全文获取类型
收费全文 | 924篇 |
免费 | 17篇 |
国内免费 | 2篇 |
专业分类
化学 | 609篇 |
晶体学 | 12篇 |
力学 | 10篇 |
数学 | 62篇 |
物理学 | 250篇 |
出版年
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 14篇 |
2017年 | 10篇 |
2016年 | 18篇 |
2015年 | 14篇 |
2014年 | 12篇 |
2013年 | 48篇 |
2012年 | 29篇 |
2011年 | 38篇 |
2010年 | 13篇 |
2009年 | 29篇 |
2008年 | 61篇 |
2007年 | 35篇 |
2006年 | 47篇 |
2005年 | 37篇 |
2004年 | 40篇 |
2003年 | 36篇 |
2002年 | 49篇 |
2001年 | 20篇 |
2000年 | 28篇 |
1999年 | 12篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 22篇 |
1995年 | 11篇 |
1994年 | 6篇 |
1993年 | 14篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 14篇 |
1989年 | 11篇 |
1988年 | 21篇 |
1987年 | 17篇 |
1986年 | 13篇 |
1985年 | 23篇 |
1984年 | 16篇 |
1983年 | 10篇 |
1982年 | 9篇 |
1981年 | 14篇 |
1980年 | 5篇 |
1979年 | 13篇 |
1978年 | 8篇 |
1977年 | 11篇 |
1976年 | 9篇 |
1975年 | 13篇 |
1974年 | 4篇 |
1973年 | 6篇 |
1972年 | 5篇 |
1936年 | 4篇 |
排序方式: 共有943条查询结果,搜索用时 1 毫秒
91.
The MP2 (the second-order M?ller-Plesset calculation) and CCSD(T) (coupled cluster calculation with single and double substitutions with noniterative triple excitations) interaction energies of all-trans n-alkane dimers were calculated using Dunning's [J. Chem. Phys. 90, 1007 (1989)] correlation consistent basis sets. The estimated MP2 interaction energies of methane, ethane, and propane dimers at the basis set limit [EMP2(limit)] by the method of Helgaker et al. [J. Chem. Phys. 106, 9639 (1997)] from the MP2/aug-cc-pVXZ (X=D and T) level interaction energies are very close to those estimated from the MP2/aug-cc-pVXZ (X=T and Q) level interaction energies. The estimated EMP2(limit) values of n-butane to n-heptane dimers from the MP2/cc-pVXZ (X=D and T) level interaction energies are very close to those from the MP2/aug-cc-pVXZ (X=D and T) ones. The EMP2(limit) values estimated by Feller's [J. Chem. Phys. 96, 6104 (1992)] method from the MP2/cc-pVXZ (X=D, T, and Q) level interaction energies are close to those estimated by the method of Helgaker et al. from the MP2/cc-pVXZ (X=T and Q) ones. The estimated EMP2(limit) values by the method of Helgaker et al. using the aug-cc-pVXZ (X=D and T) are close to these values. The estimated EMP2(limit) of the methane, ethane, propane, n-butane, n-pentane, n-hexane, n-heptane, n-octane, n-nonane, and n-decane dimers by the method of Helgaker et al. are -0.48, -1.35, -2.08, -2.97, -3.92, -4.91, -5.96, -6.68, -7.75, and -8.75 kcal/mol, respectively. Effects of electron correlation beyond MP2 are not large. The estimated CCSD(T) interaction energies of the methane, ethane, propane, and n-butane dimers at the basis set limit by the method of Helgaker et al. (-0.41, -1.22, -1.87, and -2.74 kcal/mol, respectively) from the CCSD(T)/cc-pVXZ (X=D and T) level interaction energies are close to the EMP2(limit) obtained using the same basis sets. The estimated EMP2(limit) values of the ten dimers were fitted to the form m0+m1X (X is 1 for methane, 2 for ethane, etc.). The obtained m0 and m1 (0.595 and -0.926 kcal/mol) show that the interactions between long n-alkane chains are significant. Analysis of basis set effects shows that cc-pVXZ (X=T, Q, or 5), aug-cc-pVXZ (X=D, T, Q, or 5) basis set, or 6-311G** basis set augmented with diffuse polarization function is necessary for quantitative evaluation of the interaction energies between n-alkane chains. 相似文献
92.
