Actuation of a discontinuous structure with piezoelectric actuators

An alternate approach to exciting a one-dimensional structure with discontinuities using a piezoelectric actuator is presented and examined. Instead of being bonded to the uniform side of a beam, the piezoelectric actuator is attached such that it spans two adjacent rib discontinuities. In this configuration, the actuator generates an eccentric actuation force on the structure and induces both axial and transverse motions. The goal of this work is to first model the axial and transverse response caused by the piezoelectric actuator. Then, the change in that response is examined for the case where an external disturbance force is present. The system is modeled by coupling the piezoelectric strain and structural dynamic response. The characteristics of the voltage-generated piezoelectric forces are discussed through numerical examples. The structural response found using the dynamic force–voltage model for the actuator is then compared to the response when the actuator model is approximated by its static or zero-frequency value. Furthermore, the ability of the actuator to potentially provide better control authority by using this alternate configuration is examined. The numerical study shows that when the actuator spans two discontinuities, there is potential for greater control authority than when that same actuator is placed on the uniform side of the structure.     

Reducing spatial data using an optimized regressive discrete Fourier series

With the development of optical measurement techniques it is possible to obtain vast amounts of data. In vibrometry applications in particular operational deflection shapes are often obtained with very high spatial resolution. Fortunately, many techniques exist to reduce (approximate) the measurement data. One of the most common techniques for evaluating optical measurement data is by means of a Fourier analysis. However, this technique suffers from what is known as leakage when a non-integer number of periods is considered. This gives rise to non-negligible errors, which will obviously hamper the accuracy of the synthesized shape. Another technique such as a discrete cosine transform, used in the widely spread -jpeg standard does not suffer these anomalies but can still prove erroneous at times. One of the more recent approaches is via a so-called regressive discrete Fourier series (introduced by Arruda) which suffers one disadvantage. The problem statement is nonlinear in the parameters and needs a priori information about the deflection shape. This can be resolved by using the optimized regressive discrete fourier series (ORDFS), introduced in this article, which uses a nonlinear least squares approach. In this article the method will be applied in particular to the reduction of data for laser vibrometer measurements performed on an inorganic phosphate cement (IPC) beam (1D), as well as on a car door (2D). The proposed technique will also be validated on simulations to illustrate the properties concerning compression ratio and synthesized mode shape error. The introduced method will be bench marked for compression ratio and synthesized deflection shape error with all prior mentioned techniques.     

Plasma etching of As2S3 films for optical waveguides

Chalcogenide glasses are good candidate materials for ultra-fast non-linear optic devices. In this work, we present the photolithographic process and the plasma etching of arsenic tri-sulphide (As₂S₃) film. The films were deposited on thermally oxidized silicon substrates by ultra-fast pulsed laser deposition. To protect As₂S₃ film from photo-resist developer, thin resist layer ∼100-200 nm was remained on the UV exposed area by controlling resist development time. After removing the protective layer in oxygen plasma, As₂S₃ waveguides were patterned in inductively coupled plasma reactive ion etching (ICP-RIE) system using CF₄-O₂ gas mixture. We investigated the etch rate and the etch selectivity to photo-resist of As₂S₃ as a function of bias power, induction power, operating pressure, and gas flow rate ratio of CF₄ and O₂. The film is mainly etched by the chemical reaction with fluorine radicals. The content of oxygen in the plasma determines the etched sidewall profiles and nearly vertical profile was obtained at high oxygen content plasma.     

Synthesis,crystal structure and conformational analysis of an unexpected [1,5]dithiocine product of aminopyridine and thiovanillin

The condensation reaction of 2‐mercapto‐3‐methoxybenzaldehyde with 3‐aminopyridine afforded an unexpected N‐alkylated [1,5]dithiocine instead of the N‐salicylideneaniline. The proposed mechanism for this condensation involves a strong intramolecular hydrogen bond between the thiol and the amine groups, leading to a second condensation. The corresponding product, i.e. 4,10‐dimethoxy‐13‐(pyridin‐3‐yl)‐6H,12H‐6,12‐epiminodibenzo[b,f][1,5]dithiocine methanol 0.463‐solvate, C₂₁H₁₈N₂O₂S₂·0.463CH₃OH, was characterized by single‐crystal X‐ray diffraction analysis. The supramolecular structure shows π–π stacking and S…S interactions in the crystal packing. Within the asymmetric unit, two geometries of the N atom are observed. Although a planar geometry should be expected, a pyramidal one is observed due to the crystal packing. The presence of the two geometries was further supported by density functional theory (DFT) calculations that show an electronic energy difference of less than 2 kJ mol^?1 between the two conformers.     

Architectural control of polystyrene physical properties using branched anionic polymerization initiated at ambient temperature

Ambient temperature-initiated anionic polymerization has generated branched polystyrenes of varying molecular weights and architectures by inclusion of a distyryl branching comonomer into a conventional sec-Butylithium-initiated polymerization of styrene. Primary chain length control within the branched polymers, and restriction of the branching points to varying segments of the primary chains, led to variations of glass transition temperature with no direct correlation to the branched polymer molecular weight but a strong relationship to the length of individual chains comprising the branched macromolecules.     

Asymmetric Three‐Component Heck Arylation/Amination of Nonconjugated Cyclodienes

Substituted cyclohexylamines are becoming increasingly important in drug discovery. Asymmetric Heck insertion/amination of nonconjugated cyclodienes proceeds to give 5‐aryl cyclohexenylamines with good enantioselectivity and exclusive trans configurations. Primary and secondary anilines, indoline, and benzylamines are suitable amines. The weakly donating diphosphite Kelliphite forms a deep unsymmetrical pocket, which is essential for stereoselective anti attack of amines.     

Fluorescence and Rotational Dynamics of Dityrosine

We have examined the lifetimes and rotational correlation times of dityrosine emission by time-correlated single-photon counting. We first noticed dityrosine fluorescence in samples of tyrosine and tyrosine dipeptides by its characteristic red-shifted emission at 400 to 430 nm. The longer rotational correlation time relative to tyrosine proved that this fluorescence emanated from a distinct species. Comparison with the fluorescence properties of synthesized dityrosine established the identity of the emitting species. Fluorescence intensity decays of dityrosine are generally characterized by two decay components, one with a lifetime in the range of 150 to 800 ps and another between 2.5 and 4.5 ns. We found no evidence for an excited-state reaction, since a rising phase (negative-amplitude component) was not observed. In the pH range from 4 to 10, two ground-state species exist in equilibrium with pK _a 7. Both species exhibit two fluorescence decays. The average fluorescence lifetime increases gradually with pH over the pH range from 4 to 10 and decreases at pH 2. Anisotropy decays were measured for dityrosine and the alanine–dityrosine–alanine and leucine–dityrosine–leucine dipeptides. The rotational correlation times of dityrosine and dityrosine dipeptides increase linearly with van der Waals volumes. The slope indicates a stronger solute–solvent interaction than predicted with stick boundary conditions. It is suggested that these interactions result from the presence of two zwitterionic pairs.