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71.
F. Steglich P. Gegenwart R. Helfrich C. Langhammer P. Hellmann L. Donnevert C. Geibel M. Lang G. Sparn W. Assmus G.R. Stewart A. Ochiai 《Zeitschrift für Physik B Condensed Matter》1996,103(2):235-242
We present the results of specific-heat and resistivity measurements as a function of temperature, magnetic field and hydrostatic pressure on the Kondo lattice CeNi2Ge2, the heavy-fermion superconductors CeCu2Si2 and UBe13 as well as the low-carrier-density system Yb4As3. “Non-Fermi-liquid” effects in the low-temperature normalstate properties of the three former systems are consistent with the existence of a “nearby” quantum critical point, presumably of antiferromagnetic type. Yb4As3, though showing the outward appearance of a Landau-type heavy-fermion metal, behaves very differently, i.e. as an extreme two-fluid system. 相似文献
72.
Yoshinao Tamaru Hirofumi Ochiai Tatsuya Nakamura Kazunori Tsubaki Zen-ichi Yoshida 《Tetrahedron letters》1985,26(45):5559-5562
2-Carboethoxyethylzinc iodide and 3-carboethoxypropylzinc iodide are generated by the reaction of the corresponding iodoesters with Zn-Cu couple and utilized for the palladium catalyzed coupling reaction with acid chloride to quantitatively provide gamma- and delta- keto esters, respectively. 相似文献
73.
P. A. Alekseev J. -M. Mignot E. V. Nefedova K. S. Nemkovskii V. N. Lazukov I. P. Sadikov A. Ochiai 《JETP Letters》2004,79(2):81-84
The dynamic magnetic susceptibility spectrum in a single-crystal sample of the intermediate-valence compound Sm0.67Y0.33S is studied by inelastic neutron scattering with neutron momentum transfer and sample temperatures varying over wide ranges. Two coupled collective modes have been found in the spectrum. Unlike the higher energy mode, whose intensity approximately follows the form factor of Sm2+, the lower energy mode exhibits a stronger angular dependence than could be expected from the form factor for the localized f electrons. The total intensity of the inelastic component of the magnetic response decreases with increasing temperature; this is accompanied by the appearance of a broad quasi-elastic signal of a magnetic nature at significantly lower temperatures than follows from the calculated intensities of the transitions within the excited multiplet of the Sm2+ ion. An analysis of the observed features allows the suggestion to be made that the fine structure of the magnetic excitation spectrum in (Sm,Y)S is associated with the formation of an exciton-like intermediate-valence state on Sm ions rather than with the crystal-electric-field effects. 相似文献
74.
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76.
Gronheid R Lodder G Ochiai M Sueda T Okuyama T 《Journal of the American Chemical Society》2001,123(36):8760-8765
The thermal and photochemical solvolysis of the two stereoisomeric 2-phenyl-1-propenyl(phenyl)iodonium tetrafluoroborates has been investigated in alcoholic solvents of varying nucleophilicity. The product profiles and rates of product formation in the thermal reaction are all compatible with a mechanism involving cleavage of the vinylic C-I bond assisted by the group in the trans position (methyl or phenyl), always leading to rearranged products. Depending on the nucleophilicity of the solvent, the primarily formed cations may or may not further rearrange to more stable isomers. The less reactive Z compound also yields some unrearranged vinyl ether product in the more nucleophilic solvents via an in-plane S(N)2 mechanism. The mechanism of the photolysis involves direct, unassisted cleavage of the vinylic, and aromatic, C-I bond in an S(N)1 mechanism. This produces a primary vinyl cation, which is partially trapped prior to rearrangement in methanol. The unrearranged vinyl ethers are mainly formed with retention of configuration via a lambda3-iodonium/solvent complex in an S(N)i mechanism. Thermal and photochemical solvolyses of iodonium salts are complementary techniques for the generation of different cation intermediates from the same substrate. 相似文献
77.
Bungo Ochiai Daisuke Nagai Toyoharu Miyagawa Takeshi Endo 《European Polymer Journal》2006,42(8):1934-1938
A novel polysulfone bearing exomethylene structure in the main chain was obtained by oxidation of polysulfide prepared by radical ring-opening polymerization of an eight-membered cyclic allyl sulfide, although the corresponding sulfone monomer was not polymerized at all. The thermal behaviors and the crystalline characters of the polysulfone and polysulfide are compared. 相似文献
78.
Ochiai N Sasamoto K Takino M Yamashita S Daishima S Heiden AC Hoffmann A 《Analytical and bioanalytical chemistry》2002,373(1-2):56-63
A method for the simultaneous determination of seven preservatives - sorbic acid, benzoic acid, and p-hydroxybenzoic acid ethyl, isopropyl, propyl, isobutyl, and butyl esters - in beverages, vinegar, aqueous sauces, and quasi-drug drinks has been developed using the stir-bar sorptive extraction technique then thermal desorption GC-MS analysis. The extraction conditions - pH, sample volume, extraction temperature, salt addition, and extraction time - were examined. d5-Benzoic acid and p-hydroxybenzoic acid sec-butyl ester were added as surrogate internal standards to compensate for the effect of sample matrix and coexisting analytes on the sorptive extraction. The linearity of the method was good over the concentration range from 1 to 1000 microg mL(-1) for sorbic acid, 10-1000 microg mL(-1) for benzoic acid, and 0.1-100 microg mL(-1) for p-hydroxybenzoic acid ethyl, isopropyl, propyl, isobutyl, and butyl esters, and the correlation coefficients were higher than 0.9984. The limit of detection ranged from 0.015 to 3.3 microg mL(-1). The recoveries (95-105%) and precision (RSD: 0.86-6.0%) of the method were examined by analyzing a sparkling soft drink, white wine, red wine, balsamic vinegar, soy sauce, and quasi-drug drink samples fortified at the 5 to 50 microg mL(-1) level. 相似文献
79.
A new direct allylation of the aromatic compound has been developed. A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product(s) in good yields. 相似文献
80.
Michael addition of allylsilane to α-nitro olefin in the presence of AlCl3 proceeded smoothly at low temperature to give unsaturated nitronic acid, which was converted into the γδ-enone using aqueous Ti (III). Transformation with the latter provided a convenient new synthesis of cyclopentenone. 相似文献