The K–nucleus cross sections in relativistic non-linear models

The K⁺−nucleus cross sections have been calculated in relativistic non-linear models taking into account the in-medium modifications of nucleons and mesons properties. More precisely, we have taken into account both the dressing of the nucleon effective mass by the scalar nuclear field in the target and the coupling of the mesons exchanged between the K⁺ and the nucleons to the polarization of the medium. First, using the most recent relativistic non-linear models, the in-medium σ, ω and ρ meson masses have been obtained in the nuclear matter rest frame. The influence of the non-linear contributions on the K⁺−nucleus cross sections has then been studied. Finally, we have compared our results with the experimental data.     

Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates

Two hydrated uranyl arsenates and a uranyl phosphate were synthesized by hydrothermal methods in the presence of amine structure-directing agents and their structures determined: (N₂C₆H₁₄)[(UO₂)(AsO₄)]₂(H₂O)₃, DabcoUAs, {NH(C₂H₅)₃}[(UO₂)₂(AsO₄)(AsO₃OH)], TriethUAs, and (N₂C₄H₁₂)(UO₂)[(UO₂)(PO₄)]₄(H₂O)₂, PiperUP. Intensity data were collected at room temperature using MoKα X-radiation and a CCD-based area detector. The crystal structures were refined by full-matrix least-squares techniques on the basis of F² to agreement indices (DabcoUAs, TriethUAs, PiperUP) wR₂=5.6%, 8.3%, 7.2% for all data, and R₁=2.9%, 3.3%, 4.0%, calculated for 1777, 5822, 9119 unique observed reflections (|F_o|?4σ_F), respectively. DabcoUAs is monoclinic, space group C2/m, Z=2, a=18.581(1), b=7.1897(4), c=7.1909(4) Å, β=102.886(1)°, V=936.43(9) Å³, D_calc=3.50 g/cm³. TriethUAs is monoclinic, space group P2₁/n, Z=4, a=9.6359(4), b=18.4678(7), c=10.0708(4) Å, β=92.282(1)°, V=1790.7(1) Å³, D_calc=3.41 g/cm³. PiperUP is monoclinic, space group Pn, Z=2, a=9.3278(4), b=15.5529(7), c=9.6474(5) Å, β=93.266(1)°, V=1397.3(1) Å³, D_calc=4.41 g/cm³. The structure of DabcoUAs contains the autunite-type sheet formed by the sharing of vertices between uranyl square bipyramids and arsenate tetrahedra. The triethylenediammonium cations are located in the interlayer along with two H₂O groups and are disordered. Both TriethUAs and PiperUP contain sheets formed of uranyl pentagonal bipyramids and tetrahedra (arsenate and phosphate, respectively) with the uranophane sheet-anion topology. In TriethUAs, triethlyammonium cations are located in the interlayer. In PiperUP, the sheets are connected by a uranyl pentagonal bipyramid that shares corners with phosphate tetrahedra of adjacent sheets, resulting in a framework with piperazinium cations and H₂O groups in the cavities of the structure.     

Stable boundary layers in a diffusion problem with nonlinear reaction at the boundary

We prove the existence of nonconstant stable stationary solutions of an evolution problem with a nonlinear reaction acting on the boundary. These solutions present layers at certain points of the boundary. We also study the behavior of these solutions as the small parameter appearing in the equation approaches zero and show some stability properties of the profiles given by these equilibrium solutions.     

A comparison of a theoretical model for quasi-statically and dynamically induced environmental vibration from trains with measurements

This paper presents comparisons between a theoretical ground vibration model and measured data at three sites. The model, which is briefly outlined here, encompasses both the quasi-static and dynamic mechanisms of excitation. The vertical dynamics of a number of vehicles travelling at a constant speed on an infinite track are coupled to a semi-analytical model for a three-dimensional layered ground. This model is also used to demonstrate the roles of the two components of vibration at different frequencies and for train speeds below and above the lowest ground wave speed. It is found that, in most practical cases, the dynamic component gives rise to the higher level of vibration.     

Four‐dimensional couplings among BF and matter theories from BRST cohomology

The local and manifestly covariant Lagrangian interactions in four spacetime dimensions that can be added to a “free” model that describes a generic matter theory and an abelian BF theory are constructed by means of deforming the solution to the master equation on behalf of specific cohomological techniques.     

The reaction NN→NNπ in effective field theory

A consistent counting scheme is presented that allows to study the reactions NN → NNπ within an effective field theory. Within this scheme the chiral expansion is shown to converge contrary to claims in the literature.     

Promiscuity in Antibody Catalysis: Esterolytic Activity of the Decarboxylase 21D8

The high structural similarity of decarboxylase antibody 21D8 and esterase antibody 48G7 suggests that 21D8 might also possess hydrolytic activity. Kinetic investigations show that 21D8 does promote the selective hydrolysis of methyl 4‐nitrophenyl carbonate and sodium 4‐(acetoxy)benzenesulfonate with catalytic proficiencies (k_cat/K_m)/k_un of ca. 10⁵ M ^?1. The ability of 21D8 to accelerate a reaction for which it was not developed suggests that certain antibody scaffolds are intrinsically predisposed toward catalysis, a property that can be enhanced and refined during affinity maturation in response to a transition‐state analog. At the same time, however, the restricted structural diversity of the immune system may ultimately limit the catalytic efficiency that can be achieved.     

On similarity and scaling of the radiative transfer equation

The present paper shows how the well-known similarity and scaling concepts are properties of the radiative transfer equation and not specifically of the degree of anisotropy of the phase function. It is shown that the key assumption regarding the angular dependence of the radiative field is essential in determining both the value for the parameter used to scale the radiative transfer, as well as the number of streams used in calculating the radiances for various atmospheric problems. Simulations performed on realistic type of cirrus clouds, characterized by strongly anisotropic functions, demonstrates the superior computational advantage for accurately simulating radiances. A new approach for determining the scaling parameter is introduced.