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81.
Akihiko Kanazawa Tomiki Ikeda Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》1993,31(2):335-343
Various polymeric phosphonium salts and the corresponding low-molecular-weight model compounds were prepared and their antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell counting method in sterile distilled water. Antibacterial activity of the polymers was found to be higher than that of the corresponding model compounds, particularly against S. aureus. Furthermore, the polymeric phosphonium salt exhibited a higher activity by 2 orders of magnitude than the polymeric quaternary ammonium salt with the same structure except the cationic part. Compounds with the longest alkyl chain (octyl) studied were found to exhibit particularly high activity, and this finding may be ascribed to the contribution of the increased hydrophobicity of the compounds to the cidal activity. © 1993 John Wiley & Sons, Inc. 相似文献
82.
Tricyclo[3.3.1.1]decanone azine ( adamantanone azine ) reacts with 4-substituted 1,2,4-triazoline-3,5-diones under elimination of diazo adamantane to give a 1,3-dipole ( “azomethinimine” ), which on treatment with dipolahophiles affords the [ 2 + 3] -cycloadducts. The reaction is compared with singlet oxygen oxidation. 相似文献
83.
[structure: see text] The first total synthesis of gambierol, a marine polycyclic ether toxin, has been achieved. The synthesis features the Pd(PPh3)4/CuCl/LiCl-promoted Stille coupling for the stereoselective construction of the sensitive triene side chain that includes a conjugated (Z,Z)-diene moiety. 相似文献
84.
85.
Shimazaki Y Tashiro M Motoyama T Iwatsuki S Yajima T Nakabayashi Y Naruta Y Yamauchi O 《Inorganic chemistry》2005,44(17):6044-6051
Synthetic, structural, spectroscopic, and kinetic studies have been carried out on the Pd(II) complexes of new 2N1O-donor ligands containing a pendent indole, 3-(N-2-pyridylmethyl-N-2-hydroxy-5-methoxybenzylamino)ethylindole (HMeO-iepp), 3-(N-2-pyridylmethyl-N-2-hydroxy-5-nitrobenzylamino)ethylindole (HNO2-iepp), and (N-2-pyridylmethyl-3-indolylethylamino)acetic acid (Hiepc) (H denotes a dissociable proton). [Pd(MeO-iepp)Cl] (2), [Pd(NO2-iepp)Cl] (3), and [Pd(iepc)Cl] (4) were prepared and revealed by X-ray analysis to have a pyridine nitrogen, an amine nitrogen, a phenolate or carboxylate oxygen, and a chloride ion in the coordination plane. UV absorption and 1H NMR spectral changes indicated that all the complexes could be converted to the indole-binding complexes where the O donor was replaced by the indole C2 atom by cyclopalladation in DMSO or DMF in the temperature range of 40-60 degrees C. Formation of the indole-binding complex species obeyed the first-order kinetics, from which the activation parameters were estimated. The formation rate was dependent on the properties of the O-donor group, a lower pKa value of its conjugate acid causing faster conversion to the indole-binding species in the order 2 (methoxyphenolate) < 3 (nitrophenolate) < 4 (carboxylate). On the other hand, the ratio of the indole-binding complex to the O-donor complex as a result of the conversion was greater for the complexes with a higher pKa value of the ligand OH group, the order being 2 > 3 > 4. 相似文献
86.
Hiroyuki Asanuma Sumie Gotoh Takeshi Ban Makoto Komiyama 《Journal of inclusion phenomena and macrocyclic chemistry》1997,27(3):259-264
Poly(2-vinyl-4,6-diamino-1,3,5-triazine) efficiently binds nucleic acid bases and nucleosides in water by using complementary hydrogen bonding. The binding activity decreases in the order: U, T > A C, G. The corresponding monomer shows virtually no activity, indicating a predominant role of polymer effect for the molecular recognition in water. 相似文献
87.
