全文获取类型
收费全文 | 2066篇 |
免费 | 271篇 |
国内免费 | 244篇 |
专业分类
化学 | 1439篇 |
晶体学 | 20篇 |
力学 | 94篇 |
综合类 | 4篇 |
数学 | 332篇 |
物理学 | 692篇 |
出版年
2024年 | 7篇 |
2023年 | 48篇 |
2022年 | 76篇 |
2021年 | 85篇 |
2020年 | 101篇 |
2019年 | 74篇 |
2018年 | 64篇 |
2017年 | 68篇 |
2016年 | 96篇 |
2015年 | 92篇 |
2014年 | 98篇 |
2013年 | 142篇 |
2012年 | 164篇 |
2011年 | 172篇 |
2010年 | 93篇 |
2009年 | 114篇 |
2008年 | 126篇 |
2007年 | 121篇 |
2006年 | 92篇 |
2005年 | 94篇 |
2004年 | 55篇 |
2003年 | 42篇 |
2002年 | 41篇 |
2001年 | 44篇 |
2000年 | 46篇 |
1999年 | 39篇 |
1998年 | 27篇 |
1997年 | 30篇 |
1996年 | 42篇 |
1995年 | 35篇 |
1994年 | 34篇 |
1993年 | 29篇 |
1992年 | 24篇 |
1991年 | 33篇 |
1990年 | 25篇 |
1989年 | 14篇 |
1988年 | 15篇 |
1987年 | 13篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 11篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1968年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有2581条查询结果,搜索用时 15 毫秒
61.
A series of spiropyrans with a polyaromatic or heteroaromatic pendant was synthesized conveniently.Their photochromic behaviors were investigated with the aid of absorption spectral measurements.The results indicated that the compounds with the same parent spiropyran but different aromatic pendant show significantly different photochromic properties.This may be due to the π-π orbital interaction between the polyaromatic pendant and the open photomerocyanine form of spiropyran.The results obtained are very useful in the molecule design area. 相似文献
62.
Jong-Shi Pang 《Mathematical Programming》1979,16(1):111-126
The present paper studies the linear complementarity problem of finding vectorsx andy inR
+
n
such thatc + Dx + y 0,b – x 0 andx
T
(c + Dx + y) = y
T
(b – x) = 0 whereD is aZ-matrix andb > 0. Complementarity problems of this nature arise, for example, from the minimization of certain quadratic functions subject to upper and lower bounds on the variables. Two least-element characterizations of solutions to the above linear complementarity problem are established first. Next, a new and direct method to solve this class of problems, which depends on the idea of least-element solution is presented. Finally, applications and computational experience with its implementation are discussed.Research partially supported by the National Science Foundation Grant MCS 71-03341 A04 and the Air Force Office of Scientific Research Contract F 44620 14 C 0079. 相似文献
63.
Anran Shi Xiumei Song Lei Wei Huiyuan Ma Haijun Pang Weiwei Li Xiaowei Liu Lichao Tan 《Molecules (Basel, Switzerland)》2022,27(23)
High-energy density supercapacitors have attracted extensive attention due to their electrode structure design. A synergistic effect related to core–shell structure can improve the energy storage capacity and power density of electrode materials. The Ni-foam (NF) substrate coupled with polypyrrole (PPy) conductive coating can serve as an internal/external bicontinuous conductive network. In this work, the distinctive PPy@FeNi2S4@NF and PPy@NiCo2S4@NF materials were prepared by a simple two-step hydrothermal synthesis with a subsequent in situ polymerization method. PPy@FeNi2S4@NF and PPy@NiCo2S4@NF could deliver ultrahigh specific capacitances of 3870.3 and 5771.4 F·g−1 at 1 A·g−1 and marvelous cycling capability performances of 81.39% and 93.02% after 5000 cycles. The asymmetric supercapacitors composed of the prepared materials provided a high-energy density of over 47.2 Wh·kg−1 at 699.9 W·kg−1 power density and 67.11 Wh·kg−1 at 800 W·kg−1 power density. Therefore, the self-assembled core–shell structure can effectively improve the electrochemical performance and will have an effective service in advanced energy-storage devices. 相似文献
64.
By using difference schemes, orthogonal partitions and a replacement method, some new methods to construct pure quantum error-correcting codes are provided from orthogonal arrays. As an application of these methods, we construct several infinite series of quantum error-correcting codes including some optimal ones. Compared with the existing binary quantum codes, more new codes can be constructed, which have a lower number of terms (i.e., the number of computational basis states) for each of their basis states. 相似文献
65.
将幂函数引入Eringen非局部线粘弹性本构,导出Riesz势形式的应力-应变关系.利用该关系,构造非局部弹簧和非局部阻尼器两类元件;利用元件的串联和并联,建立非局部Kelvin和非局部Maxwell粘弹性模型,推导模型的松弛模量和蠕变柔量.进一步,给出非局部粘弹性模型在生物组织超声波耗散建模中的应用. 相似文献
66.
Metasurface-based vectorial holography manifests itself as an advanced platform for large-capacity information storage, holographic display, and cryptography. However, a convenient and effective reconfigurable vectorial hologram generation mechanism still remains a challenge. Here, a rotation-driven reconfigurable vectorial holography scheme is developed via a dual-layer hybrid metasurface device, in which radiation-type and birefringent metasurfaces are cascaded hybridly. Thus, reconfigurable and highly customizable intensity and polarization response of holograms in the 3D space is achieved. Rotatable radiation-type metasurface (RTM) serves as an incidence-wavefront modulator to excite the non-rotatable birefringent metasurface (BM). The gradient descent optimization inverse design method is introduced to achieve the high-efficiency reconstruction of the Jones vector and Jones matrix distribution on both RTM and BM. On this basis, numerical analysis and experimental verification of 3-D reconfigurable vectorial holography are demonstrated in the microwave region. This scheme implies a new paradigm for 3-D reconfigurable vectorial holography and can lead to advances in high-capacity optical display, switchable meta-devices, and cryptography. 相似文献
67.
68.
69.
中药黄柏主要活性成分的光谱成像检测技术 总被引:4,自引:0,他引:4
为了实现中药主要活性成分的在体检测,运用光谱成像技术检测中药活性成分.使用自行开发的液晶光谱成像装置对中药黄柏的主要活性成分盐酸小檗碱进行了在体检测,选取紫外光源波长254 nm,获取了检品480~700 nm之间的连续荧光光谱图像.在分析检品光谱剖面图的基础上,以中国药品生物制品检定所提供的盐酸小檗碱标准品的光谱剖面图为依据,设计了高通滤波器得到了检品的特征光谱数据.对八种不同来源的市售黄柏饮片特征光谱,以及黄柏与其同科植物黄皮特征光谱的比较显示,使用本方法对中药进行定性、定量的检测,样品无需特殊处理,可在原生态的情况下进行;检测过程无损、实时;检测结果指纹特征明显. 相似文献
70.
This paper is concerned with the dynamic behaviors of wave propagation in layered periodic composites consisting of piezoelectric and piezomagnetic phases. The dispersion relations of Lamb waves axe derived. Dispersion curves and displacement fields are calculated with different piezoelectric volume fractions. Numerical results for BaTiO3/CoFe2O4 composites show that the dispersion curves resemble the symmetric Lamb waves in a plate. Exchange between the longitudinal (i.e. thickness) mode and coupled mode takes place at the crossover point between dispersion curves of the first two branches. With the increase of BaTiO3 volume fraction, the crossover point appears at a lower wave number and wave velocity is higher. These findings are useful for magnetoelectric transducer applications. 相似文献