have ilnikov chaos. When the system is changed into another ordinary differential equation through a nonsingular one-parameter linear transformation, the exact range of existence of ilnikov chaos with respect to the parameter can be specified. Numerical simulation verifies the theoretical results and analysis.     

Generating chaos with a switching piecewise-linear controller

This paper introduces a new chaos generator, a switching piecewise-linear controller, which can create chaos from a three-dimensional linear system within a wide range of parameter values. Basic dynamical behaviors of the chaotic controlled system are investigated in some detail. (c) 2002 American Institute of Physics.     

分子系统生物学的数学建模与分析

本质上,分子系统生物学就是要研究分子水平上的各种层次网络,并整合这些网络信息为系统信息。广泛使用的化学主方程为研究生物分子网络提供了一个建模框架,但应用起来具有局限性;传统的矩封闭方法可以简化生物分子网络的研究,但并没有解决反应物种的联合概率分布的重构问题。本文简单介绍了生物分子网络的数学建模与分析,特别地,对生化反应系统提出二项矩的分析方法,它与传统方法相比具有许多优势,如能够降低计算复杂度、方便联合概率分布的重构,甚至可用于非线性行为的线性逼近等。     

俄勒冈振子极限环的唯一性

本文证明了俄勒冈振子中极限环的唯一性．     

A universal unfolding of the Lorenz system

A universal unfolding of the Lorenz system is derived and studied in this paper. Both rigorous theoretical analysis and numerical simulations show that the Lorenz system, the Chen system, and the Lü system belong to the same universal unfolding. Therefore, they all have similar dynamical behaviors in the sense that if the Lorenz system has limit cycles produced from a Hopf bifurcation for a certain set of parameter values, then the other two systems also have limit cycles from the same set of parameter values; and if the Lorenz, Chen, and Lü systems are chaotic for some parameter values (for example, some typical parameter values), respectively, then the homotopic system for the Lorenz system and the Chen system, and the homotopic system for these three systems, are all chaotic within the entire domain of these homotopic parameters.     

赤霉素的快速分光光度测定法的研究

本文对赤霉素的测定提出了一种利用福林反应的快速分光光度法。由于选用适当的测量波长以消除试样溶液中杂质对吸光度的影响和采用快速提取剂以加速试样溶液的制备过程,并研究了测定中的各个环节,使操作手续简化,大大提高了分析速度,增进了测定精度。用本法所得结果与通用的荧光法相符。