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31.
    
The temperature, illumination, frequency, and photon energy dependences of the photoconductivity in a-GeSe films are investigated. The conduction activation energy is 0.95 eV, the photoconductivity edge lies at 1.4 eV. The photoconductivity is field-independent up to 3 × 104 V/cm and independent of the frequency of the chopping light up to at least 103 Hz. The activation energy of the photoconductivity decreases with decreasing temperature from 0.3 eV to almost zero. The experimental curves are consistent with activated mobilities for electrons and holes and recombination by both a direct and an indirect mechanism. A value of 4 × 1013 cm−3 for the density of localized states at the Fermi level is obtained.  相似文献   
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This work is a mini-review highlighting the relevance of the θ metallabis(dicarbollide) [3,3′-Co(1,2-C2B9H11)2] with its peculiar and differentiating characteristics, among them the capacity to generate hydrogen and dihydrogen bonds, to generate micelles and vesicles, to be able to be dissolved in water or benzene, to have a wide range of redox reversible couples and many more, and to use these properties, in this case, for producing potentiometric membrane sensors to monitor amine-containing drugs or other nitrogen-containing molecules. Sensors have been produced with this monoanionic cluster [3,3′-Co(1,2-C2B9H11)2]. Other monoanionic boron clusters are also discussed, but they are much fewer. It is noteworthy that most of the electrochemical sensor species incorporate an ammonium cation and that this cation is the species to be detected. Alternatively, the detection of the borate anion itself has also been studied, but with significantly fewer examples. The functions of the borate anion in the membrane are different, even as a doping agent for polypyrrole which was the conductive ground on which the PVC membrane was deposited. Apart from these cases related to closo borates, the bulk of the work has been devoted to sensors in which the θ metallabis (dicarbollide) [3,3′-Co(1,2-C2B9H11)2] is the key element. The metallabis (dicarbollide) anion, [3,3′-Co(1,2-C2B9H11)2], has many applications; one of these is as new material used to prepare an ion-pair complex with bioactive protonable nitrogen containing compounds, [YH]x[3,3′-Co(1,2-C2B9H11)2]y as an active part of PVC membrane potentiometric sensors. The developed electrodes have Nernstian responses for target analytes, i.e., antibiotics, amino acids, neurotransmitters, analgesics, for some decades of concentrations, with a short response time, around 5 s, a good stability of membrane over 45 days, and an optimal selectivity, even for optical isomers, to be used also for real sample analysis and environmental, clinical, pharmaceutical and food analysis.  相似文献   
34.
In this paper, several covariance-based approaches are proposed for aeroacoustic noise source analysis under the assumptions of a single dominant source and all observers contaminated solely by uncorrelated noise. The Crame?r-Rao Bounds (CRB) of the unbiased source power estimates are also derived. The proposed methods are evaluated using both simulated data as well as data acquired from an airfoil trailing edge noise experiment in an open-jet aeroacoustic facility. The numerical examples show that the covariance-based algorithms significantly outperform an existing least-squares approach and provide accurate power estimates even under low signal-to-noise ratio (SNR) conditions. Furthermore, the mean-squared-errors (MSEs) of the so-obtained estimates are close to the corresponding CRB especially for a large number of data samples. The experimental results show that the power estimates of the proposed approaches are consistent with one another as long as the core analysis assumptions are obeyed.  相似文献   
35.
Carbon nanotubes covalently modified with anthraquinone were used as an electrode for the immobilization of Trametes hirsuta laccase. The adsorbed laccase is capable of oxygen reduction at a mass transport controlled rate (up to 3.5 mA cm(-2)) in the absence of a soluble mediator. The storage and operational stability of the electrode are excellent.  相似文献   
36.
We extend the Bovier–Picco–Zhang laws of the iterated logarithm for geometrically weighted random series, and give the rate of convergence towards the limit set. To cite this article: G. Stoica, C. R. Acad. Sci. Paris, Ser. I 336 (2003).  相似文献   
37.
The charge transfer at the interface H2-0.5% Pt/Al2O3 was studied by using the transient response of the AC electrical conductance. The transient response for water and oxygen contaminated surface was of the overshoot-type.  相似文献   
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Phenyl--naphthylamine (PBN) used as rubber antioxidant was found to have native fluorescence. A spectrofluorimetric method for determination of PBN in multicomponent mixtures of polymer additives is described. The apparent excitation and fluorescence wavelengths used are 348 and 413.5 nm, respectively. Maximum fluorescence intensity is obtained by irradiating PBN dissolved in ethanol, at room temperature. The fluorescence varies linearly with the concentration of PBN in the range of 0.04–4 g mL–1. The accuracy and precision of the method are reported.  相似文献   
40.
We characterize the zero–Hopf bifurcation at the singular points of a parameter codimension four hyperchaotic Lorenz system. Using averaging theory, we find sufficient conditions so that at the bifurcation points two periodic solutions emerge and describe the stability of these orbits.  相似文献   
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