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11.
A kinetic study of the fluoride ion catalyzed isomerization of a series of 2-aryl1-butenes shows the reactions to be pseudo first order in olefin at constant fluoride ion concentration. The resultant Hammett plot is non-linear witb a concave downward break near =0. A two step mechanism involving formation of a carbanionic intermediate is proposed. A change in the rate limiting step causes the break in the Hammett plot. Carbanion trapping experiments are also reported. 相似文献
12.
Hau Sun Sam Chan Amber L. Thompson Kirsten E. Christensen Jonathan W. Burton 《Chemical science》2020,11(42):11592
Laurefurenynes C–F are four natural products isolated from Laurencia species whose structures were originally determined on the basis of extensive nuclear magnetic resonance experiments. On the basis of a proposed biogenesis, involving a tricyclic oxonium ion as a key intermediate, we have reassigned the structures of these four natural products and synthesized the four reassigned structures using a biomimetic approach demonstrating that they are the actual structures of the natural products. In addition, we have developed a synthesis of the enantiomers of the natural products laurencin and deacetyllaurencin from the enantiomer of (E)-laurefucin using an unusual retrobiomimetic strategy. All of these syntheses have been enabled by the use of tricyclic oxonium ions as pivotal synthetic intermediates.The synthesis and structural reassignment of laurefurenynes C–F has been achieved, with the new structures fitting with a proposed biosynthesis. Also reported is the synthesis of ent-laurencin and ent-deacetyllaurencin via a retrobiomimetic approach. 相似文献
13.
14.
Burton A Elomari S Chen CY Medrud RC Chan IY Bull LM Kibby C Harris TV Zones SI Vittoratos ES 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(23):5737-5748
The syntheses, structure solutions, and physicochemical and catalytic characterizations of the novel zeolites SSZ-53 and SSZ-59 are described. SSZ-53 and SSZ-59 were synthesized under hydrothermal conditions with the [1-(4-fluorophenyl)cyclopentylmethyl]trimethyl ammonium cation and 1-[1-(4-chlorophenyl)cyclopentylmethyl]-1-methyl azocanium cation, respectively, as structure-directing agents. The framework topology of SSZ-53 was solved with the FOCUS method, and the structure of SSZ-59 was determined by model building. Rietveld refinement of synchrotron X-ray powder diffraction data confirms each proposed model. SSZ-53 and SSZ-59 each possess a one-dimensional channel system delimited by 14-membered rings. Results from transmission electron microscopy, electron diffraction, catalytic experiments (spaciousness index and constraint index tests), and argon and hydrocarbon adsorption experiments are consistent with the proposed structures. 相似文献
15.
Peter G. Burton 《Chemical physics》1974,6(3):419-430
The key components of a completely theoretical parametrization of the essential-structural-elements molecular orbital (ESE MO) formalism using Slater-type AO basis in the LCAO SCF procedure are discussed. Special attention is paid to the problem of separability into core and valence parts of the total molecular wavefunction, including the case where valence functions strongly overlap neighbouring core orbitals. The use of Huzinaga and Cantu effective hamiltonian is proposed. The parametrization is tested in relation to the SO2 molecules. The role of sulphur 3d functions in bonding as predicted by the present ESE MO calculations and ab initio calculations are compared. The present parametrization appears to adequately handle both the core/valence separation, and the diffuse higher valence sulphur 3d functions in this system. 相似文献
16.
The effect of injection procedures on efficiency in micellar electrokinetic capillary chromatography
Summary Micellar electrokinetic capillary chromatography (MECC) involves the application of a high voltage (10–30 KV) across a capillary
column (75μm i.d.) which is filled with a solution containing micelles. The mobile phase in this work consisted of sodium
dodecyl sulfate in an aqueous borate/phosphate buffer system. Injection parameters in MECC were investigated to minimize the
contribution to band-broadening resulting from the injection process. Efficiencies as high as 240,000 theoretical plates/meter
are reported. 相似文献
17.
Ryan R. Burton 《Tetrahedron letters》2006,47(40):7185-7189
Ruthenium-catalyzed [2+2] cycloadditions between C1-substituted 7-oxanorbornadienes and alkynes were investigated. Most of the cycloadditions occurred smoothly at 65 °C, giving the cyclobutene cycloadducts in moderate to good yields. The C1 substituent showed strong effect on the regioselectivity (up to 110:1) of the cycloadditions. 相似文献
18.
Diethyl bromodifluoromethyl phosphonate reacts readily with cadmium metal to form a stable cadmium complex. Depending on solvent, this functionalized organocadmium reagent exhibits stability for days to months. It reacts with a variety of electrophiles and serves as a synthetically useful source for the introduction of the difluoromethylene phosphonate group into organic compounds.The synthetic utility of a wide variety of fluoromethylene phosphonium ylides has been a major effort in our laboratory over the past several years [1]. The generation and capture of difluoromethylene ylides () as a general route to difluoromethylene olefins has been of especial interest to us [2]. In an effort to increase the nucleophilicity of the ylide, we have attempted to prepare the analogous phosphonate ylide (). Although we have achieved modest success [3] by capture of () in the reaction of sodium dialkyl phosphites with diethyl bromodifluoromethylphosphonate (), attempts to pregenerate (), either from diethyl difluoromethylphosphonate () or (), have met with little success. () appears to have minimal stability even at low temperatures, and scale up processes of synthetic value would seem to be difficult. 相似文献
19.
Xin ZhangDonald J. Burton 《Journal of fluorine chemistry》2002,116(1):15-18
The organometallic reagent, (EtO)2P(O)CF2ZnBr, reacts with 1-alkynyl halides (halide=Br, I) in the presence of Cu(I)Br to give good yields of α,α-difluoropropargylphosphonates via a one pot reaction. 相似文献
20.
An isocratic reversed-phase high-performance liquid chromatographic method for the analysis of 13-cis-retinoic acid in serum is developed. Sample preparation includes deproteination with acetonitrile-perchloric acid-acetic acid followed by centrifugation. 9-Methylanthracene is used as the internal standard. Chromatographic separation is achieved on a C18 column (Zorbax) using an acetonitrile-aqueous 0.5% acetic acid (85:15, v/v) eluent containing 0.05% (w/v) sodium hexanesulfonate. The limit of detection is 12 ng/ml in serum, using 0.5 ml samples. Quantitative recoveries and excellent intra-day and inter-day precision are reported. 相似文献