全文获取类型
收费全文 | 2511篇 |
免费 | 118篇 |
国内免费 | 32篇 |
专业分类
化学 | 1550篇 |
晶体学 | 16篇 |
力学 | 86篇 |
数学 | 610篇 |
物理学 | 399篇 |
出版年
2023年 | 28篇 |
2022年 | 29篇 |
2021年 | 67篇 |
2020年 | 58篇 |
2019年 | 51篇 |
2018年 | 56篇 |
2017年 | 43篇 |
2016年 | 84篇 |
2015年 | 111篇 |
2014年 | 110篇 |
2013年 | 165篇 |
2012年 | 165篇 |
2011年 | 175篇 |
2010年 | 126篇 |
2009年 | 109篇 |
2008年 | 158篇 |
2007年 | 152篇 |
2006年 | 145篇 |
2005年 | 120篇 |
2004年 | 102篇 |
2003年 | 68篇 |
2002年 | 80篇 |
2001年 | 20篇 |
2000年 | 24篇 |
1999年 | 20篇 |
1998年 | 22篇 |
1997年 | 21篇 |
1996年 | 18篇 |
1995年 | 10篇 |
1994年 | 12篇 |
1993年 | 24篇 |
1992年 | 17篇 |
1991年 | 18篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 11篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 10篇 |
1982年 | 14篇 |
1981年 | 24篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1978年 | 14篇 |
1977年 | 14篇 |
1976年 | 9篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1956年 | 6篇 |
排序方式: 共有2661条查询结果,搜索用时 265 毫秒
81.
A detailed chemical kinetic model has been developed for supercritical water oxidation (SCWO) of methylamine, CH3NH2, providing insight into the intermediates and final products formed in this process as well as the dominant reaction pathways. The model was adapted from previous mechanisms, with a revision of the peroxyl radical chemistry to include imine formation, which has recently been identified as the dominant gas-phase pathway in amine oxidation. The developed model can reproduce previous experimental data on methylamine consumption and major product formation to reasonable accuracy, although with deficiencies in describing the induction time. Our simulations indicate that oxidation of the •CH2NH2 radical to methanimine, CH2NH, is the major channel in methylamine SCWO, with subsequent hydrolysis of CH2NH providing the experimentally observed reaction products ammonia and formaldehyde. Integral-averaged reaction rates were used to identify major reaction pathways, and a first-order sensitivity analysis indicated that the concentration of CH3NH2 is most sensitive to OH radical kinetics. Overall, this work clarifies the importance of imine chemistry in the oxidation of nitrogen-containing compounds and indicates that they are necessary to model these compounds in SCWO processes. 相似文献
82.
Nadia Lahrichi Teodor Gabriel Crainic Michel Gendreau Walter Rei Louis-Martin Rousseau 《The Journal of the Operational Research Society》2015,66(1):44-56
The dairy transportation problem (DTP) consists of determining the best routes to be performed for collecting milk from farms and delivering it to processing plants. We study the particular case of the province of Quebec, where the Fédération des producteurs de lait du Québec is responsible for negotiating the transportation costs on behalf of producers. Several issues are highlighted in the actual process of designing contracts such as using historical data. We propose an approach based on scenario analysis that consists of revising both the steps and the information used to construct the routes. We develop a generalized tabu search algorithm that integrates the different characteristics of the DTP. 相似文献
83.
We present some features of the smooth structure and of the canonical stratification on the orbit space of a proper Lie groupoid. One of the main features is that of Morita invariance of these structures—it allows us to talk about the canonical structure of differentiable stratified space on the orbispace (an object analogous to a separated stack in algebraic geometry) presented by the proper Lie groupoid. The canonical smooth structure on an orbispace is studied mainly via Spallek’s framework of differentiable spaces, and two alternative frameworks are then presented. For the canonical stratification on an orbispace, we extend the similar theory coming from proper Lie group actions. We make no claim to originality. The goal of these notes is simply to give a complementary exposition to those available and to clarify some subtle points where the literature can sometimes be confusing, even in the classical case of proper Lie group actions. 相似文献
84.
