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141.
Leulescu Marian Pălărie Ion Moanţă Anca Cioateră Nicoleta Popescu Mariana Morîntale Emilian Văruţ Marius Ciprian Rotaru Petre 《Journal of Thermal Analysis and Calorimetry》2019,136(3):1249-1268
Journal of Thermal Analysis and Calorimetry - Thermal behavior of Brown HT food dye was studied in correlation with the physical and biological antioxidant properties. Brown HT’s structure... 相似文献
142.
Carla Alice Carabet Anca Moan Ion Plrie Gabriela Iacobescu Andrei Rotaru Marian Leulescu Mariana Popescu Petre Rotaru 《Molecules (Basel, Switzerland)》2020,25(23)
Two yellow bis-azo dyes containing anthracene and two azodiphenylether groups (BPA and BTA) were prepared, and an extensive investigation of their physical, thermal and biological properties was carried out. The chemical structure was confirmed by the FTIR spectra, while from the UV–Vis spectra, the quantum efficiency of the laser fluorescence at the 476.5 nm was determined to be 0.33 (BPA) and 0.50 (BTA). The possible transitions between the energy levels of the electrons of the chemical elements were established, identifying the energies and the electronic configurations of the levels of transition. Both crystals are anisotropic, the optical phenomenon of double refraction of polarized light (birefringence) taking place. Images of maximum illumination and extinction were recorded when the crystals of the bis-azo compounds rotated by 90° each, which confirms their birefringence. A morphologic study of the thin films deposited onto glass surfaces was performed, proving the good adhesion of both dyes. By thermal analysis and calorimetry, the melting temperatures were determined (~224–225 °C for both of them), as well as their decomposition pathways and thermal effects (enthalpy variations during undergoing processes); thus, good thermal stability was exhibited. The interaction of the two compounds with collagen in the suede was studied, as well as their antioxidant activity, advocating for good chemical stability and potential to be safely used as coloring agents in the food industry. 相似文献
143.
Liviu Horia Popescu 《Integral Equations and Operator Theory》2014,79(3):355-375
The present paper is devoted to the study of some qualitative properties of C 0-groups via topological equivalence, also called conjugacy. The special case of the evolution groups is analysed. We show that hyperbolicity implies structural stability. Our constructions improve existing similar results for groups with bounded generators, and apply to linear differential equations with unbounded coefficient operator. 相似文献
144.
Sorin G. Gal 《Results in Mathematics》2014,65(3-4):453-462
By analogy with the probabilistic approach of the classical Bernstein polynomials, in this paper firstly we give the proof for the uniform convergence of the nonlinear max-product Bernstein operator by using the theory of possibility. This new approach, which interprets the max-product Bernstein operator as a possibilistic expectation of a particular fuzzy variable having a possibilistic Bernoulli distribution, does not only offer a good justification for the max-product Bernstein operator, but also allows to extend the method to other discrete max-product Bernstein type operators. 相似文献
145.
Catalytic and Atom‐Economic C
−C
Bond Formation: Alkyl Tantalum Ureates for Hydroaminoalkylation
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Rebecca C. DiPucchio Dr. Sorin‐Claudiu Roşca Prof. Laurel L. Schafer 《Angewandte Chemie (International ed. in English)》2018,57(13):3469-3472
Atom‐economic and regioselective C ?C bond formation has been achieved by rapid C?H alkylation of unprotected secondary arylamines with unactivated alkenes. The combination of Ta(CH2SiMe3)3Cl2, and a ureate N,O‐chelating‐ligand salt gives catalytic systems prepared in situ that can realize high yields of β‐alkylated aniline derivatives from either terminal or internal alkene substrates. These new catalyst systems realize C?H alkylation in as little as one hour and for the first time a 1:1 stoichiometry of alkene and amine substrates results in high yielding syntheses of isolated amine products by simple filtration and concentration. 相似文献
146.
Leulescu Marian Rotaru Andrei Pălărie Ion Moanţă Anca Cioateră Nicoleta Popescu Mariana Morîntale Emilian Bubulică Maria Viorica Florian Gabriel Hărăbor Ana Rotaru Petre 《Journal of Thermal Analysis and Calorimetry》2018,134(1):209-231
Journal of Thermal Analysis and Calorimetry - The food-colouring dye tartrazine is a significant additive and in the same time a biologically active material. Thermal behaviour of trisodium... 相似文献
147.
A theoretical study of the solvation of ( R)- N-(3,5-dinitrobenzoyl)phenylglycine- and ( R)- N-(3,5-dinitrobenzoyl)leucine-derived chiral stationary phases (CSPs) is presented. Semiflexible models of the chiral selectors are prepared from B3LYP/6-311G** calculations, and these are used in the molecular dynamics simulations of the corresponding interface. The chiral interface is examined for four solvents: 100% hexane, 90:10 hexane:2-propanol, 80:20 hexane:2-propanol, and 100% 2-propanol. Despite the similarities between phenylglycine and leucine, the interfaces are distinct both in terms of the selector orientations at the surface and in the number of hydrogen bonds formed with 2-propanol. We also find that an increase in alcohol concentration alters the preferred orientations of the selectors. 相似文献
148.
We consider amalgamated free product II1 factors M = M
1*B
M
2*B
… and use “deformation/rigidity” and “intertwining” techniques to prove that any relatively rigid von Neumann subalgebra Q ⊂ M can be unitarily conjugated into one of the M
i
’s. We apply this to the case where the M
i
’s are w-rigid II1 factors, with B equal to either C, to a Cartan subalgebra A in M
i
, or to a regular hyperfinite II1 subfactor R in M
i
, to obtain the following type of unique decomposition results, àla Bass–Serre: If M = (N
1 * CN2*C
…)
t
, for some t > 0 and some other similar inclusions of algebras C ⊂ N
i
then, after a permutation of indices, (B ⊂ M
i
) is inner conjugate to (C ⊂ N
i
)
t
, for all i. Taking B = C and , with {t
i
}
i⩾1 = S a given countable subgroup of R
+
*, we obtain continuously many non-stably isomorphic factors M with fundamental group equal to S. For B = A, we obtain a new class of factors M with unique Cartan subalgebra decomposition, with a large subclass satisfying and Out(M) abelian and calculable. Taking B = R, we get examples of factors with , Out(M) = K, for any given separable compact abelian group K. 相似文献
149.
Gelu Popescu 《Journal of Functional Analysis》2008,254(4):1003-1057
In this paper, we initiate the study of a class of noncommutative domains of n-tuples of bounded linear operators on a Hilbert space H, where m?2, n?2, and p is a positive regular polynomial in n noncommutative indeterminates. These domains are defined by certain positivity conditions on p, i.e.,
150.
M. D. Stanescu C. Popescu A. Rus C. Guran 《Journal of Thermal Analysis and Calorimetry》2008,94(2):535-538
A number of dibenzobicyclo[2.2.2]octane derivatives have been studied due to the interest of such compounds as ligands for
coordination compounds with potential biological activity. Their thermal behaviour has been analyzed in order to find out
more information about their fragmentation. A connection between the bridge substituents and the fragmentation process has
been observed. 相似文献