Use of Adogen-464 in some parent — daughter separations by reverse phase extraction chromatography

Seperation of few carrier-free daughter isotopes from their respective parents, e.g.,¹³²I from¹³²Te,¹⁴⁰La from¹⁴⁰Ba and²³⁴Th from²³⁸U, using Adogen-464, a high molecular weight quaternary ammoaium salt by reversed phase extraction chromatographic technique is reported.     

Solvent extraction of silver(I) with amberlite-LA-2 using110mAg as tracer

The use of Amberlite-LA-2, a high molecular weight secondary amine, for the radiochemical solvent extraction of Ag(I) present as anionic thiosulfato complex at pH 3 is described. The effects of different parameters on the extraction and preconcentration have been studied in detail. The method was successfully applied in the determination of silver in several synthetic mixutres and also in a few medicinal samples.     

Stability-indicating RP-HPLC method for simultaneous quantitation of tramadol and aceclofenac in presence of their major degradation products: Method development and validation

Primary objective of this study was to develop a stability-indicating reverse-phase high-performance liquid chromatography (HPLC) method for simultaneous quantitation of tramadol and aceclofenac in presence of their degradation products. The drugs were subjected to various International Conference on Harmonization recommended stress conditions, such as acid hydrolysis, alkaline hydrolysis, peroxide oxidation, thermolysis, and photolysis. The major degradation products got well resoluted from the analytes in HPLC analysis with a mobile phase composed of a mixture of 0.01?M ammonium acetate buffer (pH 6.5) and acetonitrile (65:35, v/v) through a Phenomenex Gemini C18 (250?mm?×?4.6?mm, 5?µm particle size) column. The method was linear over a range of 15–60?µg/mL for tramadol and 40–160?µg/mL for aceclofenac concentration. The analytes were detected at a wavelength of 270?nm. The method was validated and found to be specific, accurate, precise, stable, and robust for its intended use. The method can be recommended for its future use in routine quality control, accelerated and real-time stability analysis of the formulations containing tramadol and aceclofenac combination.     

Asymptotic Expansions of Posterior Distributions in Nonregular Cases

We study the asymptotic behaviour of the posterior distributions for a one-parameter family of discontinuous densities. It is shown that a suitably centered and normalized posterior converges almost surely to an exponential limit in the total variation norm. Further, asymptotic expansions for the density, distribution function, moments and quantiles of the posterior are also obtained. It is to be noted that, in view of the results of Ghosh et al. (1994, Statistical Decision Theory and Related Topics V, 183-199, Springer, New York) and Ghosal et al. (1995, Ann. Statist., 23, 2145-2152), the nonregular cases considered here are essentially the only ones for which the posterior distributions converge. The results obtained here are also supported by a simulation experiment.     

Stability for Properly Quasiconvex Vector Optimization Problem

The aim of this paper is to study the stability aspects of various types of solution set of a vector optimization problem both in the given space and in its image space by perturbing the objective function and the feasible set. The Kuratowski?CPainlevé set-convergence of the sets of minimal, weak minimal and Henig proper minimal points of the perturbed problems to the corresponding minimal set of the original problem is established assuming the objective functions to be (strictly) properly quasi cone-convex.     

Self-dual connections,hyperbolic metrics and harmonic mappings on Riemann surfaces

The Sampson-Wolf model of Teichmüller space (using harmonic mappings) is shown to be exactly the same as the more recent Hitchin model (utilizing self-dual connections). Indeed, it is noted how the self-duality equations become the harmonicity equations. An interpretation of the modular group action in this model is mentioned.     

Complete Convergence of Martingale Arrays

We study complete convergence of martingale arrays under rather weak conditions. Our results considerably strengthen many of the results available in the literature. As a tool, we establish a martingale analogue of an inequality of Hoffman-Jørgensen which was earlier known only for independent random variables.     

Multiple Scales via Galerkin Projections: Approximate Asymptotics for Strongly Nonlinear Oscillations

The method of multiple scales and the related method of averaging are commonly used tostudy slowly modulated oscillations. If the system of interest is a slightlyperturbed harmonic oscillator, then these techniques can be applied easily. If the unperturbed system is strongly nonlinear (though possiblyconservative), then these methods can run into difficulties due to the impossibilityof carrying out required analytical operations in closed form.In this paper, we abandon the requirement of closed form analyticaltreatment at all stages. Instead, Galerkin projections are used toobtain approximate realizations of the method of multiple scales. Thispaper adapts recent work using similar ideas for approximaterealizations of the method of averaging. A key contribution of thepresent work is in the systematic identification and removal of secularterms in the general nonlinear case, a procedure that is more difficultthan for the perturbed harmonic oscillator case, and that is unnecessaryfor averaging.A strength of the present work is that the heuristics (Galerkin)and asymptotics (multiple scales) are kept distinct,leaving room for systematic refinement of the formerwithout compromising the asymptotic features of the latter.     

Near-barrier fission of the system12C+232Th

The fission fragment angular distributions for the system¹²C +²³²Th have been measured in the energy range 0.97<>_c.m./V_B<1.22. the=" measured=" anisotropies=" have=" been=" compared=" with=" the=" predictions=" of=" the=" standard=" saddle=" point=" statistical=" model,=" using=" the=" second=" moment=" of=" the=" compound=" nucleus=" spin=" distribution=">l² deduced from a Wong model fit to the fission excitation function. While the measured anisotropies agree with the standard saddle point statistical model for E_c.m./V_B>1.05, they are abnormally large at lower energies. This is also true for the existing measurements of¹⁶O and¹⁹F +²³²Th systems. Since for this system pre-equilibrium fission contributions are not expected, this anomaly indicates strong channel coupling effects leading to an increase in l² at sub-barrier energies.The authors thank Drs. R.K. Choudhury and A. Saxena for useful discussions, Dr. R.J. Singh for making the thorium target and the Pellectron operation staff for excellent operation of the machine.