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971.
Seung U. Lee Mun Heum Park Jin Won Kim Hyeun Kyung Jo Won-Jeong Kim 《Applied Surface Science》2007,254(5):1493-1497
Ferroelectric BiFeO3 thin films with Nd-Cr (or Sm-Cr) co-substitution (denoted by BNdFCr and BSmFCr, respectively) were deposited on the Pt(2 0 0)/TiO2/SiO2/Si(1 0 0) substrates by a chemical solution deposition method. X-ray diffraction patterns revealed the formation of BNdFCr and BSmFCr thin films without any secondary phases. The co-substituted BNdFCr (or BSmFCr) thin films, which were annealed at 550 °C for 30 min in N2 atmosphere, exhibited enhanced electrical properties compared to BFO thin films with the remanent polarization (2Pr) and coercive electric field (2Ec) of 196, 188 μC/cm2 and 600, 570 kV/cm with the electric field of 800 kV/cm, respectively. The leakage current densities of BNdFCr and BSmFCr thin films measured at room temperature were approximately three orders of magnitude lower than that of BFO thin film, and the leakage current at room temperature of the thin films exhibited three distinctive conduction behaviors. Furthermore, the values of pulse polarizations [i.e., +(P*-P^) or −(P*-P^)] of BNdFCr and BSmFCr thin films were reasonably unchanged up to 1.4 × 1010 switching cycles. 相似文献
972.
Jing Jin Mark Prochaska Dominic Rochefort David K. Kim Lin Zhuang Francis J. DiSalvo R.B. van Dover Héctor D. Abruña 《Applied Surface Science》2007,254(3):653-661
We used a high-throughput method to screen for direct methanol fuel cell anode electrocatalysts in the Pt-Bi-Pb system. Previous studies showed that PtBi and PtPb (both NiAs structure type) were active electrocatalysts for the oxidation of formic acid, but only PtPb was active in oxidizing methanol. We synthesized thin films with continuous composition spreads of the three elements by magnetron sputtering at deposition temperatures from ambient to 510 °C. A fluorescence method was then used to identify compositions that were active toward methanol oxidation. Only films deposited between temperatures of 160 and 400 °C showed electrocatalytic activity. The areas that were active for methanol oxidation showed predominantly the NiAs structure type according to XRD, with optimal activity for compositions near PtBi0.01Pb0.53. 相似文献
973.
Hwa-Min Kim 《Physics letters. A》2007,371(4):314-317
The dynamic plasma screening and non-Maxwellian effects on elastic electron-ion collisions are investigated in generalized Lorentzian distribution plasmas. The eikonal is employed to obtain the eikonal phase as a function of the spectral index, impact parameter, collision energy, thermal energy, and Debye length. The result shows that the non-Maxwellian effect suppresses the eikonal phase. It is found that the dynamic screening effect significantly enhances the elastic collision cross section for the low thermal energy case. In addition, the eikonal collision cross section is increased by the non-Maxwellian effect. 相似文献
974.
We employ angle-resolved photoemission to characterize the electronic band structure of the Pb "nanowire" array self-assembled on a stepped Si(111) surface. Despite the highly oriented nanowires observed in scanning tunneling microscopy images, we find essentially two-dimensional Fermi contours modulated one dimensionally perpendicular to the wires. This strong two-dimensional and quasi-one-dimensional nature of the band structure explains the stability and anisotropy of the metallic phase down to 4 K as reported recently. A simple tight-binding model with each Si nanoterrace covered by a densely packed Pb overlayer successfully reproduces this modulated band structure and quantifies the electron coupling within the "nanostripes" and the step-edge potential. 相似文献
975.
Lee KI Joo SJ Lee JH Rhie K Kim TS Lee WY Shin KH Lee BC LeClair P Lee JS Park JH 《Physical review letters》2007,98(10):107202
Tunneling magnetoresistance was found to be suppressed with decreasing temperature for magnetic tunnel junctions (MTJs) oxidized under high plasma power. A strong temperature dependence of the junction resistance was observed, along with zero-bias anomalies of dynamic resistance at low temperatures. Resistance shows a logarithmic dependence on temperature, and resistance versus temperature exhibits a scaling behavior. Our experimental data can be explained in a consistent way by the Kondo effect in the MTJs with the Kondo temperature TK=20-30 K. 相似文献
976.
