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941.
A study is made of the effect of the atomic number zs of the support on the charging of thin dielectric films irradiated with 50-keV electrons at beam densities of 10–5–10–4 A·m2. It is shown that at larger zs the ratio between the charge-injection and pair-production rate increases, producing a higher space-charge buildup efficiency. The maximum charge increases with the current density, while is not affected. It is found that the charging process is associated with a spacecharge current.Translated from Izvestiya Vysshikh Uchebnkh Zavedenii, Fizika, pp. 14–18, No. 1, January, 1986. 相似文献
942.
The problem of the temporal and spatial dependences of the parameters of the action of a modulated fast-electron beam on a dense gas is posed on the basis of the transport equation. The problem is simplified by making it nondimensional and by transforming to the Fokker-Planck approximation. A Green's function formalism is developed for this problem and is used to express the solution of the general nonstationary problem in the form of a convolution of a nonstationary boundary flow with a stationary Green's function. The use of the derived equation is illustrated using as an example the solution of a problem with the simplest stationary Green's function corresponding to the straight-ahead approximation. This approximation is used to consider a general relativistic case with model scattering cross sections. The methods and results of a numerical computer solution of the nonstationary problem of electron retardation in the upper layer of the atmosphere are surveyed.Translated from Trudy Ordena Lenina Fizicheskogo Instituta im. P. N. Lebedeva AN SSSR, Vol. 145, pp. 172–188, 1984. 相似文献
943.
This paper shows the separation and determination of eight compounds containing the OH group (ethanol, pentanol, 3-methyl-1-butanol, hexanol, phenol, benzyl-alcohol, phenylethanol and geraniol) in synthetic wine by gas chromatography using UV-Vis molecular absorption spectrometry as detection system. All the parameters affecting the separation and determination were optimised using some methods of experiment design. The analytical characteristics of each compound were calculated and detection limits ranging from 2.3 to 74 mg l(-1) have been obtained. 相似文献
944.
M. T. Czyżyk M. Podgórny A. Balzarotti P. Letardi N. Motta A. Kisiel M. Zimnal-Starnawska 《Zeitschrift für Physik B Condensed Matter》1986,62(2):153-161
Using the new information supplied by extended-x-ray-absorption-fine-structure measurements and the results of our structural model, we compute the bond probability of a few ternary semiconducting III–V and II–VI alloys as a function of temperature and composition in the framework of a modified quasi-chemical approximation. We derive the thermodynamic functions of mixing, considering both elastic and chemical contributions to the bond energies. We examine how the deviation from the full randomness affects the ordering of such alloys and we construct the phase diagrams in the region of phase separation. Possible formation of ordered compounds at low temperatures is predicted. 相似文献
945.
946.
E. A. Kuznetsova S. V. Zhuravlev T. N. Stepanova 《Chemistry of Heterocyclic Compounds》1970,4(2):183-185
The reduction of some dihydrothiazolobenzothiazolium salts with sodium borohydride may take place in two directions: with the formation of thiazolidino[2, 3-b]benzathiazolines and with the cleavage of the C-S bond to give N-(-mercaptoethyl)benzothiazolines. The behavior of thiazolidino[2, 3-b]benzothiazoline under the conditions of acid and alkaline hydrolysis has been studied.For communication VI, see [1]. 相似文献
947.
948.
949.
The method of quasi-equilibrium galvanostatic curves was applied to study the thermodynamics of lithium deintercalation from the system Li
x
C6 (solid phase)/Li+ (solution) in the interval 293-323 K and the thermodynamic characteristics (G, S, H) of lithium intercalation compounds in a carbonized fabric in relation to the degree of intercalation x. 相似文献
950.
T. A. Zyablikova A. V. Il'yasov S. N. Ignat'eva S. F. Malatsion O. A. Erastov 《Russian Chemical Bulletin》1990,39(4):688-691
We have established that direct phosphorus-selenium spin-spin coupling constants in cyclic compounds with P=Se exocyclic and P-C endocyclic bonds are found in the range1JPSe=–708 to –859 Hz; in this case, it is greater for the axial orientation of P=Se than for the equatorial orientation.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 776–780, April, 1990. 相似文献