T.V.A. Lordani M.A. Brenzan L.E.R. Cortez C.R.F. Lordani P.A. Honda M.V.C. Lonardoni 《Natural product research》2015,29(10):953-957
This study evaluated the wound healing effects of topical application of an emulsion containing the HPLC-standardised extract from Calophyllum brasiliense Cambess (Clusiaceae) leaves in rats. The macroscopic analysis demonstrated that the wounds treated with the C. brasiliense emulsion healed earlier than the wounds treated with emulsion base and Dersani®. The percentage of wound healing in the group treated with the C. brasiliense emulsion was significantly higher than in the other groups at 7 and 14 days. On day 14, the animals treated with the C. brasiliense emulsion exhibited a 90.67% reduction of the wound areas. The histological evaluation revealed that on day 21, the group treated with the C. brasiliense emulsion exhibited a significant increase in fibroblasts compared with the other groups. Thus, the C. brasiliense emulsion had healing properties in the topical treatment of wounds and accelerated the healing process. 相似文献
93.
Nahoko Uchiyama Fumiyuki Kiuchi Gisho Honda Yoshio Takeda Ozodbek A. Ashurmetov 《Tetrahedron》2006,62(18):4355-4359
Trypanocidal constituents of Dracocephalum komarovi were investigated. Under guidance of the in vitro trypanocidal activity against epimastigotes of Trypanosoma cruzi, the causative agent of Chagas' disease, two new diterpenes, dracocequinones A (1) and B (2), and two known triterpene acids, ursonic acid and ursolic acid, were isolated as trypanocidal constituents, in addition to previously reported diterpenes, cyclocoulterone (4), komaroviquinone (5), dracocephalone A (6) and komarovispirone (7). Furthermore a new diterpene, komarovinone A (3), was isolated, together with four known terpenes. Among these compounds, komaroviquinone (5) showed the most potent activity with minimum lethal concentration of 0.4 μM. Structure elucidation of the new diterpenes 1-3 was described. 相似文献
94.
Hajime Kawakami Makio C. Honda Shuichi Watanabe Toshiro Sino 《Journal of Radioanalytical and Nuclear Chemistry》2014,301(2):461-468
We carried out time-series observations of 210Po and 210Pb radioactivity in the western North Pacific Ocean. The sinking fluxes of particulate organic carbon (POC) in the mesopelagic zone were estimated from 210Po radioactivity during several seasons in the subarctic and subtropical regions of the western North Pacific. The seasonal changes of POC fluxes at a depth of 400 m were larger in the subarctic region than in the subtropical region. The annual mean POC flux at a depth of 400 m was larger in the subarctic region (57 mgC m?2 day?1) than in the subtropical region (36 mgC m?2 day?1). The annual mean of the e-ratio (the ratio of POC flux to primary productivity) in the subarctic region (18 %) was about twice the e-ratio in the subtropical region (10 %). These results imply that the efficiency of the biological pump is larger in the subarctic region than in the subtropical region of the western North Pacific. 相似文献
95.
Uchiyama N Matsunaga K Kiuchi F Honda G Tsubouchi A Nakajima-Shimada J Aoki T 《Chemical & pharmaceutical bulletin》2002,50(11):1514-1516
Trypanocidal constituents of dried leaves of Laurus nobilis L. (Lauraceae) were examined. Activity-guided fractionation of the methanol extract resulted in the isolation of two guaianolides, dehydrocostus lactone (1) and zaluzanin D (2), and a new p-menthane hydroperoxide, (1R,4S)-1-hydroperoxy-p-menth-2-en-8-ol acetate (3). The minimum lethal concentrations of these compounds against epimastigotes of Trypanosoma cruzi were 6.3, 2.5, and 1.4 microM, respectively. 相似文献
96.
