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41.
Rimantė Zinkutė Ričardas Taraškevičius Tomas Želvys 《Central European Journal of Chemistry》2011,9(2):337-347
The relationship between real total contents of the major elements Na, Mg, Al, Si, P, S, K, Ca, Ti, Fe and the trace elements
Ag, As, B, Ba, Co, Cr, Cu, Mn, Mo, Ni, Pb, Sb, Se, Sn, V, U, Zn in topsoil from the central part of Vilnius is analysed. The
amounts of most elements were determined by energy-dispersive X-ray fluorescence, while amounts of Ag, B, Co were measured
by optical atomic emission spectrophotometry. Two factors were distinguished according to major elements: anthropogenic (A)
including Ca, Mg, Fe, P, S and clayey (C) including K, Al, Ti. Boron, Mn, Cr and U are significantly correlated with members
of both factors, Sb with none of them and other trace elements either with all (Cu, Zn, Pb, Se, Ba, Ni, Co) or with separate
(V, Ag, Sn, Mo, As) members of the A-factor. Only B, Mn, Cr, U (partly their additive index Z1) are influenced by the C-factor,
while twelve other trace elements (also their additive index Z2) are influenced by the A-factor. The additive index Z of all
17 elements is also affected by the A-factor. Four groups of sites have been distinguished according to normal or higher contents
of both factors. The majority of trace element anomalies are related to the sites affected by the A-factor. 相似文献
42.
采用基于密度泛函理论的平面波超软赝势方法研究了 纯的和不同高氧空位浓度金红石型TiO2-x (x=0, 0.083, 0.125, 0.167, 0.25)超胞的能带结构分布、态密度分布.同时, 采用局域密度近似+U方法调准了带隙.结果表明, 高氧空位浓度越高, 金红石型TiO2的最小带隙越变窄、电子有效质量越减小, 自由电子浓度越高, 电子迁移率越低、电导率越低.计算结果与实验结果的变化趋势相符合.
关键词:
高氧空位
2')" href="#">金红石型TiO2
电导率
第一性原理 相似文献
43.
关于Hardy不等式的加强改进 总被引:6,自引:0,他引:6
对 Hardy不等式 ,建立如下结构的加强不等式 :∑∞n=11n∑nk=1akp 1 ,an≥ 0 (n∈ N) ,0 <∑∞n=1apn<∞ ,Cp=1 -(1 -p- 1) p- 1,p≥ 2 ;1 -p- 1,1
相似文献
44.
45.
The temperature dependence of the polarized and depolarized Raman spectra of the ν2, ν4, ν6 and ν7 modes were measured for t-butyl chloride and the analogous group IVA trimethylmetal chrlorides (silicon, germanium and tin). Analysis of the lineshapes revealed that isotropic second moments and vibrational relaxation times for a given mode remained approximately constant through the series. This tranferability of relaxation parameters between molecules extended to modulation times calculated from the Kubo formalism. The above results are in contrast to earlier studies on molecules of dissimilar structure. They provide some preliminary evidence that the mechanism of vibrational relaxation may be the same for equivalent modes in members of the series. 相似文献
46.
Xingjiang Wu Ri Hong Jinku Meng Rui Cheng Zhijie Zhu Guan Wu Qing Li Cai‐Feng Wang Su Chen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(38):13690-13698
Photonic crystals (PCs) have been widely applied in optical, energy, and biological fields owing to their periodic crystal structure. However, the major challenges are easy cracking and poor structural color, seriously hindering their practical applications. Now, hydrophobic poly(tert‐butyl acrylate) (P(t‐BA)) PCs have been developed with relatively lower glass transition temperature (Tg), large crack‐free area, excellent hydrophobic properties, and brilliant structure color. This method based on hydrophobic groups (tertiary butyl groups) provides a reference for designing new kinds of PCs via the monomers with relatively lower Tg. Moreover, the P(t‐BA) PCs film were applied as the photoluminescence (PL) enhanced film to enhance the PL intensity of CdSe@ZnS QDs by 10‐fold in a liquid‐crystal display (LCD) device. The new‐type hydrophobic force assembled PCs may open an innovative avenue toward new‐generation energy‐saving devices. 相似文献
47.
Fu Ri Ling Zhi Hong He Jian Quan Yao Baio Wang Shao Ji Jiang 《Optics & Laser Technology》2008,40(7):941-945
A series of near-stoichiometric Zn:Fe:LiNbO3 crystals were grown by the high-temperature top-seed solution growth (HTTSSG) method from stoichiometric melts doped with 6 mol% K2O. Infrared (IR) transmission spectra were measured and discussed in terms of the defect structure of the near-stoichiometric Zn:Fe:LiNbO3 crystals. The results of the transmitted beam pattern distortion method show that the optical damage resistance of the near-stoichiometric Zn:Fe:LiNbO3 crystals increases rapidly when the ZnO concentration exceeds a threshold value. The threshold value concentration of ZnO of the near-stoichiometric Zn:Fe:LiNbO3 crystals is much lower than that of the congruent LiNbO3 crystals. The dependence of the optical damage resistance on the defect structure of the near-stoichiometric Zn:Fe:LiNbO3 crystals are discussed, and the holographic recording properties of the near-stoichiometric Zn:Fe:LiNbO3 crystals are investigated. 相似文献
48.
49.
SongIl Ri 《Indagationes Mathematicae》2018,29(3):962-971
The aim of this paper is to present a new idea to construct the nonlinear fractal interpolation function, in which we exploit the Matkowski and the Rakotch fixed point theorems. Our technique is different from the methods presented in the previous literatures. 相似文献
50.
Ionic liquid-modified silica particles with a large pore size were synthesized and used as the stationary phase for size exclusion chromatography coupled with a refractive index detector for the determination of polysaccharides, such as fucoidan, alginic acid, and laminarin from Undaria pinnatifida (seaweed). The molecular weight of polysaccharide was determined by a dextran standard curve (5–1100?kDa). The ionic liquid-modified silica column exhibited excellent size exclusion properties in separating laminarin from other components. The 1-butyl-3-methyl-imidazolium bis-(trifluoromethylsulfonyl)-amino silica column has superior resolution in laminarin separation than the other columns because the amino-group in ionic liquid provide π–π interactions due to aromaticity of the ring structure, which enhances the effect of the hydroxyl group in the target compound separation. The concentrations of polysaccharides were calculated using a standard linear equation to be 0.332–0.484?mg/g of fucoidan, 0.207–0.301?mg/g of alginic acid, and 0.154–0.297?mg/g of laminarin. 相似文献