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101.
K3Sb4BO13, Mr = 823.11 g.mol–1, crystallizes in the triclinic system, space group P
, Z = 2. The lattice parameters are a = 7.133(1) Å, b = 7.232(1) Å, c = 13.259(2) Å, = 82.00 (1)°, = 99.77(1)° and = 117.08(1)°, V = 598.7(2) Å3, Dx = 4.566 Mg m–3. The final R index and weighted Rw index are 0.0251 and 0.0623, respectively. The three-dimensional network of the title compound is constituted by layers (Sb3O9)n, similar to that of hexagonal bronze of Magneli. These layers are linked together, in the c direction, alternatively by edge-sharing pairs of SbO6 octahedra and BO3 triangles. This framework has interconnected tunnels, running approximately along the a and b directions, in which the K+ ions are located. 相似文献
102.
A variational formulation for a vibroacoustic problem of a membrane and a viscothermal fluid is investigated in this paper. The formulation combines a variational formulation by integral equations of the fluid, that takes into account the acoustic and entropic waves coupling, with a variational formulation of the membrane. The formulation has been implemented numerically for the problems with axisymmetric geometry. The numerical results are compared to the analytical solution for a circular membrane coupled to a cylindrical cavity filled with air. These results show the validity of numerical implementation and illustrate the thermal effects of air on the membrane-cavity system modes in the micro cavities cases. 相似文献
103.
Mohamed Tahar Kadaoui Abbassi Noura Amri Giovanni Calvaruso 《Mathematische Nachrichten》2020,293(10):1873-1887
The study of symmetries is a well known research topic in differential geometry with relevant physical interpretations. Given a Riemannian manifold , we consider pseudo-Riemannian g-natural metrics G on its tangent bundle and characterize conformal, homothetic and Killing vector fields of obtained from natural lifts of vector fields of M. 相似文献
104.
Journal of Thermal Analysis and Calorimetry - This paper aims to understand the characteristics of heat transfer and flow by natural convection of Al2O3–Cu/water-based hybrid nanofluid-filled... 相似文献
105.
Salem Saïd Noureddine Mhadhbi Fadhel Hajlaoui Samia Yahyaoui Alexander J. Norquist Tahar Mhiri 《Phase Transitions》2013,86(1):71-84
Single crystals of [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O (1) were grown through the slow evaporation of a solution containing H2SO4, (R)-C5H12N2 and CuSO4·5H2O. These crystals spontaneously transform to [(R)-C5H14N2]2[Cu(H2O)6](SO4)3 (2) over the course of four days at room temperature. The same single crystal on the same mounting was used for the determination of the structure of (1) and the unit cell determination of (2). A second single crystal of the transformed batch has served for the structural determination of (2). Compound 1 crystallizes in the noncentrosymmetric space group P21 (No. 4) and consists of trimeric [Cu(SO4)2(H2O)4]2? anions, [(R)-C5H14N2]2+ cations and occluded water molecules. Compound 2 crystallizes in P21212 (No. 18) and contains [Cu(H2O)6]2+ cations, [SO4]2? anions and occluded water molecules. The thermal decompositions of compounds 1 and 2 were studied by thermogravimetric analyses and temperature-dependent X-ray diffraction. 相似文献
106.
The synthesis of a series of selenate containing natrochalcite, A(I)M(II)(2)(H(3)O(2))(SeO(4))(2) where A = Na or K and M = Mn, Co, or Ni (here labeled as AMH and AMD for the hydrogenated and deuterated compounds, respectively), the X-ray crystal structure determinations from single crystals (Ni) and powder (Mn), magnetic properties, and magnetic structures of the cobalt analogues are reported. The nuclear crystal structures for NaNiH, KNiH, and KMnH are similar to those reported for the cobalt analogues (NaCoH and KCoH) and consist of chains of edge-sharing octahedra (MO(6)) which are connected by H(3)O(2) and SeO(4) to form layers which are in turn bridged by the alkali, in an octahedral coordination site, to form the 3D-framework. The magnetic properties are characterized by antiferromagnetic interaction at high temperatures and antiferromagnetic ordering at low temperatures (NaCoH, 3.5 K; KCoH, 5.9 K; KNiH, 8.5 K; and KMnH, 16 K), except for KNi(2)(H(3)O(2))(SeO(4))(2) which displays a weak ferromagnetic interaction and no long-range ordering above 2 K. The neutron magnetic structures of the cobalt analogues, studied as a function of temperature, are different for the two cobalt salts and also different from all the known magnetic structures of the natrochalcite family. Whereas the magnetic structure of NaCoD has a k = (0, 0, 0), that of KCoD has one consisting of a doubled nuclear cell, k = (0, 0, 1/2). Both compounds have four magnetic sublattices related to the four cobalt atoms of the nuclear unit cell. In NaCoD the moments are in the bc-plane, M(y) = 2.51(2) μ(B) and M(z) = 1.29(4) μ(B), with the major component along the cobalt chain and the resultant moment, 2.83(3) μ(B), making an angle of 27° with the b-axis. The sum of the moments within the cell is zero. For KCoD the moment at each cobalt site has a component along each crystallographic axis, M(x) = 2.40(3), M(y) = 1.03(3), M(z) = 1.59(8) giving a total M = 2.49(3) μ(B). Within one nuclear cell the moments are fully compensated. The moments corresponding to the cobalt atoms of the second nuclear cell comprising the magnetic unit cell are oriented in opposite directions. 相似文献
107.