Ionela Carazeanu Popovici Gabriel Prodan 《Journal of Sol-Gel Science and Technology》2012,63(3):457-462
Fresnoite (Ba2TiSi2O8, BTS) nano-particles were successfully synthesized at a low temperature of 900?°C by a modified Pechini sol?Cgel process with starting materials of Ba(NO3)2, Si(OC2H5)4 and Ti(OC3H7)4. The structural characterization of the precursors and derived synthesized oxide powders is done by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermal analysis (TG-DTG) and electron microscopy (SEM, EDX and TEM) studies. The effect of heat-treating temperature on the crystallinity of the fresnoite was investigated. Combined the XRD data and the strong FTIR peaks assigned to Ti?CO and Si?CO vibration, indicate the formation of fresnoite phase at a temperature of 900?°C. Also the nano-crystals size distribution was studied and the main diameter of nanoparticles was about 47?nm. 相似文献
85.
Roberto Andreani Gabriel Haeser María Laura Schuverdt Paulo J. S. Silva 《Mathematical Programming》2012,135(1-2):255-273
In this work we introduce a relaxed version of the constant positive linear dependence constraint qualification (CPLD) that we call RCPLD. This development is inspired by a recent generalization of the constant rank constraint qualification by Minchenko and Stakhovski that was called RCRCQ. We show that RCPLD is enough to ensure the convergence of an augmented Lagrangian algorithm and that it asserts the validity of an error bound. We also provide proofs and counter-examples that show the relations of RCRCQ and RCPLD with other known constraint qualifications. In particular, RCPLD is strictly weaker than CPLD and RCRCQ, while still stronger than Abadie’s constraint qualification. We also verify that the second order necessary optimality condition holds under RCRCQ. 相似文献
86.
Teodor M. Atanackovic Marko Janev Stevan Pilipovic Dusan Zorica 《Central European Journal of Physics》2013,11(10):1350-1360
In this work we extend our previous results and derive an expansion formula for fractional derivatives of variable order. The formula is used to determine fractional derivatives of variable order of two elementary functions. Also we propose a constitutive equation describing a solidifying material and determine the corresponding stress relaxation function. 相似文献
87.
Barbora Benešová Martin Kružík Gabriel Pathó 《Continuum Mechanics and Thermodynamics》2014,26(5):683-713
We design a new mesoscopic thin-film model for shape-memory materials which takes into account thermomechanical effects. Starting from a microscopic thermodynamical bulk model, we guide the reader through a suitable dimension reduction procedure followed by a scale transition valid for specimen large in area up to a limiting model which describes microstructure by means of parametrized measures. All our models obey the second law of thermodynamics and possess suitable weak solutions. This is shown for the resulting thin-film models by making the procedure described above mathematically rigorous. The main emphasis is, thus, put on modeling and mathematical treatment of joint interactions of mechanical and thermal effects accompanying phase transitions and on reduction in specimen dimensions and transition of material scales. 相似文献
88.
89.
Dorin Ervin Dutkay Gabriel Picioroaga Myung-Sin Song 《Journal of Mathematical Analysis and Applications》2014
We show how some orthonormal bases can be generated by representations of the Cuntz algebra; these include Fourier bases on fractal measures, generalized Walsh bases on the unit interval and piecewise exponential bases on the middle third Cantor set. 相似文献
90.
Teodor M. Atanacković Marko Janev Sanja Konjik Stevan Pilipović 《Continuum Mechanics and Thermodynamics》2017,29(2):569-583
We study waves in a viscoelastic rod whose constitutive equation is of generalized Zener type that contains fractional derivatives of complex order. The restrictions following from the Second Law of Thermodynamics are derived. The initial boundary value problem for such materials is formulated and solution is presented in the form of convolution. Two specific examples are analyzed. 相似文献