The bound site of Mo atoms and its local structure in a Mo/HY catalyst have been determined by detailed analysis of extended X-ray absorption fine structure (EXAFS). Molybdenum was introduced in the supercage of HY zeolite by cycles of saturated adsorption of Mo(CO)6 at room temperature and subsequent thermal decomposition at 573 K. Two Mo atoms per supercage were immobilized in each CVD-thermal treatment cycle. The Mo loading increased linearly with the cycles up to three cycles at saturation, where six Mo atoms were supported. Temperature-programmed decomposition of the adsorbed Mo(CO)6 was also characterized by GC, QMS, and FT-IR, respectively. The EXAFS analysis including multiple scattering based on theoretical calculations revealed that Mo bound with two oxygen atoms connects to Al, where one of the two oxygen atoms had been associated with a proton. The bound site is called the S(III)' site. The zeolite framework was significantly distorted by the introduction of low-valent Mo, resulting in isolation of the [MoO2Al] unit from the surrounding zeolite framework due to a quasi-disruption of Si-O bonds adjacent to the unit. In the mild oxidation of the low-valent Mo/HY sample two Mo=O bonds were newly formed and the position of Mo was displaced by 0.06 nm so that the distortion of zeolite framework around the Al atom was relieved. The structures were also supported by DFT calculations. This study is the first example that the position of metal cation in zeolite was determined unambiguously by the EXAFS analysis. 相似文献
88.
Shigeru Sasaki 《Journal of organometallic chemistry》2005,690(10):2664-2672
4,4′-Diphosphinobiaryls and 1,3- and 1,4-borylphosphinobenzenes carrying crowded triarylphosphine moieties were synthesized by reaction of the corresponding diarylchlorophosphine with an arylcopper(I) reagent. Intramolecular interaction of the phosphorus redox center with the other phosphorus or the boron redox center was investigated by cyclic voltammetry. 4,4′-Diphosphinobiaryls displayed two-step reversible redox waves with slight differences of the oxidation potentials due to weak interaction between two phosphorus redox centers across 4,4′-biarylene linkage. Borylphosphinobenzenes showed two step redox waves corresponding to oxidation at the phosphorus and reduction at the boron. Although significant interaction between the phosphorus and boron redox centers was not observed in the cyclic voltammograms due to large difference of the redox potentials between phosphorus and boron redox centers, an absorption due to weakly interacting phosphorus and boron was observed in the UV-Vis spectrum of the 1,4-borylphosphinobenzene. 相似文献
89.
Spirodienones bearing the 1-azaspiro[4.5]decane ring system have been synthesized from N-methoxy-(4-halogenophenyl)amides by the intramolecular ipso attack of a nitrenium ion generated with [hydroxy(tosyloxy)iodo]benzene in trifluoroethanol. 相似文献
90.
Kawasaki H Sasaki A Kawashima T Sasaki S Kakehashi R Yamashita I Fukada K Kato T Maeda H 《Langmuir : the ACS journal of surfaces and colloids》2005,21(13):5731-5737
Lyotropic phase behavior of the nonionic and the half-ionized oleyldimethylamine oxide (OlDMAO)/water systems was investigated using polarized light microscopy, small-angle X-ray diffraction, and differential scanning calorimetry. Nonionic OlDMAO formed isotropic micellar solution, nematic, hexagonal, cubic, and lamellar liquid crystalline phases as the surfactant concentration increased. In contrast, half-ionized OlDMAO (i.e., 1:1 mixture of the nonionic and the protonated species) had a greater tendency to form bilayer structures, and the phase diagram became quite similar to those of double-chained ionic surfactants rather than single-chained ones, despite the introduction of positive charges to the nonionic one. The preference of the bilayer structures in the half-ionized OlDMAO was interpreted in terms of the dimers stabilized by the hydrogen bond between the nonionic and protonated species. For alkyldimethylamine oxides with a saturated hydrocarbon chain (CnDMAO, chain length: n = 14, 16, and 18), the phase sequence of lyotropic liquid crystals was hardly affected by the protonation, but an elongation of the cylinders of the hexagonal phase was observed for the half-ionized C14DMAO. Consequently, it can be considered that the dominant bilayer formation of the half-ionized OlDMAO is attributed to the combined effect of the hydrogen-bonded dimer formation and the cis-double-bond configuration of the alkyl chain. 相似文献