We show that the phase transition from the decelerating universe to the accelerating universe, which is of relevance to the cosmological coincidence problem, is possible in the semiclassically quantized two-dimensional dilaton gravity by taking into account the noncommutative field variables during the finite time. Initially, the quantum-mechanically induced energy from the noncommutativity among the fields makes the early universe decelerate and subsequently the universe is accelerating because the dilaton driven cosmology becomes dominant later. 相似文献
977.
Jong-Moo Lee Yong-Soon Baek Kwang-Ryong Oh Hyung-Jong Lee Yong-Seok Kim 《Optics Communications》2007,270(2):189-194
We investigate on the variation of loss and temperature dependence of a polymeric arrayed waveguide grating (AWG) depending on its substrate, by fabricating 16-channel polymeric AWGs with various substrate conditions. Insertion loss for a polymeric AWG on a silicon substrate is measured as low as 3.1 dB. The temperature-dependent wavelength shift for a polymeric AWG detached from the substrate is maintained within 0.1 nm from 20 to 80 °C. But we observe a degradation of insertion loss and a little instability in wavelength characteristics both for the detached polymeric AWG and for a polymeric AWG on a polymer substrate. We investigate on those optical properties of the polymeric AWGs based on measured thermal expansion properties of the polymers. 相似文献
978.
Anilinolysis of O‐butyl phenyl phosphonochloridothioate in acetonitrile: Synthesis,characterization, kinetic study,and reaction mechanism 下载免费PDF全文
This paper describes a simple optimized method for the synthesis of O‐butyl phenyl phosphonochloridothioate ( 4 ) under mild conditions. The target compounds were characterized by 1H‐nuclear magnetic resonance (NMR), 13C‐NMR, and 31P‐NMR spectroscopy, as well as mass spectroscopy. The apparent structure of 4 was confirmed by optimization using the B3LYP/6‐311 + G(d,p) level in the Gaussian 09 program in acetonitrile. The nucleophilic substitution reactions of 4 with X‐anilines (XC6H4NH2) and deuterated X‐anilines (XC6H4ND2) were investigated kinetically in acetonitrile at 55.0°C. The free energy relationship with X in the anilines looked biphasic concave upwards with a break region between X = H and X = 3‐MeO, giving large negative ρX and small positive βX values. The deuterium kinetic isotope effects were secondary inverse (kH/kD < 1: 0.789‐0.995) and the magnitudes, (kH/kD), increased when the nucleophiles were changed from weakly basic to strongly basic anilines. A concerted SN2 mechanism is proposed on the basis of the selectivity parameters and the variation trend of the deuterium kinetic isotope effects with X. 相似文献
979.
Simple expressions of the reflection and transmission coefficients of fundamental Lamb waves by a rectangular notch 总被引:1,自引:0,他引:1
The scattering of Lamb waves by a two-dimensional rectangular notch is investigated for rapid inspection of defects in a structure. To derive the reflection and transmission coefficients of the scattered waves in a simple way, the scattering caused by the notch is analyzed through the composition of individual scattering processes. Linear equations corresponding to the reflection and transmission coefficients are constructed along with scattering graphs. For an illustration of the efficacy of the presented method, the scattering of fundamental symmetric and anti-symmetric modes are inspected according to the depth and width of a notch in a plate. Validity of these expressions is demonstrated by the comparison of the theoretical analysis results with those from the finite element analysis. 相似文献
980.
We look for a Brans-Dicke type generalization of Horava-Lifshitz gravity. It is shown that such a generalization is possible within the detailed balance condition. Classically, the resulting theory reduces in the low energy limit to the usual Brans-Dicke theory with a negative cosmological constant for certain values of parameters. We then consider homogeneous, isotropic cosmology and study the effects of the new terms appearing in the model. 相似文献