Rate equations for an optically-pumped,far infrared laser

Rate equations for an optically-pumped, far infrared laser are developed and solved for the case of a high intensity, pulsed pump beam. Conditions for saturated absorption and for saturated stimulated emission are established. A comparison is made to experimental data for absorption of 9.55 μm, CO₂ laser radiation in CH₃F. Generalized requirements for efficient, high power, FIR laser oscillator-amplifier systems are discussed.     

Long-pulse and CW tests of a 110-GHz gyrotron with an internal,quasi-optical converter

A high-power gyrotron, employing an internal converter that produces a Gaussian-like output mode, has been designed and tested. The tube employed a TE_22.6.1-mode interaction cavity that was designed for operation at a frequency of 110 GHz. An internal converter, consisting of an advanced launcher design and four mirrors, produced a Gaussian mode that had a relatively uniform profile at the tube output window to minimize the peak power density. Tests on the tube resulted in output power levels of 680, 530, and 350 kW for pulse durations of 0.5, 2.0, and 10.0 s, respectively. Measurements of the temperature of the output window were made during the long-pulse tests. Output power levels of 1 MW were achieved under short-pulse (1 ms) operation and the tube was operated at CW power levels in excess of 100 kW     

On the shape of the Q-branch of Raman scattering spectra in dense media. Anisotropic scattering

The Q-branch width of the anisotropic Raman spectrum for linear molecules has been shown to increase with density. Until the overlap of the O-, Q-, S-branches is small, the product of the half-widths of isotropic and anisotropic Q-branches, in units of mean frequency, is a constant characterizing the collision strength.     

Radiation-induced catalytic polymerization. I. Theory

The kinetics of radiation polymerization on a solid catalyst is discussed, under the condition that only linear termination of the chain takes place. All the kinetic equations are balance equations of particles of each type adsorbed by unit mass of the catalyst, and this makes it possible to account for the effect on the kinetics of the time dependence of the magnitude of the part of its surface on which the reactions we are considering may take place. Integro-differential equations are used for calculating the molecular weight distribution of the resulting polymer; this ensures higher accuracy of the formulas obtained than when differential equations are used and makes it possible to eliminate a number of limitations generally involved in the transition to differential equations. An expression has been found for the molecular weight distribution of the polymer product which allows for the possibility of radiation-induced catalytic polymerization on the resulting adsorbed polymer. Expressions have been derived for the average molecular weight and yield (weight and molecular) of the polymer formed. Asymptotic formulas have been obtained (for large irradiation times) for all the above values. The conclusions that can be drawn concerning the mechanism of the process based on a comparison of the formulas obtained with kinetic curves plotted from experimental data are given. It is shown how such a comparison can be utilized for calculating the rate constants for polymerization and chain termination reactions.     

Construction of the reaction networks for heterogeneous catalytic reactions: Fischer—Tropsch synthesis and related reactions

The key approaches to the generation of reaction networks for the synthesis of products from CO and H₂ are considered. The selection rules for the elementary steps on the surface of heterogeneous catalysts are formulated. Data on the surface compounds and steps related to reactions of CO and H₂ are analyzed and a set of transforms (models of elementary steps) for generation of the reaction network are selected. Eight variants of generation of reaction networks for the formation of C1 products with different sets of transforms (12 to 31) were tested in computer experiments, and eight reaction networks comprising 34 substances and 132 to 1647 elementary steps were obtained. The pathways to CO₂, CH₄, and CH₃OH and pairs of compounds CH₄, CO₂ and CH₄, HCOOH obtained from the reaction network (220 elementary steps) are compared with the published schemes.     

On the classification and coding of linear reaction mechanisms

Non-oriented kinetic graphs are classified and coded according to their topological properties.

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Reported in part at The 5th All-Union Meeting on Homogeneous Catalysis, Alma-Ata, October 1979     

Capture of adatoms by clusters in thin film deposition

The adatom diffusion and capture by clusters are considered as a random-walk problem. The method of solution is developed. Green's function for a square substrate lattice is obtained. This permits one to give a general solution for a steady-state adatom distribution around clusters and for Halpern's arrival probability. This solution is applicable for calculating capture numbers of some small capture centres. An interpolation formula for the capture number, as dependent on the perimeter length of the capture centre, is proposed for λ a. The adatoms fluxes to the 10 and 11 steps on the surface are calculated. The fluxes are anistropic but the anisotropy disappears with λ/a → ∞. The applicability of the steady-state approach is discussed. It is shown that this approximation is valid for low adatom density. The adatom fluxes to monatomic and diatomic immobile clusters are calculated under conditions when these clusters cannot be treated as capture centres. The conservation equations for these clusters are formulated whereby two different configurations of three-atomic clusters are taken into account.