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201.
Satoshi Miwa Takako Kikuchi Yoshito OhtakeKeiji Tanaka 《Polymer Degradation and Stability》2011,96(8):1503-1507
Saturated olefinic rubbers have been widely used as materials for not only municipal waterworks, but also for household uses. As a sanitizing agent for water, chlorine will be replaced by ozone in the near future from an environmental point of view. However, the ozone treatment in water seriously damages saturated olefinic rubbers, which are necessary for the infrastructure of daily life. Here, we report the surface degradation of cross-linked poly(ethylene-co-propylene-co-5-ethylidene-2-norbornene) terpolymer (EPDM) by ozone treatment, both in water and air. We also discuss how the presence of water impacts the ozone oxidation of EPDM, resulting in macroscopic damage to EPDM. 相似文献
202.
Moriyasu T Minowa K Sakamoto M Kishimoto K Kadoi H Nakajima J Mori K Ogino S Fukaya H Shida Y 《Journal of AOAC International》2011,94(6):1770-1777
An analog of aildenafil, which is a potent and highly selective inhibitor of phosphodiesterase 5, was found in a dietary supplement marketed for enhancement of sexual function. The compound was isolated by silica gel column chromatography, and its structure was identified by means of 13C-NMR spectrometry, 1H-NMR spectrometry, high-resolution MS, and X-ray structure determination. The compound was identified to be sulfoaildenafil (other names: thioaildenafil, dimethyl sildenafil thione, and thiomethisosildenafil). Sulfoaildenafil is very similar to the compound thiohomosildenafil. As it is difficult to distinguish between them by LC-photodiode array detector analysis, ultra-performance LC (UPLC)/MS, ion trap LC/MS/MS (LC/IT-MS/MS), and GC/MS were performed. The mass spectra of thiohomosildenafil by UPLC/MS and LC/IT-MS/MS showed mass fragments of m/z 58, 72, and 355, and the mass spectrum by GC/MS showed mass fragments of m/z 56, 72, and 420. Some of these fragments had low intensities, but they were useful for distinguishing between the two compounds. The relationship between aildenafil (other names: dimethylsildenafil and methisosildenafil) and homosildenafil is similar to that between sulfoaildenafil and thiohomosildenafil. Therefore, these compounds were also examined. 相似文献
203.
Yuki Kudo Takako Nakahara Tatsuro Nakagama Nobuko Seino Masaki Shinoda Katsumi Uchiyama 《Analytical sciences》2007,23(1):91-95
A surface-reaction system in a nanoliter water pool using an ink-jet microchip was developed. The reaction system in the nanodroplets formed on a poly(dimethylsiloxane) (PDMS) coated glass slide increased the diffusion-controlled reaction without using a nano-pump, specialized connector or highly sensitive detector. When nanoliter droplets were placed on the PDMS surface with a distance of 100 microm between them by the ink-jet microchip, the repeatabilities of the fluorescence intensity were 2.9% RSD (n = 7). The used ink-jet microchip had 4 different injection ports, and the distance between the ports was 0.995 mm. It was necessary to correct the distance in order to mix or dilute samples in a small droplet. The correction was successfully performed by moving the X-Y stage using inhouse-made software. A linear relationship was obtained between the Resorufin concentrations and the fluorescence intensity. We applied this system to an enzyme-linked immunosorbent assay (ELISA) for immunoglobulin A (IgA), and observed a difference in the fluorescence intensity derived from the amount of IgA (blank, 6.25 ng/mL, 12.5 ng/mL). These results show the usefulness of the open-type micro-analytical systems proposed by us. 相似文献
204.
