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91.
[reaction: see text] A new and convenient three-step synthesis of pentafluorosulfanylbenzene from 1,4-cyclohexadiene with an overall yield of >70% is reported along with a number of derivatization reactions. 相似文献
92.
Yurij?Stoyan Guntram?ScheithauerEmail author Nikolay?Gil Tatiana?Romanova 《4OR: A Quarterly Journal of Operations Research》2004,2(1):69-84
Within two-dimensional cutting and packing problems with irregular shaped objects, the concept of
-functions has been proven to be very helpful for several solution approaches. In order to construct such
-functions a previous work, in which so-called primary objects are considered, is continued. Now
-functions are constructed for pairs of objects which can be represented as a finite combination (union, intersection, complement) of primary objects which allows the handling of arbitrary shaped objects by appropriate approximations of sufficient accuracy.Received: October 2002, Revised: October 2003, AMS classification:
65K05, 90C26, 90B06All correspondence to: Guntram Scheithauer 相似文献
93.
Gutsul EI Belkova NV Sverdlov MS Epstein LM Shubina ES Bakhmutov VI Gribanova TN Minyaev RM Bianchini C Peruzzini M Zanobini F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(10):2219-2228
The reactions of the octahedral dihydrido complexes [MH(2)(PP(3))] [M=Fe, Ru, Os; PP(3)=P(CH(2)CH(2)PPh(2))(3)] with a variety of weak ROH acids have been studied by IR and NMR methods in either CH(2)Cl(2) or THF in the temperature range from 190 to 290 K. This study has allowed the determination of the spectral and thermodynamic properties associated with the formation of dihydrogen bonds (DHB) between the terminal hydrides and the OH group. Both the DHB enthalpy values and the hydride basicity factors (E(j)) have been found to increase in the order Fe < Ru < Os. The proton transfer process, leading to the DHB complexes, and eventually to eta(2)-H(2) products, has been found to depend on the acidic strength of the alcohol as well as the nature of the solvent. Low temperature IR and NMR techniques have been used to trace the complete energy profile of the proton transfer process involving the osmium complex [OsH(2)(PP(3))] with trifluoroethanol. 相似文献
94.
This review is a survey of the many scientific applications of ultrasonic broadbandspectrometry (absorption and velocity measurements with coherent sound waves)in liquids and liquid systems, covering, at present, a frequency range from nearly10 kHz to 10 GHz. Ultrasonic spectrometry has proved to be an almost universalresearch tool in many laboratories, one that is useful for investigation of variouschemical, biochemical, and physicochemical systems. Sound waves traversingliquids induce periodic perturbations in pressure and temperature, which can shiftequilibria, resulting in characteristic sound absorption and velocity dispersionspectra. An analysis of such spectra yields valuable information about thermodynamic and kinetic parameters of the particular system that is often difficult toobtain by other methods. Since such periodic perturbations imposed on the systemare incremental in nearly all cases, the system can be studied under equilibriumconditions. All nonlinear effects (heating, nonconstant fluid compressibility, andothers) are negligible, permitting, for instance, the application of linearized rateequations. In this review, various examples of measured broadband spectra arepresented. Related elementary processes are discussed. Among these are ionicand molecular reactions, including mechanisms of association and complexation,proton transfer, solvation, isomerization, interconversion, side-group rotation,hydrogen-bonding, as well as stacking processes and micelle formation. Specialattention will be given to the extensive research on chemical relaxation.Fundamental early and recent publications are cited and discussed. Many referencesare included with particular emphasis on less well known research and publicationsfrom countries of the former USSR. This review aims at a demonstration of thewidespread applications of modern ultrasonic techniques in many fields ofliquid-state research. 相似文献
95.
Petr I. Nikitin Petr M. Vetoshko Tatiana I. Ksenevich 《Journal of magnetism and magnetic materials》2007
A new type of biosensor has been developed based on detection of nanosized superparamagnetic particles that serve as labels in bioreactions. The method is based on non-linear magnetic material detection by a magnetic field having components at two frequencies f1 and f2. The response is measured at the combinatorial frequencies fi=mf1+nf2, where m and n are integers, e.g., fi=f1±2f2. Several highly sensitive readers of superparamagnetic particles have been designed and used for development of various formats of immunoassays, including those compatible with immunoconcentration and magnetic enrichment of antigens. 相似文献
96.
97.
98.
N-terminal tagging strategy for De Novo sequencing of short peptides by ESI-MS/MS and MALDI-MS/MS 总被引:1,自引:0,他引:1
Tatiana Yu. Samgina Sergey V. Kovalev Vladimir A. Gorshkov Konstantin A. Artemenko Nikita B. Poljakov Albert T. Lebedev 《Journal of the American Society for Mass Spectrometry》2010,21(1):104-111
The major portion of skin secretory peptidome of the European Tree frog Hyla arborea consists of short peptides from tryptophyllin family. It is known that b-ions of these peptides undergo head-to-tail cyclization, forming a ring that can open, resulting in several linear forms.
As a result, the spectrum contains multiple ion series, thus complicating de novo sequencing. This was observed in the Q-TOF spectrum of one of the tryptophyllins isolated from Hyla arborea; the sequence FLPFFP-NH2 was established by Edman degradation and counter-synthesis. Though no rearrangements were observed in FTICR-MS and MALDI-TOF/TOF
spectra, both of them were not suitable for mass-spectrometry sequencing due to the low sequence coverage. To obtain full
amino acid sequence by mass spectrometry, three chemical modifications to N-terminal amino moiety were applied. They include
acetylation and sulfobenzoylation of N-amino group and its transformation to 2,4,6-trimethylpyridinium by interaction with
2,4,6-trimethylpyrillium tetrafluoroborate. All three reagents block scrambling and provide spectra better than the intact
peptide. Unfortunately, all of them also readily react with lysine side chain. Hence, all investigated procedures can be used
to improve sequencing of short peptides, while acetylation is the recommended one. It shows excellent results, and it is plain
and simple to perform. This is the procedure of choice for MS-sequencing of short peptides by manual or automatic algorithms. 相似文献
99.
An efficient functionalization of the quinolizinium system is reported. The reaction of the four isomeric bromoquinolizinium salts with different organotrifluoroborates afforded alkyl-, vinyl-, aryl-, and heteroaryl quinolizinium derivatives in moderate or good yields. Reactions are carried out in water using a counterion exchange for the isolation of the cationic-coupled compounds. 相似文献
100.
Tatiana Visnevschi-Necrasov Sara C. Cunha Eugénia Nunes M. Beatriz P.P. Oliveira 《Journal of chromatography. A》2009,1216(18):3720-3724
A method based on matrix solid-phase dispersion (MSPD) has been developed for the determination of 12 isoflavones in Trifolium pratense L. Dried leaf samples were blended with C18, placed in small columns and isoflavones extracted with dichloromethane–methanol. Analyses were performed by high performance liquid chromatography with diode array detection (HPLC-DAD) with 2-methoxyflavone as internal standard. Several dispersants, eluents and clean-up steps were tested during the optimization of the process in order to obtain the best selectivity and yields. Mean recoveries ranged from 70% to 119%, with relative standard deviations <18%. The limits of detection were between 0.006 mg/l for biochanin A and 0.108 mg/l for daidzin. The performance of the optimized method in real samples was compared with a conventional method based in solid–liquid extraction (SLE). 相似文献