全文获取类型
收费全文 | 149646篇 |
免费 | 1341篇 |
国内免费 | 418篇 |
专业分类
化学 | 81710篇 |
晶体学 | 2414篇 |
力学 | 6125篇 |
综合类 | 3篇 |
数学 | 14024篇 |
物理学 | 47129篇 |
出版年
2021年 | 1049篇 |
2020年 | 1216篇 |
2019年 | 1275篇 |
2018年 | 1660篇 |
2017年 | 1710篇 |
2016年 | 2584篇 |
2015年 | 1588篇 |
2014年 | 2389篇 |
2013年 | 6158篇 |
2012年 | 4974篇 |
2011年 | 6092篇 |
2010年 | 4246篇 |
2009年 | 4265篇 |
2008年 | 5848篇 |
2007年 | 5632篇 |
2006年 | 5483篇 |
2005年 | 5053篇 |
2004年 | 4546篇 |
2003年 | 4198篇 |
2002年 | 4079篇 |
2001年 | 5579篇 |
2000年 | 4016篇 |
1999年 | 3098篇 |
1998年 | 2135篇 |
1997年 | 2232篇 |
1996年 | 2117篇 |
1995年 | 1952篇 |
1994年 | 1946篇 |
1993年 | 1762篇 |
1992年 | 2251篇 |
1991年 | 2318篇 |
1990年 | 2169篇 |
1989年 | 2130篇 |
1988年 | 2106篇 |
1987年 | 2118篇 |
1986年 | 1925篇 |
1985年 | 2422篇 |
1984年 | 2444篇 |
1983年 | 1940篇 |
1982年 | 1959篇 |
1981年 | 1790篇 |
1980年 | 1775篇 |
1979年 | 2066篇 |
1978年 | 2148篇 |
1977年 | 2075篇 |
1976年 | 2009篇 |
1975年 | 1894篇 |
1974年 | 1878篇 |
1973年 | 1912篇 |
1972年 | 1250篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
Hiroaki Miyagawa Michael J. Rich Lawrence T. Drzal 《Journal of Polymer Science.Polymer Physics》2004,42(23):4391-4400
The thermophysical and mechanical properties of a nanocomposite material composed of amine‐cured diglycidyl ether of bisphenol A (DGEBA) reinforced with organomontmorillonite clay are reported. The storage modulus at 100 °C, which was above the glass‐transition temperature (Tg), increased approximately 350% with the addition of 10 wt % (6.0 vol %) of clay. Below the Tg, the storage modulus at 30 °C increased 50% relative to the value of unfilled epoxy. It was determined that the Tg linearly increased as a function of clay volume percent. The tensile modulus of epoxy at room temperature increased approximately 50% with the addition of 10 wt % of clay. The reinforcing effect of the organoclay nanoplatelets is discussed with respect to the Tandon–Weng and Halpin–Tsai models. A pseudoinclusion model is proposed to describe the behavior of randomly oriented, uniformly dispersed platelets in nanocomposite materials. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4391–4400, 2004 相似文献
62.
Raviraj M Kulkarni Dinesh C Bilehal Sharanappa T Nandibewoor 《Analytical sciences》2004,20(4):743-747
The kinetics of oxidation of isoniazid in acidic medium was studied spectrophotometrically. The reaction between QDC and isoniazid in acid medium exhibits (4:1) stoichiometry (QDC:isoniazid). The reaction showed first order kinetics in quinolinium dichromate (QDC) concentration and an order of less than unity in isoniazid (INH) and acid concentrations. The oxidation reaction proceeds via a protonated QDC species, which forms a complex with isoniazid. The latter decomposes in a slow step to give a free radical derived from isoniazid and an intermediate chromium(V), which is followed, by subsequent fast steps to give the products. The reaction constants involved in the mechanism are evaluated. Isoniazid was analyzed by kinetic methods in pure and pharmaceutical formulations. 相似文献
63.