John Coates Takako Fukaya Kazuya Kato Ramdorai Sujatha Otmar Venjakob 《Publications Mathématiques de L'IHéS》2005,101(1):163-208
Let G be a compact p-adic Lie group, with no element of order p, and having a closed normal subgroup H such that G/H is isomorphic to Zp. We prove the existence of a canonical Ore set S* of non-zero divisors in the Iwasawa algebra Λ(G) of G, which seems to be particularly relevant for arithmetic applications. Using localization with respect to S*, we are able to define a characteristic element for every finitely generated Λ(G)-module M which has the property that the quotient of M by its p-primary submodule is finitely generated over the Iwasawa algebra of H. We discuss the evaluation of this characteristic element at Artin representations of G, and its relation to the G-Euler characteristics of the twists of M by such representations. Finally, we illustrate the arithmetic applications of these ideas by formulating a precise version of the main conjecture of Iwasawa theory for an elliptic curve E over Q, without complex multiplication, over the field F generated by the coordinates of all its p-power division points; here p is a prime at least 5 where E has good ordinary reduction, and G is the Galois group of F over Q. 相似文献
205.
K. Fukaya 《Geometric And Functional Analysis》1998,8(3):466-528
((Without abstract))
Submitted: July 1997, Revised version: November 1997 相似文献
206.
Takako Nakamura Tsuguyori Ohana Masahiro Suzuki Masatou Ishihara Akihiro Tanaka Yoshinori Koga 《Surface science》2005,580(1-3):101-106
Photolysis of perfluoroazooctane with diamond-like carbon (DLC) films led to the surface modification to introduce perfluorooctyl functional groups, confirmed by means of FT-IR, XPS, Raman and TOF-SIMS measurements. The DLC films modified with fluorine moieties showed reduction of the surface energy evaluated by contact angle to water, as compared with pristine DLC film. The contact angle of chemically modified DLC film is 105°, comparable to that of polytetrafluoroethylene (PTFE). By monitoring with XPS, we found that the results on the value of fluorine/carbon ratio of fluorinated DLC films depending on irradiation time are consistent with those of contact angle. Chemical modification of DLC films with perfluorooctyl functionalities also led to improvement of their frictional properties. The friction coefficient of the modified film is 0.05 under vacuum condition, whereas that of the pristine film shows very high value (>1). 相似文献
207.
Takako Nemoto MedYahya Ould MedSalem Kazuyuki Tanaka 《Mathematical Logic Quarterly》2007,53(3):226-236
In this paper we study the determinacy strength of infinite games in the Cantor space and compare them with their counterparts in the Baire space. We show the following theorems: 1. RCA0 ? ‐Det* ? ‐Det* ? WKL0. 2. RCA0 ? ( )2‐Det* ? ACA0. 3. RCA0 ? ‐Det* ? ‐Det* ? ‐Det ? ‐Det ? ATR0. 4. For 1 < k < ω, RCA0 ? ( )k ‐Det* ? ( )k –1‐Det. 5. RCA0 ? ‐Det* ? ‐Det. Here, Det* (respectively Det) stands for the determinacy of infinite games in the Cantor space (respectively the Baire space), and ( )k is the collection of formulas built from formulas by applying the difference operator k – 1 times. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
208.
Tetsushi Kijima Masakazu Nishida Haruhiko Fukaya Masato Yoshida Hideo Sawada 《先进技术聚合物》2014,25(3):258-264
Aromatic ketones such as 4′‐methoxyacetophenone (MAP), acetophenone (AP), 4‐acetylbiphenyl (ABP), and 2‐acetyl‐6‐methoxynapthalene (AMN) interacted with fluoroalkyl end‐capped 2‐acrylamido‐2‐methylpropanesulfonic acid oligomer [RF‐(AMPS)n‐RF] at 80°C for 3 h to give the corresponding fluorinated oligomer/aromatic ketones composites. In these composites, the RF‐(AMPS)n‐RF/MAP and /AP composites were found to give the homoaldol condensation products of MAP and AP, respectively. In contrast, the corresponding non‐fluorinated AMPS oligomer/MAP and sulfuric acid/MAP composites could not give the homoaldol product at all under similar conditions. This suggests that the RF‐(AMPS)n‐RF oligomer could provide the suitable fluorinated oligomeric gel newtwok cores to interact with MAP or AP as a guest molecule, and the homoaldol condensation of encapsulated MAP and AP should proceed smoothly in the fluorinated oligomeric gel network cores. The RF‐(AMPS)n‐RF/ABP and /AMN composites could not give the homoaldol products at all under similar conditions, indicating that the more bulky aromotic ketones than MAP or AP are not likely to be encapasulated as guest molecules into the fluorinated AMPS oligomeric gel netwok cores. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
209.
