Graphene as a reversible spin manipulator of molecular magnets

One of the primary objectives in molecular nanospintronics is to manipulate the spin states of organic molecules with a d-electron center, by suitable external means. In this Letter, we demonstrate by first principles density functional calculations, as well as second order perturbation theory, that a strain induced change of the spin state, from S=1→S=2, takes place for an iron porphyrin (FeP) molecule deposited at a divacancy site in a graphene lattice. The process is reversible in the sense that the application of tensile or compressive strains in the graphene lattice can stabilize FeP in different spin states, each with a unique saturation moment and easy axis orientation. The effect is brought about by a change in Fe-N bond length in FeP, which influences the molecular level diagram as well as the interaction between the C atoms of the graphene layer and the molecular orbitals of FeP.     

Crystallization and structural relaxation in quasicrystalline Al6CuMg4

We report here electron microscopic, differential scanning calorimetric (DSC) and X-ray diffraction studies on the phase transition in Al₆CuMg₄ alloy. Structural analysis of the transformed crystalline phase suggests that some of the lattice sites, which define the vertices of triacontahedron - the basic volume element of three dimensional Penrose tiling for this system - are fractionally occupied. We also observed that the specific heat of the as grown quasicrystalline alloy reduces gradually from 1.08J/gm. K at 330K to the Dulong Petit value 0.84J/gm. K around 420K, due to structural relaxation of the quasicrystalline phase.     

Colloidal Microcapsules: Self‐Assembly of Nanoparticles at the Liquid–Liquid Interface

Colloidal microcapsules (MCs) are highly modular, inherently multiscale constructs of capsules stabilized by nano‐/microparticle shells, with applications in many areas of materials and biological sciences, such as drug delivery, encapsulation, and microreactors. Until recently, fabrication of colloidal MCs focused on the use of submicron‐sized particles because the smaller nanoparticles (NPs) are inherently unstable at the interface owing to thermal disorder. However, stable microcapsules can now be obtained by tuning the interactions between the nanometer‐sized building blocks at the liquid–liquid interface. This Review highlights recent developments in the fabrication of colloidal MCs using NPs.     

Dendronized polymers via Diels–Alder “click” reaction

A modular approach toward the synthesis of polymers containing dendron groups as side chains is developed using the Diels–Alder “click” reaction. For this purpose, a styrene‐based polymer appended with anthracene groups as reactive side chains was synthesized. First through third‐generation polyester dendrons containing furan‐protected maleimide groups at their focal point were synthesized. Facile, reagent‐free, thermal Diels–Alder cycloaddition between the anthracene‐containing polymer and latent‐reactive dendrons leads to quantitative functionalization of the polymer chains to afford dendronized polymers. The efficiency of this functionalization step was monitored using ¹H and ¹³C NMR spectroscopy and FTIR and UV–vis spectrometry. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 410–416, 2010     

Anisotropy of the electron momentum distribution in Bi2Sr2CaCu2O8+δ superconductor studied by positron annihilation

The temperature dependent (30-300 K) Doppler broadening of the positron annihilated γ-radiation measurement has been investigated on single crystalline Bi₂Sr₂CaCu₂O_8+δ (Bi-2212) high T_c superconducting samples along two different crystallographic orientations. It has been observed that throughout the temperature range the electron momentum distribution has a larger value along the crystallographic c-axis than in the a-b plane. The temperature dependent Doppler broadened positron annihilation γ-radiation lineshape analysis shows a step like increase of S-parameter at the temperature region 92-116 K.     

Phonon dispersion in aluminium arsenide and antimonide

The phonon dispersion curves for aluminium arsenide and antimonide have been investigated by using a deformation bond approximation model. The results obtained from this model are compared with the experimental values wherever it is available. Since there is no complete experimental phonon dispersion curves for AlAs, we could not compare our calculated results, but the results of AlSb have been compared with the inelastic neutron scattering measurements at 15 K. However, we compare the phonon frequencies of AlAs and AlSb at critical points of the Brillouin zone obtained by our calculations and Raman spectroscopy measurements. This model predicts the phonon modes satisfactorily in all the symmetry directions of the Brillouin zone (BZ). The spectrum has similar features as observed in other III–V compound semiconductors.     

Baryon inhomogeneities due to cosmic string wakes at the quark-hadron transition

Baryon inhomogeneities generated during the quark-hadron transition may alter the abundances of light elements if they persist up to the time of nucleosynthesis. These inhomogeneities survive up to the nucleosynthesis epoch if they are separated by a distance of at least a few metres. In this work we present a model where large sheets of these inhomogeneities separated by a distance of a few km are formed by cosmic string wakes during the quark-hadron transition. The effect of these sheets on nucleosynthesis will also put constraints on the various cosmic string parameters.     

On the perfect penrose tiling and its basic building blocks

We show that the basic building blocks of a perfect Penrose pattern (PPT) in two dimensions can be established by adding another condition to the Penrose’s original edge rules. The implications of this result are discussed in the context of recent papers by Onada, Jaric, Ronchetti and others concerning growth algorithm for PPT’s.     

Hydromagnetic slip flow with heat transfer in an inclined channel

The problem of steady two-dimensional laminar flow in slip flow regime of a viscous incompressible and electrically conducting fluid through an inclined channel of rectangular cross-section in presence of a transverse magnetic field has been considered. The walls of the channel are assumed to have prescribed temperatures and finite conductivities. The expressions for the velocity component, induced magnetic field and the temperature are obtained and their numerical results are shown graphically.     

Interaction of dimethyl sulphoxide with chloranil by ESR and optical methods

The molecular charge-transfer absorption bands have been observed in solution of dimethyl sulphoxide (DMSO) and tetrachloro-p-benzoquinone (chloranil) in chloroform and cyclohexanone. The stability constant, the thermodynamic parameter of the complex and the extinction co-efficient of CT bands at 350 nm in chloroform and 360 nm in cylohexanone have been estimated on the assumption of the 1:1 complex formation. Detection of ESR signal of the solution of chloranil in pure DMSO (g ≈ 2) indicates the formation of chloranil radical anion, the precursor being the charge-transfer complex, which dissociates partly in high dielectric constant DMSO.