K. Sakurai Y. Kondo K. Miyazaki T. Okamoto S. Irie T. Sasaki 《Journal of Polymer Science.Polymer Physics》2004,42(13):2595-2603
Aiming to develop a high‐performance fiber‐reinforced rubber from styrene–butadiene rubber (SBR), we applied a special technique using electron‐beam (EB)‐irradiation‐induced graft polymerization to ultrahigh‐molecular‐weight‐polyethylene (UHMWPE) fibers. The molecular interaction between the grafted UHMWPE fibers and an SBR matrix was studied through the evaluation of the adhesive behavior of the fibers in the SBR matrix. Although UHMWPE was chemically inert, two monomers, styrene and N‐vinyl formamide (NVF), were examined for graft polymerization onto the UHMWPE fiber surface. Styrene was not effective, but NVF was graft‐polymerized onto the UHMWPE fibers with this special method. A methanol/water mixture and dioxane were used as solvents for NVF, and the effects of the solvents on the grafting percentage of NVF were also examined. The methanol/water mixture was more effective. A grafting percentage of 16.4% was the highest obtained. This improved the adhesive force threefold with respect to that of untreated UHMWPE fibers. These results demonstrated that EB irradiation enabled graft polymerization to occur even on the inert surface of UHMWPE fibers. However, the mechanical properties of the fibers could be compromised according to the dose of EB irradiation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2595–2603, 2004 相似文献
64.
Curtis T. Mcmullen 《Acta Mathematica》2003,191(2):191-223
65.
The form of the probability density derived from the evolution in time of a previously truncated frequency distribution of animal Liveweights is of interest in animal husbandry. Truncated frequency distributions arise when the heavier animals are sold for slaughter and the lighter animals retained. The demands of modern quality assurance schemes require that, given information on animal growth, the farmer is able to estimate the number of animals that would meet the specifications at some time in the future after truncation. Assuming that animal growth can be described by a linear stochastic differential equation, we derive an explicit expression for the probability density of animal Liveweights at any time after the truncation of an initial Gaussian density. It is shown that this probability density converges rapidly to a Gaussian density, so that after about 20 days of typical growth rates for lambs, the resulting density is practically indistinguishable from Gaussian. 相似文献
66.
67.
An all-optical fiber nonlinear Fabry-Perot resonator is proposed. The steady-state model for describing this resonator is developed. The transmission and refection bistabilities are shown numerically. Our results show that the bistability in this system is similar to that in a normal nonlinear Fabry-Perot etalon, except that the characteristics of the bistability can be changed not only by the cavity length but also by the phase shifts of the fiber loop mirrors. 相似文献
68.
Results of experimental investigations of the volt-brightness characteristics, frequency dependences of brightness, and the
directional radiation pattern of electroluminescent MSDM, MSCM, and MSDCM emitters, where M stands for the first transparent
and second nontransparent electrodes, S is a semiconductor, D is a thin-film dielectric, and C is a silicone-based composite
liquid dielectric with a powdered segnetoelectric filler, developed on conventional “smooth” and rough glass substrates are
presented. It is shown that electroluminescent structures on rough surfaces have a brightness approximately two times higher
than that of similar structures developed on a “smooth” substrate.
Ul’yanovsk State University, 42, L. Tolstoi St., Ul’yanovsk, 432700, Russia. Translated from Zhurnal Prikladnoi Spektroskopii,
Vol. 64, No. 4, pp. 507–512, July–August, 1997. 相似文献
69.
T. N. Mamedov V. N. Duginov A. V. Stoykov I. L. Chaplygin D. Herlach U. Zimmermann V. N. Gorelkin J. Major M. Schefzik 《JETP Letters》1998,68(1):64-70
The residual polarization of negative muons in crystal silicon samples with phosphorus (P: 1.6×1013 cm−3) and antimony (Sb: 2×1018 cm−3) impurities is investigated. The measurements are made in a 1000 G magnetic field oriented in a direction transverse to the
muon spin in the temperature range 4–300 K. The relaxation rate and shift of the precession frequency in the silicon sample
with the phosphorus impurity are measured more accurately than previously. It is found that in antimony-doped silicon the
acceptor center
μ
A1 at temperatures below 30 K can be in both ionized and neutral states. The experimental data are interpreted on the basis
of spin-lattice relaxation of the magnetic moment of an acceptor center, formation of acceptor-donor pairs, and recombination
of charge carriers at the acceptor. Preliminary measurements showed a nonzero residual polarization of negative muons in germanium.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 1, 61–66 (10 July 1998) 相似文献
70.
Two groups of 10 speech-language pathology graduate students were each given 7 weeks of singing lessons to determine whether voice lessons could have an effect on their clinical and perceptual skills. Pre-, mid-, and posttests to measure various skills were designed and implemented. With use of paired sample statistical testing, statistically significant results were obtained. In addition, the subjective responses of the students show that the lessons were effective in improving pitch perception, breath control, and legato production or easy onset. This study supports efforts to integrate curricula in vocal performance and speech-language pathology. 相似文献