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71.
Positivity - Since 2001, rough convergence has been discussed in research where the core factor degree of roughness has been treated only as a real number. Instead of analyzing different results... 相似文献
72.
We report theoretical results for reaction and vibrational quenching of the ultracold collision D + H(2) (v, j = 0) for a wide range of initial vibrationally excited states v. The v-dependence of the zero-temperature limit of the reaction rate coefficient shows two distinct regimes: a barrier dominated regime for 0 ≤ v ≤ 4, and a barrierless regime for v ≥ 5. We also present detailed distributions over the rovibrational states of the products. We find an approximate conservation of the internal vibrational energy; namely, the branching ratios always favor the highly excited final states, which have vibrational energies similar to that of the entrance channel. 相似文献
73.
Sweetman A Jarvis S Danza R Bamidele J Gangopadhyay S Shaw GA Kantorovich L Moriarty P 《Physical review letters》2011,106(13):136101
We reversibly switch the state of a bistable atom by direct mechanical manipulation of bond angle using a dynamic force microscope. Individual buckled dimers at the Si(100) surface are flipped via the formation of a single covalent bond, actuating the smallest conceivable in-plane toggle switch (two atoms) via chemical force alone. The response of a given dimer to a flip event depends critically on both the local and nonlocal environment of the target atom-an important consideration for future atomic scale fabrication strategies. 相似文献
74.
75.
Reaction dynamics of prototypical, D + H2 and Cl (2P) + H2, chemical reactions occurring through the conical intersections of the respective coupled multi-sheeted potential energy
surfaces is examined here. In addition to the electronic coupling, nonadiabatic effects due to relativistic spin-orbit coupling
are also considered for the latter reaction. A time-dependent wave packet propagation approach is undertaken and the quantum
dynamical observables viz., energy resolved reaction probabilities, integral reaction cross-sections and thermal rate constants
are reported. 相似文献
76.
The tricyclic ketones 13 and 14, prepared from naphthalene and 2-methoxynaphthalene respectively, were subjected to reductive methylation in anhydrous ammonia to provide the β, γ -unsaturated ketones 16 and 17 in high yield which were stereoselectively converted into the A/B trans-fused compounds 3 and 4 respectively. 相似文献
77.
Strong laws of large numbers (SLLN) for weighted averages are proved under various dependence assumptions when the variables are not necessarily independent or identically distributed. The results considerably extend the existing results. Weighted versions of the Marcinkiewicz-Zygmund SLLN are also formulated and proved under a similar set up. It seems that such results are not known even for independent and identically distributed random variables. 相似文献
78.
Sarbajit Ghosal Jon L. Ebert Sidney A. Self 《Particle & Particle Systems Characterization》1993,10(1):11-18
Accurate information on the size distribution of fly ash is needed to determine its role in the radiation transfer process in pulverized coal combustors. The Coulter Multisizer was used to determine the size distribution in the particle diameter range 1–200 μm. To size over such large diameter ranges, data must be obtained using several orifices, and then combined. In order to use the smaller orifices, the larger particles have to be removed from the sample. A wet-sieving apparatus, designed for accurate separation of the particles by size, is described. A scheme for combining data obtained using orifices of different diameters is presented. It appears from this study that the lower limit of size measurement using an orifice is set by sensitivity, rather than by signal/noise. A lognormal distribution function, truncated outside the measurement limits, fits the size distribution data well. This function allows detailed size information to be stored compactly using four parameters. Size parameters for six fly ashes representative of U. S. coals are presented. 相似文献
79.
Subhashis Chatterjee Shobhit Nigam Jeetendra Bahadur Singh Lakshmi Narayan Upadhyaya 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2013,19(5):539-551
This article presents a software reliability growth model based on non-homogeneous Poisson process. The main focus of this article is to deliver a method for software reliability modelling incorporating the concept of time-dependent fault introduction and fault removal rate with change point. Also in this article, a cost model with change point has been developed. Based on the cost model optimal release policy with change point has been discussed. Maximum likelihood technique has been applied to estimate the parameters of the model. The proposed model has been validated using some real software failure data. Comparison has been made with models incorporating change point and without change point. The application of the proposed cost model has been shown using some numerical examples. 相似文献
80.
A simple yet generalized theory is developed to study inter band tunneling property of narrow band gap III–V compound semiconductors. The band structures of these low band gap semiconductors with sufficiently separated split-off valance band are usually described by the three energy band model of Kane, so this has been adopted here for the analysis of interband tunneling property in the case of InAs, InSb, and In1-xGaxAsyP1-y lattice matched to InP as representative direct band gap semiconductors having varied split-off valence band compared to their bulk state band gap energy. It has been found that the magnitude of tunneling rate from heavy hole decreases with increasing band nonparabolicity and the impact is more significant at high electric field in the three-band model of Kane than those with simple parabolic energy band approximations reflecting the direct influence of energy band parameters on inter band tunneling transitions. With proper consideration of band nonparabolicity, the results of the analysis of tunneling rate of these narrow gap materials show significant deviations from the results when simple parabolic band approximation is considered. The exact physical basis of the sources of deviation in the nonparabolic case from the corresponding parabolic band approximations is discussed in association to band coupling effect, transverse energy dependence, and the interplay between them. Moreover, under certain limiting conditions, our results reduce to the well-known results of parabolic band approximation and thus providing an indirect test to the accuracy of our generalized formulations. 相似文献