全文获取类型
收费全文 | 977篇 |
免费 | 153篇 |
国内免费 | 118篇 |
专业分类
化学 | 698篇 |
晶体学 | 11篇 |
力学 | 86篇 |
综合类 | 18篇 |
数学 | 108篇 |
物理学 | 327篇 |
出版年
2024年 | 5篇 |
2023年 | 23篇 |
2022年 | 29篇 |
2021年 | 36篇 |
2020年 | 34篇 |
2019年 | 45篇 |
2018年 | 39篇 |
2017年 | 32篇 |
2016年 | 45篇 |
2015年 | 43篇 |
2014年 | 65篇 |
2013年 | 86篇 |
2012年 | 64篇 |
2011年 | 75篇 |
2010年 | 41篇 |
2009年 | 49篇 |
2008年 | 52篇 |
2007年 | 73篇 |
2006年 | 69篇 |
2005年 | 55篇 |
2004年 | 38篇 |
2003年 | 33篇 |
2002年 | 35篇 |
2001年 | 27篇 |
2000年 | 26篇 |
1999年 | 15篇 |
1998年 | 19篇 |
1997年 | 17篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 12篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1980年 | 1篇 |
1971年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1248条查询结果,搜索用时 11 毫秒
31.
32.
Yu Xiangtao Yang Jun Sui Zhuyin Wang Mingyong 《Journal of Solid State Electrochemistry》2021,25(8):2201-2212
Journal of Solid State Electrochemistry - Self-supporting porous Ni film with uniform honeycomb-like micropores and a thickness of up to 66 μm is electrodeposited by dynamic hydrogen... 相似文献
33.
34.
Chaozhong Cai Fu-An Kang Derek A. Beauchamp Zhihua Sui Ronald K. Russell Christopher A. Teleha 《Tetrahedron: Asymmetry》2013,24(11):651-656
Two cycloaddition methods were applied to chiral protected aminocyclopentenes 2 and 9 and provided novel bicyclic products 3 and 4 in good yields. The explanation for the observed stereochemistry was based on the sterically encumbered β-face forcing the cycloadditions to occur on the α-face of the cyclopentene ring. The stereochemistry of 4 was confirmed by X-ray of the fumarate salt 10 and showed the trans-relationship between the newly formed ring and the chiral –NHBoc group. 相似文献
35.
本文研究了复合酶酶解前后假酸浆提取物的抗氧化活性能力,并采用薄层色谱法(TLC)对酶解产物中总黄酮进行了分离,利用高效液相色谱-质谱联用技术对其鉴定分析。通过对DPPH自由基、羟自由基及超氧阴离子自由基清除能力实验,酶解液抗氧化性能显著高于假酸浆提取液;酶解液的薄层及HPLC-MS法初步鉴定出假酸浆中含有桑色素、二氢槲皮素和儿茶素三种黄酮。 相似文献
36.
Jing Zhao Jihai Zhang Mengfan Jing Guopeng Sui Dingyao Liu Ke Wang Qiang Fu 《Journal of Polymer Science.Polymer Physics》2019,57(7):368-377
Herein, we reported the formation mechanism of hybrid crystalline (cylindrite) in isotactic polypropylene (iPP)/carbon fiber (CF) via pulling a CF within the iPP melt. The α‐row nuclei layer closely attached to the surface of CF acts as a self‐nucleation site, rather than a heterogeneous nucleation one, to grow cylindrites. As a result, the polymorphic feature of iPP/CF cylindrite is significantly influenced by the microstructure of α‐row nuclei. With decreasing crystallization temperature (Tc), the polymorphic cylindrite changes from pure α‐form to mixed α‐/β‐form and to β‐rich form. The main characteristics of this change include: (a) the outlines of α‐row nuclei layer correspond to wave‐like, saw‐like, and straight lines; (b) the orientation level of iPP molecules in the α‐row nuclei layer become higher; (c) the α‐lamellae rearrange from loose to compact; and (d) the distance between the growth sites of β‐sectors and the surface of CF is evidently longer than in the case of α‐sectors. Moreover, this study provides a guideline for developing the interfacial enhanced iPP/CF composites through manipulation of polymorphic structure in cylindrites. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 368–377 相似文献
37.