Quinolone Analogs 13: Synthesis of Novel 1,1′‐(2‐Methylenepropane‐1,3‐diyl)di(4‐quinolone‐3‐carboxylate) and Related Compounds 下载免费PDF全文
Yoshihisa Kurasawa Kiminari Yoshida Naoki Yamazaki Eisuke Kaji Kenji Sasaki Yoshito Zamami Takatoshi Fujii Min Zhao Hideyuki Ito Haruhiko Fukaya 《Journal of heterocyclic chemistry》2014,51(6):1720-1726
The reaction of the 4‐hydroxyquinoline‐3‐carboxylate 6 with pentaerythritol tribromide gave the 1,1′‐(2‐methylenepropane‐1,3‐diyl)di(4‐quinolone‐3‐carboxylate) 11 , whose reaction with bromine afforded the 1,1′‐(2‐bromo‐2‐bromomethylpropane‐1,3‐diyl)di(4‐quinolone‐3‐carboxylate) 12 . Compound 12 was transformed into the (Z)‐1,1′‐(2‐acetoxymethylpropene‐1,3‐diyl)di(4‐quinolone‐3‐carboxylate) 13 or (E)‐1,1′‐[2‐(imidazol‐1‐ylmethyl)propene‐1,3‐diyl]di(4‐quinolone‐3‐carboxylate) 14 . Hydrolysis of the dimer (Z)‐ 13 or (E)‐ 14 with potassium hydroxide provided the (E)‐1,1′‐(2‐hydroxymethylpropene‐1,3‐diyl)di(4‐quinolone‐3‐carboxylic acid) 15 or (Z)‐1,1′‐[2‐(imidazol‐1‐ylmethyl)propene‐1,3‐diyl]di(4‐quinolone‐3‐carboxylic acid) 16 , respectively. The nuclear Overhauser effect (NOE) spectral data supported that those hydrolysis resulted in the geometrical conversion of (Z)‐ 13 into (E)‐ 15 or (E)‐ 14 into (Z)‐ 16 . 相似文献
210.
Quinolone Analogues 15: Synthesis and Antimalarial Activity of 4‐Phenyl‐1‐(1‐triazolylmethyl‐4‐quinolon‐3‐ylcarbonyl)semicarbazide and Related Compounds 下载免费PDF全文
Yoshihisa Kurasawa Kiminari Yoshida Naoki Yamazaki Kenji Sasaki Yoshito Zamami Zhao Min Atsumi Togi Hideyuki Ito Eisuke Kaji Haruhiko Fukaya 《Journal of heterocyclic chemistry》2014,51(Z1):E249-E254
The 1‐hydrazinocarbonylmethyl‐4‐quinolone‐3‐carboxylate ( 10 ) was converted into the 1‐(4‐amino‐1,2,4‐triazol‐3‐ylmethyl)‐4‐quinolone‐3‐carboxylic acid ( 13 ), whose reaction with arylcarbaldehydes gave the 1‐(4‐arylmethyleneamino‐1,2,4‐triazol‐3‐ylmethyl)‐4‐quinolone‐3‐carboxylic acids ( 5a , 5b , 5c , 5d , 5e , 5f , 5g ). Compound 10 was also transformed into the 1‐(4‐amino‐1,2,4‐triazol‐3‐ylmethyl)‐4‐quinolone‐3‐carbohydrazide ( 15 ), whose reaction with phenyl isocyanate or phenyl isothiocyanate afforded the 4‐phenyl‐1‐(1‐triazolylmethyl‐4‐quinolon‐3‐ylcarbonyl)semicarbazide ( 6a ) or 4‐phenyl‐1‐(1‐triazolylmethyl‐4‐quinolon‐3‐ylcarbonyl)thiosemicarbazide ( 6b ), respectively. Compounds 6a , 6b showed the in vitro antimalarial activity to chloroquine‐resistant Plasmodium falciparum, wherein their IC50 was 3.89 and 3.91 μM, respectively. 相似文献