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131.
The object of the present paper is to study weakly cyclic Z symmetric spacetimes. At first we prove that a weakly cyclic Z symmetric spacetime is a quasi Einstein spacetime. Then we study \({{(WCZS)}_{4}}\) spacetimes satisfying the condition div \({C=0}\). Next we consider conformally flat \({{(WCZS)}_{4}}\) spacetimes. Finally, we characterise dust fluid and viscous fluid \({{(WCZS)}_{4}}\) spacetimes. 相似文献
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134.
A 3D porous metal-organic framework [Zn3(ntb)2(EtOH)2]n.4nEtOH (1) that generates 1D channels of honeycomb aperture has been prepared by the solvothermal reaction of Zn(NO3)(2).6 H2O and 4,4',4'-nitrilotrisbenzoic acid (H3NTB) in EtOH at 110 degrees C. Framework 1 exhibits reversible single-crystal-to-single-crystal transformations upon removal and rebinding of the coordinating EtOH as well as the EtOH guest molecules, which give rise to desolvated crystal [Zn3(ntb)2]n (1') and resolvated crystal [Zn3(ntb)2-(EtOH)2]n.4nEtOH (1'). The X-ray structures indicate that 3D host framework is retained during the transformations from 1 to 1' and from 1' to 1', but the coordination geometry of ZnII ions changes from/to trigonal bipyramid to/from tetrahedron, concomitant with the rotational rearrangement of a carboxylate plane of the NTB3- relative to its associated phenyl ring. To retain the single crystal integrity, extensive cooperative motions must exist between the molecular components throughout the crystal. Framework 1' exhibits permanent porosity, thermal stability up to 400 degrees C, and blue luminescence, and high storage capabilities for N2, H2, CO2, and CH4. 相似文献
135.
Seo SY Jung JW Jung JK Kim NJ Chin YW Kim J Suh YG 《The Journal of organic chemistry》2007,72(2):666-668
Rodgersinol was synthesized via seven linear steps in 31% overall yield, and the absolute configuration of the C-10 stereogenic center was elucidated. The key feature of the synthesis involves the efficient Cu(II)-mediated coupling of two aromatic moieties for the diaryl ether intermediate and the enantioselective construction of the hydroxypropyl substituent by a regio- and stereoselective methyl addition to the chiral aryloxiranes in an inversion manner. 相似文献
136.
Novel fully π‐conjugated poly(arylene ethynylene)s 1 and 2 having diphenylmaleimides in the backbone were prepared utilizing a Pd(0)‐Cu(I) catalyzed coupling reaction (Sonogashira method) of N‐alkyl substituted 1,2‐di(4‐bromophenyl) maleimides ( 5 and 6 ) with 1,4‐diethynylbenzene. Whereas polymer 1 with an N‐hexyl side chain showed low solubility, 2 having an N‐ dodecyl group was completely soluble in common organic solvents. Determined by GPC, M̄w of 2 was 45 800 Da with a polydispersity index of 2.5. Polymer 2 showed UV‐visible absorption maxima at 330 nm and 413 nm and greenish yellow fluorescence with a maximum of 530 nm. 相似文献
137.
Jung‐Bae Jun Jin‐Woong Kim Joon‐Woo Lee Kyung‐Do Suh 《Macromolecular rapid communications》2001,22(12):937-940
A new method to synthesize uniform polyaniline‐coated composite microparticles was contrived considering the surface reactivity and porous structure of substrate polymer particles. It was found that the pore diameter together with the epoxy functional group plays a crucial role in controlling the structure of polyaniline shell. The polyaniline composite particles produced in this study are believed to find great applicability in piezoelectronics and as electro‐rheological fluids. 相似文献
138.
Sang‐Wook Park Seung‐Hyeun Park Wonho Kim Dong‐Soo Suh In‐Joe Sohn 《Journal of polymer science. Part A, Polymer chemistry》2000,38(19):3543-3549
The phase‐transfer catalyzed graft copolymerization of methyl methacrylate onto polychloroprene was carried out using tricaprylylmethylammonium chloride as a phase‐transfer catalyst in a two‐phase system of an aqueous Na2S2O8 solution and toluene at 55 °C under a nitrogen atmosphere. The initial rate of graft copolymerization was expressed as the combined terms of quaternary onium cation and peroxydisulfate anion in the aqueous phase rather than the fed concentrations of catalyst and Na2S2O8. The observed initial rate of graft copolymerization was used to analyze the graft copolymerization mechanism with a cycle phase‐transfer initiation step in the heterogeneous liquid–liquid system. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3543–3549, 2000 相似文献
139.
Junghun Suh Chul-Seong Jeung 《Journal of polymer science. Part A, Polymer chemistry》1997,35(3):527-532
Polymeric oxaaza macrocycles (PEI-OAM) are constructed on poly(ethylenimine) (PEI) by Ni(II)-template alkylation of PEI with diethyleneglycol ditosylate. The Kf values for Ni(II), Cu(II), and Zn(II) complexes of PEI–OAM are measured at pH 3.5–10 at 25°C. At pH 7, log Kf values for these complexes are 9–15, indicating that the polymeric oxaaza macrocycles can readily reduce concentrations of these metal ions below ppb level. Metal binding ability of nonpolymeric oxaaza macrocyclic compounds reported in the literature decreases rapidly as pH is lowered below 7, whereas that of PEI–OAM decreases to lesser extents. This is attributed to the electrostatic effects exerted by the ammonium ions of PEI backbone. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 527–532, 1997. 相似文献
140.
Junghun Suh Hyung Soon Park 《Journal of polymer science. Part A, Polymer chemistry》1997,35(7):1197-1210
Three molecules of 5-(bromoacetyl) salicylate ( 1 ) complexed to Fe(III) ion were crosslinked with poly(ethylenimine) (PEI) in DMSO by alkylation of amino groups of PEI with 1 , leading to the formation of Fe(Sal)3PEI, a water-soluble polymer. Several other derivatives including the immobilized form were also prepared. Examination of the values of log Kf for the PEI derivatives indicated that each Fe(III) binding site in Fe(Sal)3PEI contains three salicylate moieties. In addition, the log Kf revealed that the effective molarity (EM) of the salicylate groups contained in the Fe(III) binding site is ca. 1000M. The high EM value shows that the geometry of the coordination sphere is well conserved during the crosslinkage with PEI of 1 preassembled around Fe(III) ion. In view of the EM value and the pKa values of salicylic phenols in apo(Sal)3-PEI, the metal-free form, the three salicylate groups of each Fe(III) binding site appear to occupy proximal positions leading to effective cooperation in Fe(III) binding. Fast, strong, and selective binding of Fe(III) ion by the binding site comprising three salicylate moieties was demonstrated. In addition, rapid demetalation of the resulting complexes as well as chemical stability of the immobilized chelating agents built on PEI were achieved. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 1197–1210, 1997 相似文献