Chunxiao Lv Qing Li Yaowen Zhang Zhenyu Sui Bosai He Huarong Xu Yidi Yin Xiaohui Chen Kaishun Bi 《Journal of mass spectrometry : JMS》2013,48(8):904-913
A fast, sensitive and reliable ultra fast liquid chromatography‐tandem mass spectrometry (UFLC‐MS/MS) method has been developed and validated for simultaneous quantitation of polygalaxanthone III (POL), ginsenoside Rb1 (GRb1), ginsenoside Rd (GRd), ginsenoside Re (GRe), ginsenoside Rg1 (GRg1) and tumulosic acid (TUM) in rat plasma after oral administration of Kai‐Xin‐San, which plays an important role for the treatment of Alzheimer's disease (AD). The plasma samples were extracted by liquid–liquid extraction using ethyl acetate–isopropanol (1:1, v/v) with salidrdoside as internal standard (IS). Good chromatographic separation was achieved using gradient elution with the mobile phase consisting of methanol and 0.01% acetic acid in water. The tandem mass spectrometric detection was performed in multiple reaction monitoring mode on 4000Q UFLC‐MS/MS system with turbo ion spray source in a negative and positive switching ionization mode. The lower limits of quantification were 0.2–1.5 ng/ml for all the analytes. Both intra‐day and inter‐day precision and accuracy of analytes were well within acceptance criteria (±15%). The mean absolute extraction recoveries of analytes and IS from rat plasma were all more than 60.0%. The validated method has been successfully applied to comparing pharmacokinetic profiles of analytes in normal and AD rat plasma. The results indicated that no significant differences in pharmacokinetic parameters of GRe, GRg1 and TUM were observed between the two groups, while the absorption of POL and GRd in AD group were significantly higher than those in normal group; moreover, the GRb1 absorbed more rapidly in model group. The different characters of pharmacokinetics might be caused by pharmacological effects of the analytes. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
38.
Hong Zheng Ning Lian Sui Wang Yuemei Cui Yunhui Zhai 《International journal of environmental analytical chemistry》2013,93(6):431-441
In this article, a new method that utilizes a diethyldithiocarbamate-modified nanometre TiO2 (TiO2–DDTC) as solid-phase extractant has been developed for simultaneous preconcentration of trace Cu(II), Pb(II), Zn(II), and Cd(II) prior to measurement by inductively coupled plasma atomic emission spectrometry (ICP-AES). The separation/preconcentration conditions of analytes, which include the effects of pH, sample flow rate and volume, elution conditions, and interfering ions on the recovery of the analytes, were investigated. At pH 5, the adsorption capacity of modified nanometre TiO2–DDTC was found to be 6.2, 19, 4.7, and 6.0?mg/g for Cu(II), Pb(II), Zn(II), and Cd(II), respectively. According to the definition of IUPAC, the detection limits (3σ) of this method for Cu(II), Pb(II), Zn(II), and Cd(II) were 0.41, 1.7, 0.39, and 0.52?ng/mL, respectively. The proposed method achieved satisfied results when applied to the determinations of trace Cu(II), Pb(II), Zn(II), and Cd(II) in biological and natural water samples. 相似文献
39.
Wei Zhang Ping Sui Prof. Wei Zheng Prof. Lingyun Li Prof. Shuaihua Wang Prof. Ping Huang Wen Zhang Qi Zhang Prof. Yan Yu Prof. Xueyuan Chen 《Angewandte Chemie (International ed. in English)》2023,62(45):e202309230
Eco-friendly lead-free organic–inorganic manganese halides (OIMHs) have attracted considerable attention in various optoelectronic applications because of their superior optical properties and flexible solution processibility. Herein, we report a novel pseudo-2D layered OIMH (MTP)2MnBr4 (MTP: methyltriphenylphosphonium), which exhibits intense green emission under UV/blue or X-ray excitation, with a near-unity photoluminescence quantum yield, high resistance to thermal quenching (I150 °C=84.1 %) and good photochemical stability. These features enable (MTP)2MnBr4 as an efficient green phosphor for blue-converted white light-emitting diodes, demonstrating a commercial-level luminous efficiency of 101 lm W−1 and a wide color gamut of 116 % NTSC. Moreover, these (MTP)2MnBr4 crystals showcase outstanding X-ray scintillation properties, delivering a light yield of 67000 photon MeV−1, a detection limit of 82.4 nGy s−1, and a competitive spatial resolution of 6.2 lp mm−1 for X-ray imaging. This work presents a new avenue for the exploration of eco-friendly luminescent OIMHs towards multifunctional light-emitting applications. 相似文献
40.
同位素稀释-火花源质谱法分析人参样品中微量元素 总被引:2,自引:0,他引:2
本文采用同位素稀释-火花源质谱法定量分析了吉林野山参,园参及高丽参中30多种微量元素的含量。测定下限2μg/g,相对标准偏差在5~28%以内。 相似文献