Fourier transform spectral interferometric coherent anti-Stokes Raman scattering (FTSI-CARS) spectroscopy

A novel Fourier transform spectral interferometric (FTSI) multiplex coherent anti-Stokes Raman scattering (CARS) technique is developed to extract the vibrational spectrum equivalent to the spontaneous Raman scattering. The conventional FTSI method is modified to use the internal nonresonant CARS signal as a local oscillator to perform spectral interferometry. Utilizing the causality of the coherent vibration (i.e., there should be no signal before the laser excitation), this new FTSI method recovers the entire complex vibrational spectral parameters. We demonstrate this technique with a previously reported single-pulse multiplex CARS method that uses a single phase-controlled broadband ultrafast laser pulse.     

Synthesis of ZnO nanospheres with uniform nanopores by a hydrothermal process

ZnO nanospheres were successfully synthesized by a hydrothermal process (S1 sample) and a wet-chemical method (S2 sample). Following synthesis, calcination treatment at 450 °C was performed for the sample prepared by the wet-chemical method (S3 sample). All of the samples possessed a regular spherical shape. A polycrystalline wurtzite structure was confirmed in the S1 and S3 samples by X-ray diffraction and selected area electron diffraction, whereas a mixture of ZnO nanoparticles and amorphous materials was observed in the sample S2. The surface area and pore structure of the samples were investigated by nitrogen adsorption–desorption measurements. Uniform nanopores with a diameter of 4.07 nm were present in the S1 sample while a broad pore size distribution was obtained for the S2 and S3 samples. The highest surface area was obtained for the S1 sample and a possible formation mechanism was studied.     

Angular dependence of the dipole-dipole interaction in a nearly one-dimensional sample of Rydberg atoms

Atoms in an ultracold highly excited sample are strongly coupled through the dipole-dipole interaction. In an effort to understand and manipulate the complicated interactions in this system we are investigating their dependence on the relative orientation of the dipoles. By focusing a 480 nm beam from a tunable dye laser into a magneto-optical trap, we produce a nearly one-dimensional sample of Rydberg atoms. The trap lies at the center of four conducting rods with which we can vary the magnitude and direction of the electric field at the trap, thus controlling the orientation of the dipoles with respect to the sample axis. We have measured the strength of the interaction for a variety of relative orientations.     

SnO<Subscript>2</Subscript> nanowires bridged across trenched electrodes and their gas-sensing characteristics

By using a thermal chemical vapor deposition and Au-catalyzed in situ alignment and growth process, SnO₂ nanowires could be bridged across trenched electrodes. In this process, a complicated and individual alignment process could be avoided and a number of devices can be fabricated in one step in a wafer scale. The gas-sensing characteristics of the developed sensor were significantly better when compared to those of other types of NO₂ sensors reported in the literature. When the concentration of NO₂ was 5 ppm, the sensitivity was higher than 150. Especially, the reaction time of 8–14 s was noticeably fast, which is attributed to the microtrench structure beneath the nanowires. PACS 61.46.Fg; 85.35.Kt; 81.15.Gh     

Antiferromagnetic interactions in Er-doped SnO<Subscript>2</Subscript> DMS nanoparticles

Diluted magnetic semiconductor (DMS) nanoparticles of Sn_1−x Er _x O₂ (x = 0.0, 0.02, 0.04, and 0.1) were prepared by sol–gel method. The X-ray diffraction patterns showed SnO₂ rutile structure for all samples with no impurity peaks. The decrease in crystallite size with Er concentration was confirmed from TEM measurements (from 12 to 4 nm). The UV–Visible absorption spectra of Er-doped SnO₂ nanoparticles showed blue shift in band gap compared to undoped SnO₂. The electron spin resonance analysis of Er-doped SnO₂ nanoparticles indicate Er³⁺ in a rutile lattice and also decrease in intensity with Er concentration above x = 0.02. Temperature-dependent magnetization studies and the inverse susceptibility curves indicated increased antiferromagnetic interaction with Er concentration.     

Long period grating cascaded to photonic crystal fiber modal interferometer for simultaneous measurement of temperature and refractive index

We propose and demonstrate a novel and simple dual-parameter measurement scheme based on a cascaded optical fiber device of long-period grating (LPG) and photonic crystal fiber (PCF) modal interferometer. The temperature and refractive index (RI) can be measured simultaneously by monitoring the spectral characteristics of the device. The implemented sensor shows distinctive spectral sensitivities of -30.82 nm/RIU (refractive index unit) and 47.4 pm/°C by the LPG, and 171.96 nm/RIU and 10.4 pm/°C by the PCF modal interferometer. The simultaneous measurement of the temperature and external RI is experimentally demonstrated by the sensor. The temperature shift and RI shift calculated by the sensor matrix agree well with the actual temperature and RI change in the experiment.     

Microstructure effect on microtopography of chemically etched α + β Ti alloys

Microstructure effect on chemical etching behavior of the annealed Ti-6Al-4V and Ti-3Al-2.5V titanium (Ti) alloys was compared with that of unalloyed commercially pure titanium. The microstructural evolution of structure phases after annealing the titanium and its alloys at temperature near and above β transus and followed by furnace cooling to room temperature was studied using optical microscope, scanning electron microscope and X-ray diffraction techniques. The microstructure study illustrates that the heat treatment enhanced partitioning effect allows extensive formation of hemispherical and near spherical pits roughened surface to be readily acquired by chemically etching the annealed α + β titanium alloys. The kinetics of the chemical etching reaction process show a linear dependence on time. The annealed α + β titanium alloys that exhibit relatively lower weight loss and thickness reduction rate illustrate less chemical activity than the annealed unalloyed titanium.     

High-density plasma etching of indium-zinc oxide films in Ar/Cl2 and Ar/CH4/H2 chemistries

The dry etching characteristics of transparent and conductive indium-zinc oxide (IZO) films have been investigated using an inductively coupled high-density plasma. While the Cl₂-based plasma mixture showed little enhancement over physical sputtering in a pure argon atmosphere, the CH₄/H₂/Ar chemistry produced an increase of the IZO etch rate. On the other hand, the surface morphology of IZO films after etching in Ar and Ar/Cl₂ discharges is smooth, whereas that after etching in CH₄/H₂/Ar presents particle-like features resulting from the preferential desorption of In- and O-containing products. Etching in CH₄/H₂/Ar also produces formation of a Zn-rich surface layer, whose thickness (∼40 nm) is well-above the expected range of incident ions in the material (∼1 nm). Such alteration of the IZO layer after etching in CH₄/H₂/Ar plasmas is expected to have a significant impact on the transparent electrode properties in optoelectronic device fabrication.