Raida Jallouli Fatma Khrouf Ahmed Fendri Tahar Mechichi Youssef Gargouri Sofiane Bezzine 《Applied biochemistry and biotechnology》2012,168(8):2330-2343
An extracellular lipase from Fusarium solani strain (F. solani lipase (FSL)) was purified to homogeneity by ammonium sulphate precipitation, gel filtration and anion exchange chromatography. The purified enzyme has a molecular mass of 30 kDa as estimated by sodium dodecyl sulphate polyacrylamide gel electrophoresis. The 12 NH2-terminal amino acid residues showed a high degree of homology with a putative lipase from the fungus Necteria heamatoccocae. It is a serine enzyme, like all known lipases from different origins. Interestingly, FSL has not only lipase activity but also a high phospholipase activity which requires the presence of Ca2+ and bile salts. The specific activities of FSL were about 1,610 and 2,414 U/mg on olive oil emulsion and egg-yolk phosphatidylcholine as substrates, respectively, at pH 8.0 and 37 °C. The (phospho)lipase enzyme was stable in the pH range of 5–10 and at temperatures below 45 °C. 相似文献
108.
Asymmetric hydrogenation of 1-aryl-3,4-dihydroisoquinolines using the [IrCODCl](2)/(R)-3,5-diMe-Synphos catalyst is reported. Under mild reaction conditions, this atom-economical process provides easy access to a variety of enantioenriched 1-aryl-1,2,3,4-tetrahydroisoquinoline derivatives, which are important pharmacophores found in several pharmaceutical drug candidates, in high yields and enantiomeric excesses up to 99% after a single crystallization. 相似文献
109.
Hajlaoui F Naïli H Yahyaoui S Turnbull MM Mhiri T Bataille T 《Dalton transactions (Cambridge, England : 2003)》2011,40(43):11613-11620
A series of novel organically templated metal sulfates, [C(5)H(14)N(2)][M(II)(H(2)O)(6)](SO(4))(2) with (M(II) = Mn (1), Fe (2), Co (3) and Ni (4)), have been successfully synthesized by slow evaporation and characterized by single-crystal X-ray diffraction as well as with infrared spectroscopy, thermogravimetric analysis and magnetic measurements. All compounds were prepared using a racemic source of the 2-methylpiperazine and they crystallized in the monoclinic systems, P2(1)/n for (1, 3) and P2(1)/c for (2,4). Crystal data are as follows: [C(5)H(14)N(2)][Mn(H(2)O)(6)](SO(4))(2), a = 6.6385(10) ?, b = 11.0448(2) ?, c = 12.6418(2) ?, β = 101.903(10)°, V = 906.98(3) ?(3), Z = 2; [C(5)H(14)N(2)][Fe(H(2)O)(6)](SO(4))(2), a = 10.9273(2) ?, b = 7.8620(10) ?, c = 11.7845(3) ?, β = 116.733(10)°, V = 904.20(3) ?(3), Z = 2; [C(5)H(14)N(2)][Co(H(2)O)(6)](SO(4))(2), a = 6.5710(2) ?, b = 10.9078(3) ?, c = 12.5518(3) ?, β = 101.547(2)°, V = 881.44(4) ?(3), Z = 2; [C(5)H(14)N(2)][Ni(H(2)O)(6)](SO(4))(2), a = 10.8328(2) ?, b = 7.8443(10) ?, c = 11.6790(2) ?, β = 116.826(10)°, V = 885.63(2) ?(3), Z = 2. The three-dimensional structure networks for these compounds consist of isolated [M(II)(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+) cations and (SO(4))(2-) anions linked by hydrogen-bonds only. The use of racemic 2-methylpiperazine results in crystallographic disorder of the amines and creation of inversion centers. The magnetic measurements indicate that the Mn complex (1) is paramagnetic, while compounds 2, 3 and 4, (M(II) = Fe, Co, Ni respectively) exhibit single ion anisotropy. 相似文献
110.
Moulay Tahar Sougrati Malick Jean Samuel Jouen Charly Vaudolon Béatrice Hannoyer 《Hyperfine Interactions》2012,211(1-3):83-97
The operation of a gas counter, designed for Conversion Electron M?ssbauer Spectroscopy measurement at low temperature, has been investigated. The experimental setup is described and tested with two pure gases, He and Ne, and two mixtures, He-5%CH4 and He-5%N2. The impacts on the counter performances of the applied voltage, the gas composition and pressure as well as the gas renewing are investigated between 41?K and 300?K. This investigation is made using 119Sn M?ssbauer source and metallic tin absorber. The appropriate operating conditions of the present counter have been established for temperatures down to 41?K for both pure gases, and 61 and 85?K for He-5%N2 and He-5%CH4 respectively. 相似文献