A home made column of commercially available iminodiacetate resin, Muromac A-1 (50–100 mesh) was used to concentrate rare earth elements (REEs) (15 elements: Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) in seawater. An automated low pressure flow analysis method with on-line column preconcentration/inductively coupled plasma mass spectrometry (ICP-MS) is described for the determination of REEs in seawater. Sample solutions (adjusted to pH of 3.0) passed through the column. After washing the column with water, the adsorbed elements were subsequently eluted into the plasma with 0.7 M nitric acid. Calibration curves were accomplished by means of purified artificial seawater with a sample loading time of 120 s. Detection limits (DLs) of the on-line column preconcentration/ICP-MS by eight replicate operations were between 0.040 and 0.251 pg ml−1 for REEs in the artificial seawater. The precision was less than 8.9% for REEs and one sample can be processed in 7 min using a 7 ml of sample. The proposed method was applied to determine REEs in coastal seawater of Hiroshima Bay, Japan. 相似文献
97.
98.
An on-line column preconcentration technique for flow-injection atomic absorption spectrometry was developed. Diverse metal ions (Cd2+, Zn2+, Cu2+, Mn2+, Pb2+, Fe3+ and Cr3+) in solution were concentrated quantitatively by a microcolumn (7-mm × 4-mm i.d.) packed with Muromac A-1, which is an iminodiacetate chelate resin, in a flow-injection system. From the pH dependence of the uptake of the ions, all the divalent metals examined were recovered quantitatively in the pH range 3–5 and the trivalent metals were recovered at a maximum pH of 1. Enrichment factors using 20-ml samples were in the range 90–180-fold for the seven elements and the sampling rate was 13 h?1. The 3σ detection limits were in the range 0.14–2.1 μg l?1 and the relative standard deviations for replicate measurements (n=3–4) were in the range 0.7–1.7%. The method was compared with flame and graphite furnace atomic absorption spectrometry. Application to the determination of cadmium and copper in several standard reference materials is described. 相似文献
99.
K. Oda Y. Kikawada T. Oi T. Honda 《Journal of Radioanalytical and Nuclear Chemistry》2008,277(2):475-478
A total of 19 elements in the samples of atmospheric deposition collected in Kawasaki, Japan, were determined by neutron activation
analysis, ICPAES and flame photometry. The amounts of soil dust depositions were larger in springs and those of Sb and Zn
depositions were larger in summers than in the other seasons. The values of the enrichment factors were higher for Sb and
Zn than for the other elements determined throughout the sampling period. A factor analysis showed that the two elements were
characterized as industrial components. Rubber products like tires that contain noncombustibles and rubber accelerators were
a possible origin of high concentrations of Sb and Zn in the present samples. 相似文献
100.
Kosumi D Kusumoto T Fujii R Sugisaki M Iinuma Y Oka N Takaesu Y Taira T Iha M Frank HA Hashimoto H 《Physical chemistry chemical physics : PCCP》2011,13(22):10762-10770
Carotenoids containing a carbonyl group in conjugation with their polyene backbone are naturally-occurring pigments in marine organisms and are essential to the photosynthetic light-harvesting function in aquatic algae. These carotenoids exhibit spectral characteristics attributed to an intramolecular charge transfer (ICT) state that arise in polar solvents due to the presence of the carbonyl group. Here, we report the spectroscopic properties of the carbonyl carotenoid fucoxanthin in polar (methanol) and nonpolar (cyclohexane) solvents studied by steady-state absorption and femtosecond pump-probe measurements. Transient absorption associated with the optically forbidden S(1) (2(1)A) state and/or the ICT state were observed following one-photon excitation to the optically allowed S(2) (1(1)B) state in methanol. The transient absorption measurements carried out in methanol showed that the ratio of the ICT-to-S(1) state formation increased with decreasing excitation energy. We also showed that the ICT character was clearly visible in the steady-state absorption in methanol based on a Franck-Condon analysis. The results suggest that two spectroscopic forms of fucoxanthin, blue and red, exist in the polar environment. 相似文献