Reaction of D2 with palladium fulleride C60Pd4.9

Fullerene deuteride was obtained by the reaction of deuterium with solid palladium fulleride C₆₀Pd_4.9 under fairly mild conditions. The compound was identified by FD-MS, UV-Vis and IR spectroscopies, and TLC.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 483–484, February, 1996     

Kinetics of zinc(II) cloride extraction with tributyl phosphate

The equilibrium and rate of solvent extraction of zinc chloride complexes from HCl solutions into benzene solutions of tributyl phosphate (TBP) have been studied. The extracted species are discussed in the light of the results. The extraction was found to be first order with respect to both Zn(II) and TBP, and zero order for HCl. The rate-controlling steps are discussed and the rate constants for these reactions are calculated.     

Noncoercive Boundary Value Problems for Elliptic Partial Differential and Differential-Operator Equations

In this paper we find conditions guarantee that irregular boundary value problems for elliptic differential-operator equations of the second order in an interval are fredholm. We apply this result to find some algebraic conditions guarantee that irregular boundary value problems for elliptic partial differential equations of the second order in cylindrical domains are fredholm. Apparently this is the first paper where the regularity of an elliptic boundary value problem is not satisfied on a manifold of the dimension equal to dimension of the boundary. Nevertheless the problem is fredholm and the resolvent is compact. It is interesting to note that the considered boundary value problems for elliptic equations in a cylinder being with separating variables are noncoercive.     

Geometric quantization of topological gauge theories

We show that Abelian gauge theories in 2+1 space-time dimensions with the introduction of a topological Chern-Simons term can be quantized with the use of the symplectic formalism. The consistency of our results are verified by the agreement with the ones from the Dirac case.     

Optimal algebraic multilevel preconditioning for local refinement along a line

The application of some recently proposed algebraic multilevel methods for the solution of two-dimensional finite element problems on nonuniform meshes is studied. The locally refined meshes are created by the newest vertex mesh refinement method. After the introduction of this refinement technique it is shown that, by combining levels of refinement, a preconditioner of optimal order can be constructed for the case of local refinement along a line. Its relative condition number is accurately estimated. Numerical tests demonstrating the performance of the proposed preconditioners will be reported in a forthcoming paper.     

THE USE OF THERMOELASTICITY TO EVALUATE STRESS REDISTRIBUTION AND NOTCH SENSITIVITY IN CERAMIC MATRIX COMPOSITES

Thermoelastic stress analysis was used to document the effect of composite damage on the stress distribution in three ceramic matrix composites. Composite damage was found to significantly alter the thermoelastic response of each material, with the greatest effect noted in SiC/CAS. Thermoelastic imaging of these materials affords a more complete picture of how the various damage mechanisms affect the stress distribution. In particular, a stress concentration factor computed from thermoelastic images, serves as an indicator of stress redistribution. The stress concentration factors were computed by comparing notch root to far field temperatures, and monitored after the introduction of various amounts of damage. In each material, the stress concentration factor diminished as the damaging load approached the ultimate stress. Reduction in the stress concentration is associated with local changes in modulus, mechanistically arising from combinations of fiber, matrix and interface fracture. Stress redistribution occurs as a consequence of modulus changes, leading to lower notch sensitivity in each of the tested composites.     

The effect of complexing processes on energy transfer Tl+→Gd3+ and Tl+→Tb3+ in glass

T. Shevchenko Kiev University, 252022 Kiev, Pr. Akad. Glushakova, 6, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 3, pp. 192–196, May–June, 1995.